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A kind of liquid crystal polyester and its molding composition and its application

A molding composition, liquid crystal polyester technology, applied in liquid crystal materials, chemical instruments and methods, etc., can solve problems affecting the application of liquid crystal polymers, mold filling dissatisfaction, resin fluidity, etc.

Active Publication Date: 2017-05-31
KINGFA SCI & TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Its preparation usually adopts the high-temperature melt polymerization method, but due to the self-polymerization of monomers such as HBA and HNA or the branched cross-linking reaction of the molecular chain, the melt processability and physical properties of the final liquid crystal product are poor, especially the resin The fluidity of the liquid crystal polymer is seriously affected, which leads to the mold filling dissatisfaction during the molding process of the liquid crystal polyester molding composition, which seriously affects the application of liquid crystal polymers in thin-walled parts of electronic appliances.

Method used

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  • A kind of liquid crystal polyester and its molding composition and its application
  • A kind of liquid crystal polyester and its molding composition and its application
  • A kind of liquid crystal polyester and its molding composition and its application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0066] Add the following monomer raw materials, acylating agent and catalyst to the polymerization reaction device equipped with agitator, reflux condenser, monomer feeding port, nitrogen inlet, thermometer and torque sensor.

[0067] (I) p-Hydroxybenzoic acid 1298.4 g (47 mol %) HBA

[0068] (Ⅱ) 6-hydroxy-2-naphthoic acid 112.9 g (3mol%) HNA

[0069] (Ⅲ) Terephthalic acid 731g (22mol%) TA

[0070] (IV) 99.7 g (3 mol%) IA of isophthalic acid

[0071] (Ⅴ) 4,4'-biphenol 931.1 g (25mol %) BP

[0072] Acylating agent: acetic anhydride 2041 g

[0073] Catalyst: Magnesium acetate 103 mg

[0074] After the feeding is completed, completely replace the atmosphere in the reaction vessel with nitrogen, raise the temperature of the reaction system to 140°C under the protection of nitrogen, and keep the nitrogen pressure at 0.2MPa, and maintain this temperature for 2 hours to carry out the acylation reaction; After the reaction is over, turn on the vacuum pump to reduce the pressure i...

Embodiment 2-5

[0075] Embodiment 2-5: according to the formula of table 1, after the acylation reaction finishes, open vacuum pump and the pressure in the reactor is decompressed to 10KPa-30KPa, discharge acetic acid and unreacted acetic anhydride molecule rapidly from the rectifying column, to meet the rapid The process of heating requires that when the amount of acetic acid received reaches more than 50% of the theoretical value, the temperature should be raised rapidly to 210°C, the reduced pressure condition should be maintained and the temperature of the reaction system should be raised to the highest temperature of 370°C within 6 hours, during which the acetic acid, especially Phenol and other by-product small molecules that cause molecular chain rearrangement and branching are then decompressed to 60KPa in 30 minutes; the rest are the same as in Example 1; the melting point, melt viscosity, and storage modulus release rate of the liquid crystal polyester are rod-shaped Fluid lengths ar...

Embodiment 6-12

[0076] Embodiment 6-12: according to the formula of table 1, after the acylation reaction finishes, open vacuum pump and the pressure in the reactor is decompressed to 10KPa-30KPa, discharge acetic acid and unreacted acetic anhydride molecule rapidly from the rectifying column, in order to satisfy rapidly The process of heating requires that when the amount of acetic acid received reaches more than 50% of the theoretical value, the temperature should be raised rapidly to 220°C, the reduced pressure condition should be maintained and the temperature of the reaction system should be raised to the highest temperature of 380°C within 6 hours, during which the acetic acid, especially Phenol and other by-product small molecules that cause molecular chain rearrangement and branching are then decompressed to 70KPa in 30 minutes; the rest are the same as in Example 1; the melting point, melt viscosity, and storage modulus release rate of the liquid crystal polyester are rod-shaped Fluid...

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Abstract

Disclosed are a liquid crystal polyester, a moulding composition consisting thereof and a use thereof, composed of repeating structural units of formulae [I]-[V], wherein dynamic thermo-mechanical analysis (DMA) is used for testing, and the liquid crystal polyester satisfies: the storage modulus release rate ΔG, as defined in following formula (1), is greater than or equal to 95.0% to less than or equal to 99.4%. (1) ΔG＝[G(-50)-G(melting point)] / G(-50)*100%. The DMA storage modulus release rate ΔG of the liquid crystal polyester of the present invention is greater than or equal to 95.0% to less than or equal to 99.4%. The liquid crystal polyester and the moulding composition prepared from the liquid crystal polyester have a relatively high fluidity, an excellent melting property, and a high moulding stability for small-size thin-walled mouldings, and are particularly suitable for applying to thin-walled electric pieces.

Description

technical field [0001] The invention relates to the field of polymer materials, in particular to a liquid crystal polyester, a molding composition composed of it and its application. Background technique [0002] As a high-performance special engineering plastic, thermotropic liquid crystal polymer (TLCP) has excellent mechanical properties, good fluidity, heat resistance, chemical corrosion resistance, flame retardancy and electrical insulation properties. It is currently used in electronic appliances and small It is widely used in precision thin-walled parts and other fields. Its preparation usually adopts the high-temperature melt polymerization method, but due to the self-polymerization of monomers such as HBA and HNA or the branched cross-linking reaction of the molecular chain, the melt processability and physical properties of the final liquid crystal product are poor, especially the resin The fluidity of the liquid crystal polymer is seriously affected, resulting in...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G63/60C08G63/80C08L67/04C08K13/04C08K7/14C09K19/38
CPCC08G63/60C08G63/80C08K7/14C08K13/04C08L67/04
Inventor 孙华伟李闻达肖中鹏宋彩飞罗德彬许柏荣易庆锋周广亮姜苏俊曹民曾祥斌蔡彤旻
Owner KINGFA SCI & TECH CO LTD