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A three-dimensional interpenetrating al by in situ reaction 2 o 3 /al composite approach

A composite material and in-situ reaction technology, applied in the field of materials, can solve the problems of uneven dispersion, different performance, uneven distribution of reinforcement particles, etc., and achieve the effect of improving wear resistance, clear interface and good combination

Inactive Publication Date: 2017-06-20
CHANGAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are some problems in the traditional composite method: 1). Uneven dispersion, easy to agglomerate, resulting in unstable performance of the material; 2). Anisotropy (fiber reinforcement), the performance of different orientations of the material is not the same; 3). Reinforcement There is discontinuity in the three-dimensional space of the body, and the reinforcement effect needs to be improved; 4). There is an upper limit for the amount of ceramic reinforcement added;
However, this method has the problem of uneven distribution of reinforcement particles formed by the reaction
Although various stirring methods are used, the silicon oxide powder cannot be uniformly distributed in the metal aluminum, and at high temperatures, the silicon oxide has already begun to react with the aluminum liquid during stirring, resulting in uneven distribution of the components of the composite material. To ensure the performance of the composite material, it is important that the formed composite material is not a three-dimensional network composite material, and no connection is formed between the reinforcements, and it is actually a particle-reinforced composite material.

Method used

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  • A three-dimensional interpenetrating al by in situ reaction  <sub>2</sub> o  <sub>3</sub> /al composite approach
  • A three-dimensional interpenetrating al by in situ reaction  <sub>2</sub> o  <sub>3</sub> /al composite approach
  • A three-dimensional interpenetrating al by in situ reaction  <sub>2</sub> o  <sub>3</sub> /al composite approach

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] (1) SiO 2 Preparation of ceramic slurry: Weigh 70g of analytically pure 200 mesh SiO 2 Powder, weigh 7g H 3 BO 3 , weigh 0.3g carboxymethyl cellulose, measure 30mL water, measure 4.9mL ammonium polyacrylate, mix the weighed materials and stir evenly, pour them into the mixing bottle, add ceramic balls and wet grind on the mixer 24h, get SiO 2 Ceramic slurry;

[0030] (2) The pretreatment of polyurethane foam: get hole number and be that 10ppi polyurethane foam soaks 5h in the NaOH solution of 20% in mass fraction, knead the thin film between polyurethane foam ribs, then immerse in the PVA solution of 5% in mass fraction Activation treatment at 60°C for 24h.

[0031] (3) Slurry: immerse the pretreated polyurethane foam in SiO 2 Carry out vacuum impregnation and slurrying in the ceramic slurry, the vacuum degree is -0.1MPa, and the dipping time is 5 minutes. After slurrying, the green body is taken out and dried at room temperature and normal pressure to obtain a dr...

Embodiment 2

[0035](1) SiO 2 Preparation of ceramic slurry: Weigh 70g of analytically pure 200 mesh SiO 2 Powder, weigh 7g H 3 BO 3 , weigh 0.3g carboxymethyl cellulose, measure 30mL water, measure 4.9mL ammonium polyacrylate, mix the weighed materials and stir evenly, pour them into the mixing bottle, add ceramic balls and wet grind on the mixer 24h, get SiO 2 Ceramic slurry;

[0036] (2) The pretreatment of polyurethane foam: get hole number and be that 20ppi polyurethane foam soaks 5h in the NaOH solution of 20% in mass fraction, knead the thin film between the tendons of polyurethane foam, then immerse in the PVA solution of 5% in mass fraction Activation treatment at 60°C for 24h.

[0037] (3) Slurrying: immerse the pretreated polyurethane foam into the SiO2 ceramic slurry for vacuum impregnation and slurrying. The vacuum degree is -0.1 MPa, and the immersion time is 5 minutes. After slurrying, the green body is taken out, and dried at room temperature and normal pressure to obt...

Embodiment 3

[0041] (1) SiO 2 Preparation of ceramic slurry: Weigh 70g of analytically pure 200 mesh SiO 2 Powder, weigh 7g H 3 BO 3 , weigh 0.3g carboxymethyl cellulose, measure 30mL water, measure 4.9mL ammonium polyacrylate, mix the weighed materials and stir evenly, pour them into the mixing bottle, add ceramic balls and wet grind on the mixer 24h, get SiO 2 Ceramic slurry;

[0042] (2) The pretreatment of polyurethane foam: get hole number and be that 30ppi polyurethane foam soaks 5h in the NaOH solution of 20% in mass fraction, knead the film between polyurethane foam tendons, then immerse in the PVA solution of 5% in mass fraction Activation treatment at 60°C for 24h.

[0043] (3) hanging paste: the pretreated polyurethane foam is immersed in the SiO 2 Carry out vacuum impregnation and slurrying in the ceramic slurry, the vacuum degree is -0.1MPa, and the dipping time is 5 minutes. After slurrying, the green body is taken out, and dried at room temperature and normal pressure ...

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Abstract

A three-dimensional interpenetrating Al prepared by in-situ reaction 2 o 3 / Al composite method, the SiO 2 Add powder, water, boric acid, ammonium polyacrylate, and carboxymethyl cellulose to water, mix and prepare SiO 2 Ceramic slurry; polyurethane foam impregnated into SiO 2 Carry out vacuum impregnation and slurrying in the ceramic slurry, sinter after drying, and then place it in molten aluminum at 800-1100°C, and keep it warm for 20min-240min. Due to the in-situ reaction, the interface between the alumina reinforcement and the aluminum matrix in this material is clear and well bonded; the alumina ceramics produced by the reaction maintain the appearance and structure of the network silica ceramics before the reaction; the formed alumina network As a reinforcement, ceramics are continuously distributed in the aluminum matrix, which can effectively disperse the load and improve the strength of the alumina / aluminum composite material; the formed network alumina reinforcement is harder than the aluminum matrix, which can effectively improve the alumina / aluminum composite material. wear resistance.

Description

technical field [0001] The invention belongs to the field of material technology, and relates to a method for preparing three-dimensional through Al through in-situ reaction. 2 o 3 / Al composite method. Background technique [0002] Aluminum alloy has the advantages of low density, high specific strength, and easy forming. It is one of the ideal metal materials for the transportation industry to achieve the goal of light weight and high speed, and has been widely used in the industrial field. The way to further strengthen the performance of aluminum alloy is to form composite materials, such as: particle reinforcement, fiber reinforcement and so on. However, there are some problems in the traditional composite method: 1). Uneven dispersion, easy to agglomerate, resulting in unstable performance of the material; 2). Anisotropy (fiber reinforcement), the performance of different orientations of the material is not the same; 3). Reinforcement There is discontinuity in the th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C21/00C22C29/12C22C32/00C22C1/10
CPCC22C1/1015C22C1/1068C22C21/00C22C29/12C22C32/0036C22C1/1021C22C1/1073
Inventor 桑可正李红伟黄治文景胜
Owner CHANGAN UNIV