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Amino polycarboxylic acids as processing aids in the production of superabsorbents

A technology of amino polycarboxylic acid and chelating agent, applied in the direction of absorbent pads, medical science, bandages, etc., can solve the problems of increased residual monomer fraction, incorrect temperature management, insufficient conversion, etc., and achieve improved gel processability Effect

Active Publication Date: 2016-03-23
EVONIK SUPERABSORBER GMBH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, if the reaction proceeds too slowly (e.g. as a result of defective initiation or incorrect temperature management), there can be, for example, a significant increase in the so-called residual monomer fraction due to insufficient conversion

Method used

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  • Amino polycarboxylic acids as processing aids in the production of superabsorbents

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0136] Embodiment 1: (use DTPA pentasodium salt as the batch of processing aid)

[0137] The chelating agent was added to an aqueous solution of 40.2% by weight diethylenetriaminetetraacetic acid sodium salt using 1.19 g ( 80EexDow) form monomer solution.

Embodiment 2a

[0138] Embodiment 2a (using EDTA tetrasodium salt = Bliquidex BASF as a processing aid)

[0139] The chelating agent was added to an aqueous solution of 42.5% by weight ethylenediaminetetraacetic acid sodium salt using 0.85 g ( in monomer solution in the form of BliquidexBASF).

Embodiment 2b

[0140] Embodiment 2b (using EDTA tetrasodium salt = Bliquidex BASF as a processing aid)

[0141] The chelating agent was added to 42.5% by weight ethylenediaminetetraacetic acid sodium salt aqueous solution ( in monomer solution in the form of BliquidexBASF).

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Abstract

Described is the production of water-absorbing polymeric particles by polymerizing a monomer solution or suspension comprising a) at least one ethylenically unsaturated acid-functional monomer which is optionally at least partly present as salt, b) at least one crosslinker and c) at least one initiator, wherein the process further comprises drying the resulting polymer and also optionally grinding the dried polymer and sieving the ground polymer and also optionally surface-postcrosslinking the dried and possibly ground and sieved polymer, and wherein the polymerization is carried out in the presence of aminopolycarboxylic acids and / or salts thereof, in particular in the presence of ethylenediaminedisuccinic acid and / or a salt thereof.

Description

technical field [0001] The present invention is in the field of superabsorbents and water-absorbing polymer particles. The present invention specifically relates to a method for producing water-absorbent polymer particles by using specified aminopolycarboxylic acids and / or salts thereof. The present invention relates to water-absorbing polymer particles, hygiene articles comprising water-absorbing polymer particles, and the use of specified aminopolycarboxylic acids and / or salts thereof as processing aids in the production of water-absorbing polymer particles. Background technique [0002] Superabsorbents are known, a term referring to crosslinked hydrophilic polymers capable of absorbing large quantities of aqueous fluids. This ability is based on the strong interaction of water with hydrophilic groups (in particular ionic groups or groups capable of forming hydrogen bonds) on the superabsorbent. Other customary names for superabsorbents include: "superabsorbent polymers"...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F290/06C08F222/14C08J3/24A61L15/24A61L15/60
CPCC08F2/04C08F2/18C08G63/83C08J2300/14B01J20/261B01J20/267B01J20/3014B01J20/3085C08F2/44C08F6/008C08L101/14C08L33/02A61L15/24A61L15/60
Inventor C·鲁瓦克I·罗伊D·加尔茨
Owner EVONIK SUPERABSORBER GMBH
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