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Curing agent of phosphate bonding agent self-hardening sand and preparation and using methods of curing agent of phosphate bonding agent self-hardening sand

A curing agent and binder technology, applied in the direction of manufacturing tools, casting molding equipment, metal processing equipment, etc., can solve the problems of poor moisture absorption resistance, achieve good collapsibility, and improve the effect of pollution

Active Publication Date: 2016-08-17
辽宁谱瑞科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The present invention provides a curing agent for phosphate binder self-setting sand and its preparation method and use method, and its purpose is to develop a liquid curing agent To replace powdery alkaline oxide and alkaline hydroxide, improve the dust pollution caused by powdery curing agent; solve the technical problem of poor moisture absorption resistance existing in the heating and hardening process of phosphate binder sand

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] The weight ratio of each component in the curing agent of this embodiment is: component I aniline is 20% of the weight of the binder, and component II is 10% of the weight of the binder. Wherein the weight percentage of each component in component II is: 43% of urea, 40% of water, 5% of ammonium chloride, 4% of silane, and 8% of tetraethylenepentamine.

[0024] The preparation method of component II:

[0025] Step 1: first add 40Kg of water to the reactor, and raise the temperature to 70°C;

[0026] Step 2: Start the agitator to start stirring, add 43Kg of urea into the reaction kettle, at this time the temperature will drop, after all dissolve, heat up to 75°C again;

[0027] Step 3: Slowly add 5Kg of ammonium chloride to the reaction kettle, and keep warm at 70°C until completely dissolved;

[0028] Step 4: Cool down to room temperature, add 8Kg of tetraethylenepentamine and 4Kg of silane, stir for 20 minutes after the dissolution is complete, and discharge.

[002...

Embodiment 2

[0031] The weight ratio of each component in the curing agent in this embodiment is: component I aniline is 20% of the weight of the binder, and component II is 20% of the weight of the binder. Wherein the weight percentage of each component in component II is: 30% of urea, 34% of water, 15% of ammonium chloride, 6% of silane, and 15% of tetraethylenepentamine.

[0032] The preparation method of component II:

[0033] Step 1: First add 34Kg of water to the reactor, and raise the temperature to 70°C;

[0034] Step 2: Start the agitator to start stirring, add 30Kg of urea into the reaction kettle, at this time the temperature will drop, after all dissolve, heat up to 75°C again;

[0035] Step 3: Slowly add 15Kg of ammonium chloride to the reaction kettle, and keep warm at 70°C until completely dissolved;

[0036] Step 4: Cool down to room temperature, add 15Kg of tetraethylenepentamine and 6Kg of silane, stir for 30 minutes after the dissolution is complete, and discharge.

...

Embodiment 3

[0039] The weight ratio of each component in the curing agent of this embodiment is: component I aniline is 10% of the weight of the binder, and component II is 10% of the weight of the binder. Wherein the weight percentage of each component in component II is: urea 25%, water 40%, ammonium chloride 20%, silane 1%, tetraethylenepentamine 14%.

[0040] The preparation method of component II:

[0041] Step 1: first add 40Kg of water to the reactor, and raise the temperature to 50°C;

[0042] Step 2: Start the agitator to start stirring, add 25Kg of urea into the reaction kettle, the temperature will drop at this time, after all dissolve, heat up to 70°C again;

[0043] Step 3: Slowly add 20Kg of ammonium chloride into the reaction kettle, keep warm at 60°C until completely dissolved;

[0044] Step 4: Cool down to room temperature, add 14Kg of tetraethylenepentamine and 1Kg of silane, stir for 15 minutes after the solution is transparent, and discharge.

[0045] The core-makin...

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PUM

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Abstract

The invention provides a curing agent of phosphate bonding agent self-hardening sand. The curing agent of the phosphate bonding agent self-hardening sand can be applied to modeling and core making. Phosphate is a phosphate bonding agent which takes aluminium dihydrogen phosphate as a main ingredient. The curing agent comprises two components including a component I and a component II, wherein the component I is phenylamine; the component II consists of urea, water, ammonium chloride, silane and tetraethylenepentamine; and the hardening speed of a sand sample is adjusted by adjusting the addition of the two components. A using method of the curing agent comprises the following specific process steps: mixing the curing agent and crude sand at first; then adding the phosphate bonding agent and mixing uniformly to discharge sand; and pouring the mixture into a mold, compacting and preparing the sample, wherein the sand sample can be self-hardened at room temperature. The tensile strength of the prepared sand sample is greater than or equal to 1.0 MPa after 24 hours, and moreover, the sand sample is good in anti-moisture-absorption performance and collapsibility. The curing agent is simple in preparation process and stable in chemical property, and has good application prospect. The self-hardening process involved in the invention facilitates solving the technical problem of poor anti-moisture-absorption performance of the traditional hot and hard phosphate sand core and the technical problems of difficulty in quantifying in the self-hardening process and easiness in generation of dust during sand mixing.

Description

technical field [0001] The invention relates to the field of molding (core-making) materials in the foundry industry, in particular to a liquid solidifying agent for phosphate self-hardening sand used in foundry and a preparation and use method thereof. Background technique [0002] Phosphate binder sand for foundry has the advantages of high high temperature strength, small high temperature deformation, low gas generation, good collapsibility, etc. It is a valuable molding and core making material. Phosphate binder can be hardened by heating, and the sand core produced has high initial strength and is easy to absorb moisture. The strength drops seriously under high ambient humidity, which affects its use in foundry production; while no-bake sand technology, mold 1. The core does not need to be baked, and can be hardened and formed at room temperature, which not only saves energy, but also helps to improve labor production efficiency and reduce production costs. At present,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B22C1/18
CPCB22C1/185
Inventor 刘伟华宋来李英民
Owner 辽宁谱瑞科技有限公司
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