Primer for bonding of addition type silicone rubber and dry type transformer material
A technology of primer and silane coupling agent, which is applied in the direction of adhesives, adhesive additives, non-polymer adhesive additives, etc., can solve the problem of inapplicable bonding between addition-type silicone rubber and dry-type transformers, and achieve enhanced Adhesive effect, effect of promoting hydrolysis
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Embodiment 1
[0049] Mix and stir 8 parts by mass of silicone resin and 100 parts by mass of ethanol at room temperature. After the silicone resin is completely dissolved, add 7 parts by mass of vinyltrimethoxysilane, 3 parts by mass of (3-methacryloyloxypropane base) trimethoxysilane, 5 parts by mass of (3-glycidoxypropyl) trimethoxysilane and 25 parts by mass of ethyl orthosilicate, mix evenly to obtain the primer. Wherein, the silicone resin structure is as follows:
[0050] [(CH 3 ) 3 SiO 1 / 2 ] 5 [H(CH 3 ) 2 SiO 1 / 2 ] 10 [HOSiO 3 / 2 ] 5 [SiO 4 / 2 ] 20
[0051] Apply the primer above to the surface of the dry-type transformer material, let it dry at room temperature for half an hour, then apply and mold silicone rubber (Dow Corning HV1551 / 55P), and cure at 150°C for half an hour. After cooling, tear off the silicone layer by hand to observe its peeling state on the surface of the substrate.
Embodiment 2
[0053] Mix and stir 20 parts by mass of silicone resin and 100 parts by mass of ethanol at room temperature. After the silicone resin is completely dissolved, add 3 parts by mass of vinyltrimethoxysilane, 8 parts by mass of (3-acryloyloxypropyl) Trimethoxysilane, 6 parts by mass of (3-glycidoxypropyl) triethoxysilane, 35 parts by mass of ethyl orthosilicate and 0.5 part by mass of glacial acetic acid were mixed uniformly to obtain the primer.
[0054] Wherein, the silicone resin structure is as follows:
[0055] [(CH 3 ) 3 SiO 1 / 2 ] 3 [H(CH 3 ) 2 SiO 1 / 2 ] 15 [HOSiO 3 / 2 ] 2 [SiO 4 / 2 ] 25
[0056] Apply the primer above to the surface of the dry-type transformer material, let it dry at room temperature for half an hour, then apply and mold silicone rubber (Dow Corning HV1551 / 55P), and cure at 150°C for half an hour. After cooling, tear off the silicone layer by hand to observe its peeling state on the surface of the substrate.
Embodiment 3
[0058] Mix and stir 13 parts by mass of silicone resin and 100 parts by mass of isopropanol at room temperature. After the silicone resin is completely dissolved, add 5 parts by mass of vinyltriethoxysilane, 6 parts by mass of (3-methylpropene Acyloxypropyl) trimethoxysilane, 4 parts by mass of (3-glycidoxypropyl) trimethoxysilane, 30 parts by mass of propyl orthosilicate and glacial acetic acid of 0.2 parts by mass, mix evenly to get Primer.
[0059] Wherein, the silicone resin structure is as follows:
[0060] [H(CH 3 ) 2 SiO 1 / 2 ] 15 [HOSiO 3 / 2 ] 4 [SiO 4 / 2 ] 30
[0061] Apply the primer above to the surface of the dry-type transformer material, let it dry at room temperature for half an hour, then apply and mold silicone rubber (Dow Corning HV1551 / 55P), and cure at 150°C for half an hour. After cooling, tear off the silicone layer by hand to observe its peeling state on the surface of the substrate.
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