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Photocuring solder-resist ink

A solder mask ink, light curing technology, applied in the direction of ink, optics, organic chemistry, etc., can solve the problems of the accuracy of pattern size and the lack of uniformity of pattern edges.

Active Publication Date: 2016-06-22
INSIGHT HIGH TECH (BEIJING) CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Photoinitiators commonly used in existing solder resist inks, such as: 907, DETX, IRGACUREOXE02 or their combinations, are still deficient in the accuracy of the pattern size and the uniformity of the pattern edge, and need to be improved

Method used

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  • Photocuring solder-resist ink

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] 1) Preparation of solder mask ink:

[0048] The components shown in Table 1 were blended in the amounts (parts by mass) shown in Table 1, and stirred, mixed and dispersed to obtain light-curable solder resist ink formulations A-E.

[0049] Table 1

[0050]

[0051] 2) Film forming process of solder mask:

[0052] Screen print each light-curing solder mask ink formulation on the deoxidized copper clad board, use a hot air circulation drying oven, dry at 75 ℃ for 40 minutes, after drying, slowly cool to room temperature, and fix the line width on it. 20μm and 150μm line width pattern photomask, with mercury lamp at 150mJ / cm 2 Exposure amount for front exposure, using 1wt% Na 2 CO 3 The aqueous solution was developed with a spray pressure of 0.25MPa and a temperature of 30°C for 90 seconds, and then washed and dried.

[0053] 3) Performance evaluation of solder mask:

[0054] Edge neatness evaluation:

[0055] Use a 100-fold stereo microscope to observe the edge regularity of the pat...

Embodiment 2

[0075] Replace the exposure light source with a 365nm LED lamp. The other process is the same as in Example 1. The results are listed in Table 3.

[0076] table 3

[0077]

[0078] Conclusion: 5-(4-isopropylphenylthio)indan-1,2-dione-2-oxime-O-acetate formulation A and 5-(n-butoxy)indan- The formula B of 1,2-diketone-2-oxime-O-acetate has better comprehensive effects than formulas C, D, and E in the test.

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Abstract

The invention relates to photocuring solder-resist ink. The ink comprises (A) alkali-soluble resin, (B) at least one photoinitiator compound shown as a formula (I), (C) a compound the molecule of which contains olefinic bond unsaturated groups, and (D) pigment.

Description

Technical field [0001] The invention relates to the composition of a photocurable solder resist ink and a method for forming a solder resist film. After the photocurable composition is coated on a substrate and dried, the dried coating film is irradiated with ultraviolet light through a mask plate. The solder resist pattern is formed by development with an alkaline aqueous solution. Background technique [0002] In a printed circuit board, electronic components are mounted on the soldering area of ​​a printed circuit substrate on which a conductive circuit pattern is preformed, and all circuit areas outside the soldering area are covered by a solder mask as a permanent protective film. In this way, when the electronic component is soldered to the printed circuit board, the solder can be prevented from sticking to the area that does not need to be covered by the solder, and the conductors constituting the circuit pattern can be prevented from being oxidized due to direct exposure ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D11/101C09D11/107G03F7/027
CPCC07D209/86C07D295/135C07D307/83C07D307/937C07D333/66C07D333/78C07D493/04C08F2/50C09B55/009C09B57/00G02B1/04G02B5/201G03F7/0007G03F7/029G03F7/031C07C251/20C07D307/88
Inventor 赵文超王辰龙
Owner INSIGHT HIGH TECH (BEIJING) CO LTD