La-doped TiO2 nano-catalysis material used for low-temperature plasma catalysis synergistic effect

A nano-catalytic material, low-temperature plasma technology, applied in catalyst activation/preparation, physical/chemical process catalyst, metal/metal oxide/metal hydroxide catalyst, etc. Insufficient rate and other problems, to achieve the effect of good catalytic effect, improved quantum yield and simple process flow

Inactive Publication Date: 2016-02-03
合肥科丽尔科技有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] TiO 2 Although it has a good catalytic effect, it can only absorb light in the ultraviolet region due to its wide band gap, resulting in insufficient utilization of incident light, making TiO used in low-temperature plasma and catalytic synergy technology 2 The catalytic efficiency of thin film catalysts needs to be improved

Method used

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  • La-doped TiO2 nano-catalysis material used for low-temperature plasma catalysis synergistic effect
  • La-doped TiO2 nano-catalysis material used for low-temperature plasma catalysis synergistic effect
  • La-doped TiO2 nano-catalysis material used for low-temperature plasma catalysis synergistic effect

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Embodiment

[0024] La-doped TiO for low-temperature plasma-catalyzed synergy was prepared by the following steps 2 Nano catalytic materials:

[0025] (1) Add 10 ml of butyl titanate to the reactor, then slowly add 25 ml of absolute ethanol while stirring the butyl titanate to obtain a mixed solution, stir the mixed solution vigorously for 2 hours, then add 0.4 g of polyethylene Diol (20000), continue to stir for 30 minutes, obtain solution A;

[0026] (2) 25 milliliters of absolute ethanol and 1 milliliter of deionized water were mixed evenly, and then 100 milligrams of lanthanum nitrate and 2 milliliters of nitric acid were added successively, and the pH was controlled to be 2-3 to obtain solution B;

[0027] (3) solution B is added dropwise in the solution A of stirring, continue to stir for 2 hours, obtain Ti0 2 Sol;

[0028] (4) the prepared Ti0 2 The sol was sealed and placed for 10 hours in order to prepare the film;

[0029] (5) Coating with the ceramic electrode material as t...

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Abstract

The invention discloses a La-doped TiO2 nano-catalysis material used for low-temperature plasma catalysis synergistic effect. The La-doped TiO2 nano-catalysis material is prepared by the following steps: slowly adding absolute ethyl alcohol into butyl titanate; stirring and then adding polyethylene glycol, and continuing to stir to obtain a solution A; sequentially adding lanthanum nitrate and nitric acid into a mixed solution of the absolute ethyl alcohol and de-ionized water and controlling the pH to be 2-3 to obtain a solution B; dripping the solution B into the solution A and stirring to obtain TiO2 sol; sealing the TiO2 sol for a certain period of time to prepare a film; taking a ceramic electrode material as a base for plating the film; after plating the film, drying in a drying oven; repeatedly carrying out film plating and drying operation for 5 times to obtain a ceramic electrode base coated film; putting the ceramic electrode base coated film into a box type furnace and preserving heat at 20 DEG C for 0.5 hour; and preserving heat at 450 DEG C for 0.5 hour to obtain the La-doped TiO2 nano-catalysis material. According to the La-doped TiO2 nano-catalysis material, a technological flow is simple and convenient, industrial production is convenient to realize and the catalytic effect is good; and the degradation rate on benzene is 86% and is improved by 30% compared with that of a pure ceramic electrode material.

Description

technical field [0001] The present invention relates to nanometer TiO 2 In the field of photocatalyst thin film manufacturing, it mainly involves TiO used in low-temperature plasma catalytic synergistic reactors 2 Manufacturing industry of photocatalytic thin film materials, specifically La doped TiO for low temperature plasma catalytic synergy 2 nanocatalytic materials. Background technique [0002] Low-temperature plasma and catalyst synergy technology is currently the frontier research field for air pollution treatment. It not only has the characteristics of convenience and efficiency of low-temperature plasma technology, but also has the characteristics of high precision and high efficiency of catalytic oxidation, so it has become a research hotspot. The core of this technology is to effectively combine the low-temperature plasma generator with the catalyst to exert a synergistic effect. Therefore, the preparation of a catalyst material that is effectively combined wit...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/10B01J21/06B01J35/02B01J37/02H01M4/88H01M4/90
CPCY02E60/50
Inventor 卢俊清何柄谕周敏
Owner 合肥科丽尔科技有限公司
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