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Preparation method of a flexible carbon nanotube-polyaniline thermoelectric device

A technology of carbon nanotubes and thermoelectric devices, which is applied in the manufacture/processing of thermoelectric devices, materials for lead-out wires of thermoelectric devices, etc., can solve the problems of poor folding performance, insufficient flexibility, limitations, etc., and achieve simple production process and preparation The effect of simple method and light weight

Inactive Publication Date: 2018-06-26
DONGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the existing polyaniline-carbon nanotube thermoelectric composites have insufficient flexibility and poor folding performance, which limits their applications as wearable and portable devices.

Method used

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  • Preparation method of a flexible carbon nanotube-polyaniline thermoelectric device
  • Preparation method of a flexible carbon nanotube-polyaniline thermoelectric device
  • Preparation method of a flexible carbon nanotube-polyaniline thermoelectric device

Examples

Experimental program
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Effect test

Embodiment 1

[0031] (1) Add 15mg of carbon nanotubes and 45mg of sodium dodecylbenzenesulfonate into 60mL of 1mol / L HCl solution, sonicate for 30min, treat with a cell pulverizer for 120min, add 15mg of aniline, sonicate for 30min, and proceed under ice bath Magnetic stirring;

[0032] (2) Add 45mg of ammonium persulfate to 5mL of 1mol / L HCl solution, stir evenly; add the ammonium persulfate solution into the syringe and inject it into the stirring (1) within 30min, and stir for 12h under ice bath, Obtain carbon nanotube-polyaniline composite solution;

[0033] (3) Put the polyester with a mass fraction of 5% into a sodium hydroxide solution and heat it in an oil bath at 75°C for 10 minutes, then put the polyester cloth piece into a 75°C aqueous solution and stir it magnetically for 10 minutes, take out the polyester and dry it and add it to the solution obtained in (2) solution, and sonicated for 2 hours, and then dried under vacuum at 60°C for 6 hours. Repeat the above steps 3 times; ...

Embodiment 2

[0037] (1) Add 15mg of carbon nanotubes and 45mg of sodium dodecylbenzenesulfonate into 60mL of 1mol / L HCl solution, sonicate for 30min, treat with a cell pulverizer for 120min, add 30mg of aniline, sonicate for 30min, and proceed under ice bath Magnetic stirring;

[0038] (2) Add 90 mg of ammonium persulfate to 10 mL of 1mol / L HCl solution, and stir evenly; add the ammonium persulfate solution into the syringe and inject it into the stirring (1) within 40 minutes, and stir for 12 hours under an ice bath to obtain Carbon nanotube-polyaniline composite solution;

[0039] (3) Put the polyester with a mass fraction of 5% into a sodium hydroxide solution and heat it in an oil bath at 75°C for 10 minutes, then put the polyester cloth piece into a 75°C aqueous solution and stir it magnetically for 10 minutes, take out the polyester and dry it and add it to the solution obtained in (2) solution, and sonicated for 2 hours, and then dried under vacuum at 60°C for 6 hours. Repeat the ...

Embodiment 3

[0042] (1) Add 15mg of carbon nanotubes and 45mg of sodium dodecylbenzenesulfonate into 60mL of 1mol / L HCl solution, sonicate for 30min, treat with a cell pulverizer for 120min, add 5mg of aniline, sonicate for 30min, and proceed under ice bath Magnetic stirring;

[0043] (2) Add 15 mg of ammonium persulfate to 3 mL of 1mol / L HCl solution, and stir evenly; add the ammonium persulfate solution into the syringe and inject it into the stirring (1) within 20 minutes, and stir for 12 hours in an ice bath to obtain Carbon nanotube-polyaniline composite solution;

[0044](3) Put the polyester with a mass fraction of 5% into the sodium hydroxide solution and heat it in an oil bath at 75°C for 10 minutes, then put the polyester cloth piece into the aqueous solution at 75°C and stir it magnetically for 10 minutes, take out the polyester and dry it and add it to the solution obtained in (2) solution, and sonicated for 2 hours, and then dried under vacuum at 60°C for 6 hours. Repeat the...

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Abstract

The invention relates to a method for preparing a flexible carbon nanotube-polyaniline thermoelectric device, comprising: adding carbon nanotubes and sodium dodecylbenzenesulfonate to HCl solution, ultrasonication, cell crushing, and then adding aniline, ultrasonication , stirred under ice-bath conditions to obtain a carbon nanotube-aniline dispersion, add dropwise the HCl solution of ammonium persulfate, and obtain a carbon nanotube-polyaniline dispersion after the reaction; the fabric is put into a sodium hydroxide solution and heated, and then put Stir in water at 60-90°C, take it out, dry it, add it to the carbon nanotube-polyaniline dispersion, ultrasonicate it, dry it, repeat the steps of fabric impregnation and drying; cut the dried polyester into rectangular strips , alternately fixed on the flexible substrate, and parallel connection of rectangular strips with conductive fibers, that is. The method of the invention is simple, and the prepared carbon nanotube-polyaniline composite thermoelectric fabric has the advantages of light weight, good flexibility and foldability, and can be assembled into a large-scale portable thermoelectric device.

Description

technical field [0001] The invention belongs to the field of preparation of thermoelectric devices, in particular to a preparation method of flexible carbon nanotube-polyaniline thermoelectric devices. Background technique [0002] Modern life makes people increasingly inseparable from wearable and portable devices such as watches, bracelets, hearing aids, and mobile phones. How to provide continuous energy supply for these devices is an urgent problem to be solved. Traditional dry battery energy supply is not permanent, needs to be replaced frequently, and is relatively bulky and cannot be bent and folded. Batteries are also bulky, inflexible, and prone to contamination. So people turned their attention to new energy sources, such as solar energy and thermoelectric energy. Compared with solar energy, thermoelectric devices use temperature differences to generate electricity, which is more in line with the concept of sustainable energy utilization. Although inorganic the...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L35/24H01L35/34H10N10/856H10N10/01
CPCH10N10/856H10N10/01
Inventor 李耀刚李朋王宏志张青红侯成义
Owner DONGHUA UNIV
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