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Silane modified polymer concrete mud inhibitor and preparation method thereof

A silane-modified polymer technology, which is applied in the field of silane-modified polymer concrete mud inhibitor and its preparation, can solve the problems of reducing the bonding strength between cement and aggregate, weak clay inhibition performance, and weak adsorption capacity. Achieve the effects of alleviating and improving negative effects, obvious adsorption and dispersion effects, and strong adsorption and dispersion capabilities

Active Publication Date: 2016-07-27
中建西部建设北方有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

First of all, when the soil content in sand and gravel is high, the water reducing rate of polycarboxylate superplasticizer will be greatly reduced, the fluidity of concrete will drop sharply, the slump loss will be rapid, and the transportable time will be greatly shortened, so it is difficult to guarantee Transportation, pumping and construction requirements for concrete
Secondly, when there is a lot of soil in the aggregate sandstone, it will also reduce the bond strength between the cement and the aggregate, which will adversely affect the properties of concrete such as compression resistance, shrinkage, flexural resistance, and wear resistance.
Patent CN102358763A proposes a method for preparing an admixture for suppressing the side effects of clay. This admixture reduces the adsorption of clay to polycarboxylate superplasticizer through competitive adsorption, and has a certain inhibitory effect on clay, but its interaction with clay The mode of action is electrostatic adsorption. This kind of physical adsorption by electrostatic action has its limitations in universality and stability. The adsorption capacity is weak, and the adsorption on the soil is not firm, so the inhibitory performance on clay is not strong. limited effect

Method used

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  • Silane modified polymer concrete mud inhibitor and preparation method thereof
  • Silane modified polymer concrete mud inhibitor and preparation method thereof
  • Silane modified polymer concrete mud inhibitor and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041]The method for preparing silane-modified polymer concrete mud inhibitor in the present embodiment comprises the following steps:

[0042] Step 1: in the reactor with reflux and stirring device, the allyltrimethoxysilane of 1 mass part and the allyl sodium sulfonate of 1.5 mass parts are dissolved in deionized water by 45 mass parts and 70 In a mixed solution composed of isopropanol in parts by mass, stir and dissolve to obtain a base solution, and raise the temperature of the base solution to 70°C; in a reactor with a reflux and stirring device, dissolve 33 parts by mass of acrylic acid in 9 parts by mass of deionized water were stirred and dissolved to obtain an acrylic acid solution; in a reactor with a reflux and stirring device, 2.1 parts by mass of ammonium persulfate was dissolved in 14 parts by mass of deionized water, stirred and dissolved to prepare Obtain ammonium persulfate solution;

[0043] Step 2: Keep the temperature of the basic solution at 70°C, and add...

Embodiment 2

[0046] The method for preparing silane-modified polymer concrete mud inhibitor in the present embodiment comprises the following steps:

[0047] Step 1: In a reactor with a reflux and stirring device, dissolve 1.5 parts by mass of allyltriethoxysilane and 2.5 parts by mass of sodium methallyl sulfonate in 49 parts by mass of deionized In a mixed solution composed of water and 80 parts by mass of isopropanol, stir and dissolve to obtain a base solution, and adjust the temperature of the base solution to 75°C; in a reactor with a reflux and stirring device, 33.8 parts by mass of Dissolve methacrylic acid in 10 parts by mass of deionized water, stir and dissolve to obtain a methacrylic acid solution; in a reactor with a reflux and stirring device, dissolve 2.5 parts by mass of potassium persulfate in 15 parts by mass of deionized water In deionized water, stir and dissolve to obtain potassium persulfate solution;

[0048] Step 2: Keep the temperature of the basic solution at 75°...

Embodiment 3

[0051] The method for preparing silane-modified polymer concrete mud inhibitor in the present embodiment comprises the following steps:

[0052] Step 1: in the reactor with reflux and stirring device, the allyltrimethoxysilane of 2 mass parts and the allyl sodium sulfonate of 3.5 mass parts are dissolved in the deionized water by 52 mass parts and 90 In a mixed solution composed of isopropanol in parts by mass, stir and dissolve to obtain a base solution, and adjust the temperature of the base solution to 80°C; in a reactor with a reflux and stirring device, dissolve 34.5 parts by mass of acrylic acid in 10 parts by mass of deionized water were stirred and dissolved to obtain an acrylic acid solution; in a reactor with a reflux and stirring device, 2.8 parts by mass of ammonium persulfate was dissolved in 15 parts by mass of deionized water, stirred and dissolved to prepare Obtain ammonium persulfate solution;

[0053] Step 2: Keep the temperature of the basic solution at 80°...

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Abstract

The invention provides a silane modified polymer concrete mud inhibitor and a preparation method thereof. The prepared silane modified polymer concrete mud inhibitor is a low-molecular-weight linear copolymer and can chemically adsorb mud by virtue of chemical bonding, the mud adsorbing capacity is high, the absorption is firm, and a certain dispersive action is further applied to mud after the absorption, so that the flowing property of a concrete system is improved; by being compound with a polycarboxylate water reducer in use, the silane modified polymer concrete mud inhibitor has a strong competitive adsorption advantage, the absorption of mud to the polycarboxylate water reducer can be obviously reduced, and adverse effects caused by mud in concrete can be effectively relieved.

Description

technical field [0001] The invention relates to the technical field of preparation and application of high-performance concrete admixtures, in particular to a silane-modified polymer concrete mud inhibitor capable of effectively alleviating the negative impact of soil on concrete and a preparation method thereof. Background technique [0002] Due to the rapid development of the concrete industry, the consumption of raw materials is increasing day by day, high-quality sand and gravel are seriously in short supply, and there are more and more inferior sand and gravel with high mud content. affect the performance of concrete. First of all, when the soil content in sand and gravel is high, the water reducing rate of polycarboxylate superplasticizer will be greatly reduced, the fluidity of concrete will drop sharply, the slump loss will be rapid, and the transportable time will be greatly shortened, so it is difficult to guarantee Transportation, pumping and construction require...

Claims

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Application Information

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IPC IPC(8): C04B24/42C04B22/06C04B22/14C04B24/02C04B24/04C04B24/16
CPCC04B40/0039C04B24/42C04B24/16C04B24/02C04B24/04C04B22/147C04B22/062
Inventor 孟刚刘磊张凯峰刘行宇赵世冉刘博博邓天明耿飞姚源李文龙
Owner 中建西部建设北方有限公司
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