Unlock instant, AI-driven research and patent intelligence for your innovation.

A kind of preparation method of multifunctional remediation agent for the treatment of heavy metal polluted soil

A technology of contaminated soil and remediation agent, which is applied in the field of soil pollution control, can solve the problems of unscientific proportion of agents, destruction of soil fertility, and long repair period, etc., and achieve the effects of low cost, enhanced pH buffering capacity, and fast action

Inactive Publication Date: 2018-05-08
TONGJI UNIV
View PDF11 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Currently commonly used chemical passivation materials mainly include phosphates, carbonates, silicates and clay minerals, etc. Invention patents are mostly used after simple mixing of the above components, and there are disadvantages such as unscientific dosage, large usage, long repair cycle, poor long-term effect, high price, and easy damage to soil fertility.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] (1) Mix rice husk powder with a particle size of 50 mesh and attapulgite with a particle size of 150 mesh at a weight ratio of 1:10, take 20 g of the above mixture, and add it to 100 mL of 30% MgCl 2 The solution was stirred continuously and the pH value of the mixture was adjusted to 10 with 1 mol / L NaOH to obtain a precipitate, which was filtered with suction and dried at 105°C. Under the condition of isolated air, the dried product was roasted at 450°C for 2 h, and after cooling to room temperature, it was ground into material A of not less than 100 mesh.

[0023] (2) Take 20g of material A and add it to 100mL nitrogen and phosphorus mixed solution (NH 4 + The concentration is 100 mg / L, PO 4 3- 250mg / L), room temperature, 200r / min stirring condition for 4h and then filtered, the filtered solid was dried at 105°C, and ground to a size of not less than 200 mesh to obtain a multifunctional restoration agent.

[0024] Select Cd 2+ Contaminated soil was used as the s...

Embodiment 2

[0026] (1) Mix wheat straw powder with a particle size of 50 mesh and bentonite with a particle size of 200 mesh at a weight ratio of 1:9, take 20 g of the above mixture, and add it to 100 mL of 40% MgCl 2 The solution was stirred continuously and the pH value of the mixture was adjusted to 10 with 1 mol / L NaOH to obtain a precipitate, which was filtered with suction and dried at 105°C. Under the condition of isolated air, the dried product was roasted at 500°C for 1.5 h, and after cooling to room temperature, it was ground into a material A of not less than 100 mesh.

[0027] (2) Take 20g of material A and add it to 100mL nitrogen and phosphorus mixed solution (NH 4 + The concentration is 120 mg / L, PO 4 3- 300mg / L), room temperature, 200r / min under stirring conditions for 6h and then filtered, the filtered solid was dried at 105°C, and ground to a size of not less than 200 mesh to obtain a multifunctional restoration agent.

[0028] Select Pb 2+ Contaminated soil was use...

Embodiment 3

[0030] (1) Mix corncob powder with a particle size of 50 mesh and diatomite with a particle size of 200 mesh at a weight ratio of 1:8, take 20 g of the above mixture, and add it to 100 mL of 35% MgCl 2 The solution was stirred continuously and the pH value of the mixture was adjusted to 10 with 1 mol / L NaOH to obtain a precipitate, which was filtered with suction and dried at 105°C. Under the condition of isolated air, the dried product was calcined at 550°C for 3 h, and after cooling to room temperature, it was ground into material A of not less than 100 mesh.

[0031] (2) Take 20g of material A and add it to 100mL nitrogen and phosphorus mixed solution (NH 4 + The concentration is 150 mg / L, PO 4 3- 320mg / L), room temperature, 200r / min stirring condition for 4h and then filtered, the filtered solid was dried at 105°C, and ground to a size of not less than 200 mesh to obtain a multifunctional restoration agent.

[0032] Select Cr 3+ Contaminated soil was used as the sampl...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle sizeaaaaaaaaaa
particle sizeaaaaaaaaaa
particle size (mesh)aaaaaaaaaa
Login to View More

Abstract

The invention relates to a preparation method of a multifunctional repair agent used for governing heavy metal contaminated soil, in particular to biomass charcoal and clay compound which is generated in a nitrogen and phosphorus solution by using agricultural biomass waste and clay mineral as raw materials and conducting magnesium salt modification and high-temperature roasting, and loaded with struvite. When lands are utilized, the compound can conduct passivation and stabilization on heavy metal ions in soil while having the functions of slow release fertilizer, mobility and bioavailability of heavy metal are lowered to the maximum extent, and the aim of repairing heavy metal contaminated soil in situ is achieved. The prepared repair agent has the dual functions of enhancing soil fertilizer efficiency and stabilizing heavy metal, and the preparation method is simple, quick in efficacy, low in cost and capable of being used for efficient in-situ repair of farmlands and other industrial heavy metal polluted soil.

Description

technical field [0001] The invention belongs to the technical field of soil pollution control, and in particular relates to a preparation method of a multifunctional restoration agent for heavy metal polluted soil control. Background technique [0002] Soil heavy metal pollution refers to the phenomenon that human activities bring heavy metals into the soil, causing the content of heavy metals in the soil to be significantly higher than its natural background value, and causing ecological damage and environmental quality deterioration. With the rapid growth of population and the continuous expansion of industrial and agricultural production, the situation of heavy metal pollution in soil is becoming more and more serious, and the problems caused by it are becoming more and more prominent, which has become a serious environmental problem facing the world. Heavy metal pollution not only changes the physical, chemical and biological properties of soil, reduces the yield and qua...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C09K17/40C05G3/04C05G3/80
CPCC05G3/80C09K17/40
Inventor 王学江夏鹏王浩景焕平马荣荣张志昊成雪君王佳忆马嵩赵建夫夏四清
Owner TONGJI UNIV