A kind of fluorocarbon ink and preparation method and a kind of fluorocarbon ink transfer film

A fluorocarbon and ink technology, applied in the directions of reproduction/marking method, ink, printing, etc., can solve the problems of uneven anti-corrosion effect, corrosion and discoloration of plates, waste of artificial energy, etc., to improve the effect of pigment dispersion and arrangement, and enhance solvent resistance. Aggressive, productivity-enhancing effects

Active Publication Date: 2019-07-12
DONGGUAN ZHUOYI PRINTING PROD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, the inks used in various transfer films on the market are non-weather-resistant self-drying inks. After transferring to the board, fluorocarbon varnish is applied on the surface as a protective layer, and the corners need to be waterproofed. A lot of anti-corrosion work has caused a lot of material loss, and waste of labor and energy
Moreover, even if a lot of anti-corrosion work has been done, the anti-corrosion effect is still uneven. It takes a long time to detect anti-corrosion. It is often several months before the user finds problems such as corrosion and discoloration of the plate, which brings huge economic losses to the user.
[0003] The invention patent with the patent application number 201510268713.0 discloses a weather-resistant ink, which uses a blend system of acrylic resin and fluorocarbon resin to achieve high weather resistance of the ink and highly uniform dispersion of the pigment, and is more suitable for use on polyester substrates in terms of performance. In the effect example of this patent, after coating the ink layer, it is necessary to coat a layer of high weather-resistant transparent varnish on the ink layer for protection, which still cannot get rid of the anti-corrosion work of coating the protective varnish

Method used

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  • A kind of fluorocarbon ink and preparation method and a kind of fluorocarbon ink transfer film
  • A kind of fluorocarbon ink and preparation method and a kind of fluorocarbon ink transfer film

Examples

Experimental program
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Effect test

Embodiment 1

[0043] A fluorocarbon ink transfer film is composed of a base film layer 1, an attached release layer 2, a fluorocarbon ink pattern layer 3, and an adhesive layer 4 that are stacked in sequence, and the fluorocarbon ink pattern layer 3 passes through the attached The release layer 2 is formed by printing fluorocarbon ink.

[0044] Described fluorocarbon ink comprises the raw material of following parts by weight:

[0045] Acrylic resin 19 parts

[0046] Fluorocarbon resin 29 parts

[0047] CAB resin emulsion 5.5 parts

[0048] Curing agent 1.5 parts

[0049] Pigment 17.5 parts

[0050] Dispersant 0.75 parts

[0051] Matte powder 0.75 parts

[0052]26 parts of organic solvents.

[0053] Wherein, the acrylic resin is Rohm and Haas B-44, the fluorocarbon resin is Arkema 460, the CAB resin content of the CAB resin emulsion is 15-25wt%, and the CAB resin is Eastman CAB- 381-0.5, the curing agent is 3175 of Bayer, the pigment is titanium dioxide, the dispersant is Lubrizol 8...

Embodiment 2

[0055] A fluorocarbon ink transfer film is composed of a base film layer 1, an attached release layer 2, a fluorocarbon ink pattern layer 3, and an adhesive layer 4 that are stacked in sequence, and the fluorocarbon ink pattern layer 3 passes through the attached The release layer 2 is formed by printing fluorocarbon ink.

[0056] Described fluorocarbon ink comprises the raw material of following parts by weight:

[0057] 18 parts acrylic resin

[0058] Fluorocarbon resin 28 parts

[0059] CAB resin emulsion 5 parts

[0060] Curing agent 1 part

[0061] Pigment 15 parts

[0062] Dispersant 0.5 parts

[0063] Matte powder 0.5 parts

[0064] 20 parts of organic solvent.

[0065] Wherein, the acrylic resin is Rohm and Haas B-44, the fluorocarbon resin is Arkema 460, the CAB resin content of the CAB resin emulsion is 15wt%, and the acetyl group content of the CAB resin is 10wt%, The butyryl content is 40wt%, the hydroxyl content is 1wt%, the curing agent is Bayer's 3175, t...

Embodiment 3

[0067] A fluorocarbon ink transfer film is composed of a base film layer 1, an attached release layer 2, a fluorocarbon ink pattern layer 3, and an adhesive layer 4 that are stacked in sequence, and the fluorocarbon ink pattern layer 3 passes through the attached The release layer 2 is formed by printing fluorocarbon ink.

[0068] Described fluorocarbon ink comprises the raw material of following parts by weight:

[0069] 20 parts acrylic resin

[0070] Fluorocarbon resin 30 parts

[0071] CAB resin emulsion 6 parts

[0072] Hardener 2 parts

[0073] Pigment 20 parts

[0074] 1 part dispersant

[0075] matte powder 1 part

[0076] 32 parts of organic solvents.

[0077] Wherein, the acrylic resin is Rohm and Haas B-44, the fluorocarbon resin is Arkema 460, the CAB resin content of the CAB resin emulsion is 25wt%, and the acetyl group content of the CAB resin is 15wt%, The butyryl content is 35wt%, the hydroxyl content is 2wt%, the curing agent is Bayer's 3175, the pigme...

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Abstract

The invention relates to the field of industrial coatings, in particular to fluorocarbon ink, a preparation method and a fluorocarbon ink transfer film. The fluorocarbon ink comprises raw materials in parts by weight as follows: 18-20 parts of acrylic resin, 28-30 parts of fluorocarbon resin, 5-6 parts of CAB resin emulsion, 0-2 parts of a curing agent, 15-20 parts of pigment, 0-1 part of a dispersing agent, 0-1 part of matt powder, and 20-32 parts of organic solvent. The fluorocarbon resin is at least one of PVDF resin and FEVE resin. The invention also provides the fluorocarbon ink transfer film comprising a base film layer, an attached release layer, a fluorocarbon ink pattern layer and a back gluing layer which are sequentially overlapped, wherein the fluorocarbon ink pattern layer is formed by printing the fluorocarbon ink on the attached release layer. The hardness of a fluorocarbon ink coating is 1.5-2 H, the adhesive force is higher than level 1, the coating has no obvious changes at least for 1000 h in neutral salt fog, and delta E is smaller than or equal to 3.0 in a weather resistance test.

Description

technical field [0001] The invention relates to the field of industrial coatings, in particular to a fluorocarbon ink, a preparation method and a fluorocarbon ink transfer film. Background technique [0002] At present, the inks used in various transfer films on the market are non-weather-resistant self-drying inks. After transferring to the board, fluorocarbon varnish is applied on the surface as a protective layer, and the corners need to be waterproofed. A lot of anti-corrosion work has caused a lot of material loss, as well as a waste of labor and energy. Moreover, even if a lot of anti-corrosion work has been done, the anti-corrosion effect is uneven. It takes a long time to detect anti-corrosion, and users often find problems such as corrosion and discoloration of the plates after several months, which has brought huge economic losses to users. [0003] The invention patent with the patent application number 201510268713.0 discloses a weather-resistant ink, which uses...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D11/106C09D11/107C09D11/03B32B7/06B41M5/382
CPCB32B7/06B41M5/382C09D11/03C09D11/106C09D11/107
Inventor 黎国忠刘炳全
Owner DONGGUAN ZHUOYI PRINTING PROD
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