Preparation method of ecological chelated straw fertilizer
A straw fertilizer, chelation technology, applied in organic fertilizers, fertilization devices, fertilizer mixtures, etc., can solve the problems of harming crops in the next season, difficult decay time, difficult farmers' application, etc., to achieve waste utilization, reduce mobility and biological efficiency. Effectiveness, the effect of increasing soil organic matter content
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[0016] The preparation method of the ecological chelated straw fertilizer of the present invention comprises the following steps: (a) fermenting the straw to obtain a fermentation mixture, (b) adding carbon disulfide to the fermentation mixture to react under alkaline conditions. By adding carbon disulfide to the fermentation mixture and reacting under alkaline conditions, the final product can not only be used for soil fertilization, but also can chelate heavy metal ions in the soil, especially the adsorption of cadmium ions, which realizes waste Utilization has the effect of environmental protection; and step (a) and step (b) are not mutually isolated steps, but are interrelated; in step (a), the straw is fermented to degrade cellulose and lignin, and is transformed into inorganic Nitrogen can slowly increase the nitrogen content in farmland, and at the same time release nitrogen free radicals to enhance the stability of heavy metal chelation. The prepared ecological chelate...
Embodiment 1
[0022] The present embodiment provides a kind of preparation method of ecological chelated straw fertilizer, it comprises the following steps:
[0023] (a) Fermenting the straw to obtain a fermentation mixture, specifically: collecting the straw, drying in the air, crushing to form fine particles with a particle size of about 3 cm, and then cooking for 2 hours; adding ligninase and fiber of the straw mass (dry weight) after cooling Sulfase (0.56CBU / g ligninase and 1FPU / g cellulase), placed in an airtight container and fermented at room temperature for 3 days to obtain a fermentation mixture;
[0024] (b) Take 1 kg of the fermentation mixture, then add 0.3 kg of sodium hydroxide and 22 g of carbon disulfide to it in sequence and react at 45° C. for 4 hours.
Embodiment 2
[0026] This embodiment provides a preparation method of ecological chelated straw fertilizer, the operation steps of which are basically the same as those in Example 1, the difference is: in step (b), before adding sodium hydroxide and carbon disulfide, the fermentation mixture is added Add organic amine to react. Specifically: take 1kg of fermentation mixture, add 16g of ethylenediamine to it, react at 90°C for 2.5 hours, then add 0.3kg of sodium hydroxide, 22g of carbon disulfide and react at 45°C for 4 hours.
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