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Magnesium indium phosphate matrix material for rare earth phosphor and preparation method thereof

A technology of magnesium indium phosphate and rare earth phosphors, which is applied in the direction of luminescent materials, chemical instruments and methods, etc., can solve the problems of rare exploration of new matrix materials, and achieve the effect of simple preparation process

Active Publication Date: 2017-10-17
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, most of the research work in this field is based on the doping modification of the reported compounds, or the research on a series of isomorphic compounds of the more mature matrix, while the work of exploring new matrix materials is relatively rare.

Method used

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  • Magnesium indium phosphate matrix material for rare earth phosphor and preparation method thereof
  • Magnesium indium phosphate matrix material for rare earth phosphor and preparation method thereof
  • Magnesium indium phosphate matrix material for rare earth phosphor and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] Example 1: Mg 25 In 30 P 45 o 182.5 Preparation of Phosphor Matrix

[0040] Weigh 0.1947g MgO, 0.8049g In 2 o 3 , 1.0004g NH 4 h 2 PO 4 Put it in a beaker, add an appropriate amount of nitric acid to dissolve the raw materials, add a small amount of polyvinyl alcohol and an appropriate amount of deionized water after the solution is clarified, heat and stir until it is completely evaporated to dryness, dry the beaker in a drying oven and grind it evenly; then carry out two final steps Sintering (the sintering temperature of the first stage is 1200°C, after 15 hours of heat preservation, it is cooled to room temperature with the furnace, and ground for 10 minutes; the sintering temperature of the second stage is 1200°C, and it is cooled to room temperature with the furnace after 15 hours of heat preservation, and the heating rate of the two steps of sintering is 5 °C / min). Take out the burnt sample and grind it to get Mg 25 In 30 P 45 o 182.5 Phosphor matrix...

Embodiment 2

[0041] Example 2: Mg 23 In 29 P 44 o 176.5 Preparation of Phosphor Matrix

[0042] Weigh 0.1851g MgO, 0.8040g In 2 o 3 , 1.0108g NH 4 h 2 PO 4 , the rest of the steps are the same as in Example 1.

Embodiment 3

[0043] Example 3: Mg 27 In 33 P 47 o 194 Preparation of Phosphor Matrix

[0044] Weigh 0.1965g MgO, 0.8272g In 2 o 3 , 0.9763g NH 4 h 2 PO 4 , the rest of the steps are the same as in Example 1.

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Abstract

The invention discloses a magnesium and indium phosphate matrix material for rare-earth phosphor and a method for preparing the magnesium and indium phosphate matrix material. Chemical composition of the magnesium and indium phosphate matrix material is Mg21-28In28-34P42-48Oy (the y is equal to 168-199). The method includes preparing the magnesium and indium phosphate matrix material by the aid of wet-chemical and solid-phase sintering processes. The magnesium and indium phosphate matrix material and the method have the advantages that a novel phosphate compound which can be used as a phosphor matrix material is successfully researched and developed and contains indium elements, rare-earth elements which are used as activation centers can partially replace the indium elements to enter matrix crystal lattices, and accordingly the compound prepared by the aid of the method can be used as the matrix material for the phosphor; reports on magnesium and indium phosphate matrix materials are unavailable in the prior art; processes for preparing the magnesium and indium phosphate matrix material are simple, and the like.

Description

Technical field: [0001] The invention relates to the field of rare earth luminescent materials, in particular to a magnesium indium phosphate matrix material for rare earth fluorescent powder and a preparation method thereof. Background technique: [0002] In today's information age, phosphors are widely used in lighting, display, decoration, detection, anti-counterfeiting and many other fields, and have become an indispensable material in people's daily life. As an important part of phosphor, the matrix has an important impact on the performance of the product. Different matrixes have different crystal structures. After doping with activated ions, the energy level splitting is different due to the different crystal field environments. Macroscopically, The above shows the difference in spectral properties. Because of its moderate phonon energy, strong absorption band in the vacuum ultraviolet-ultraviolet region, high solubility of rare earth ions, stable physical and chemic...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K11/70C09K11/81
CPCC09K11/70C09K11/7737C09K11/7752
Inventor 蔡格梅张静司家勇金展鹏
Owner CENT SOUTH UNIV
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