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Adhesive sheet and optical member

A technology for optical components and adhesive sheets, applied in the direction of film/sheet-like adhesives, adhesives, etc., can solve the problems of inability to pick up, peel off and become heavy, polarizing plate or liquid crystal cell damage, etc., to achieve manufacturing efficiency, flexibility and flexibility. Curvature improvement, improved breakage or deformation

Active Publication Date: 2020-05-22
NITTO DENKO CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The surface protection film is peeled off when it is no longer needed, but with the increase in size and thickness of the liquid crystal display panel, damage to the polarizing plate or liquid crystal cell is likely to occur in the peeling process, so it is required to have a protective film that does not cause damage during peeling. Moderate adhesive force such as warping, and requires light peelability, pick-up, etc. to enable re-peeling
In particular, with the thinning of displays in recent years, the optical members constituting the displays have also become thinner. For optical members with a thickness of 150 μm or less, the optical members are deflected during the transportation process, which makes it impossible to transport, or the optical members cannot be transported. Problem of Sufficient Adhesion with Other Members (Patent Document 2)
In order to avoid these problems, deflection is suppressed by thickening the base material constituting the surface protection film, but the peeling becomes heavier when the thickness is increased, so when the surface protection film is no longer needed when the surface protection film is peeled off with a pick-up tape, it may not be possible. bad condition picked up

Method used

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  • Adhesive sheet and optical member
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  • Adhesive sheet and optical member

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0175]

[0176] Polyester-based films (manufactured by Teijin Corporation, "TR-8550T1", polyethylene terephthalate (PET)) as the first and third resin layers, and polyethylene-based films as the second resin layer Resin (manufactured by Nippon Polyethylene Co., Ltd., "Novatec LL UE320", low-density polyethylene (PE)) was supplied to three extruders respectively, and co-extruded so that the first resin layer / second resin layer / third resin The thickness ratio of the layers was 25:30:25, thereby forming a three-layer coextruded multilayer film (resin layer film) having a thickness of 80 μm. In addition, the resin layer film was prepared similarly to Example 1 based on the structure of Table 5 about the resin layer film in other Example and a comparative example.

[0177]

[0178] The acrylic polymer solution (A) (40% by mass) was diluted to 20% by mass with ethyl acetate, and hexamethylene as a crosslinking agent was added to 500 parts by mass of the solution (100 parts by mas...

Embodiment 2

[0182]

[0183] The acrylic polymer solution (A) (40% by mass) was diluted to 20% by mass with ethyl acetate, and organopolysiloxane was added to 500 parts by mass of the solution (100 parts by mass of solid content). Alkanes (manufactured by Shin-Etsu Silicone Co., Ltd., trade name: KF-353) diluted to 10% solution 2 parts by mass (solid content 0.2 parts by mass), bis(trifluoromethane as an ionic compound) with ethyl acetate Lithium sulfonyl)imide (manufactured by Tokyo Chemical Industry Co., Ltd., trade name: LiTFSI) diluted to 10% solution 1.5 parts by mass (solid content 0.15 parts by mass), hexamethylene diisocyanate as a crosslinking agent Cyanurate form (manufactured by Nippon Polyurethane Industry Co., Ltd., trade name Coronate HX (C / HX)) 3.5 parts by mass (solid content: 3.5 parts by mass) and polyisocyanate modified form (manufactured by Mitsui Chemicals, trade name: TAKENATE 600) 0.3 parts by mass (solid content: 0.3 parts by mass), 1 mass of iron(III) acetylaceto...

Embodiment 3

[0187]

[0188] The acrylic polymer solution (B) (40% by mass) was diluted to 20% by mass with ethyl acetate, and polyethylene oxide was added as a surfactant to 500 parts by mass (solid content: 100 parts by mass) of the solution. Nonylpropenylphenyl ether ammonium sulfate (manufactured by Daiichi Kogyo Pharmaceutical Co., Ltd., trade name: Aqualon HS-10) was diluted to 10% with ethyl acetate to obtain 3 parts by mass of a solution (0.3 parts by mass of solid content), as The isocyanurate form of hexamethylene diisocyanate (manufactured by Nippon Polyurethane Industry Co., Ltd., trade name Coronate HX (C / HX)) 5 parts by mass (solid content 5 parts by mass) of the hexamethylene diisocyanate of the linking agent, diisocyanurate as a crosslinking catalyst 2 mass parts (0.02 mass parts of solid content) of dibutyltin laurate (1 mass % ethyl acetate solution) were mixed and stirred, and an acrylic adhesive solution (F) was prepared.

[0189]

[0190] The acrylic adhesive solut...

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Abstract

The invention relates to an adhesive sheet and an optical member. The provided adhesive sheet can be easily fetched, and the optical member is protected by the adhesive sheet. The adhesive sheet comprises the following layers in sequence: a first resin layer, a second resin layer, a third resin layer, and an adhesive layer made of an adhesive composition; and is characterized in that then tensile strength of the first resin layer and the third resin layer is 180 MPa or more, the tensile strength of the second resin layer is less than 150 MPa, the ratio of the thickness of the second resin layer to the total thickness of the first resin layer and the third resin layer is 10 or less; the primary peeling force of the adhesive sheet is 6 N / 25 mm or less when the adhesive sheet is peeled off from a triacetyl cellulose film in an angle of 180 degrees at a temperature of 23 DEG C under a condition of 50% RH; the adhesive sheet can be cut into sheets with a width of 20 mm and a length of 150 mm; and the difference of H1 and H2 (deflection amount) is less than 35 mm, wherein the H1 represents the central height when the end portion is fixed on a glass plate by a tape when the adhesive surface is outward and the H2 represent the height when a load of 4.8 grams is arranged on the center position.

Description

technical field [0001] The present invention relates to an adhesive sheet and an optical member. [0002] The adhesive sheet of the present invention is used to protect polarizing plates, wavelength plates, phase difference plates, optical compensation films, reflection sheets, brightness enhancement films, protective glasses, It is useful as a surface protection film used for the surface of an optical member such as a shield, a hard coat film, a transparent conductive glass, and a transparent conductive film. Background technique [0003] In recent years, when optical components and electronic components are transported or mounted on printed circuit boards, each component is transferred in a state packaged with a predetermined sheet or in a state attached with an adhesive tape. Among them, the surface protection film is particularly widely used in the fields of optical and electronic components. [0004] A surface protection film is generally bonded to an adherend via an ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J7/29
CPCC09J7/29C09J2203/318C09J2423/00C09J2427/00C09J2467/006C09J2469/00
Inventor 渡部奈津子天野立巳三井数马
Owner NITTO DENKO CORP