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Multilayer stretch blow molded container and multilayer preform

A technology of stretch blow molding and pre-products, which is applied in the direction of containers, rigid containers, layered products, etc., can solve the problems of damaging the excellent transparency of polyester resins, achieve excellent mechanical strength, and prevent interlayer peeling effects

Inactive Publication Date: 2016-09-07
TOYO SEIKAN GRP HLDG LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, when a blend of a polyester resin and a polyamide resin, especially an aromatic polyamide resin such as polym-xylylene adipamide (MXD6), which has particularly excellent gas barrier properties among polyamide resins, is When the resin composition is used as an intermediate layer, the problem of impairing the excellent transparency possessed by polyester resin occurs

Method used

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  • Multilayer stretch blow molded container and multilayer preform
  • Multilayer stretch blow molded container and multilayer preform
  • Multilayer stretch blow molded container and multilayer preform

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0166]By using a co-injection molding machine, a multilayer preform of two kinds of three-layer constitution (PET / middle layer / PET) was molded. Dried PET1 was put into the hopper of the injection molding machine for forming the inner and outer PET layers, and dried APET1 and PA1 blended at a weight ratio of 70:30 were put into the hopper of the injection molding machine for forming the intermediate layer, and These materials were co-injection molded. While the intermediate layer was formed at a temperature of 260°C, the inner and outer PET layers were set at a temperature of 290°C. The weight of the preform was 24 g and the proportion of the intermediate layer was 6% by weight of the whole bottle. The preform is shaped such that the intermediate layer does not reach the mouth / neck nor the bottom.

[0167] Next, the multi-layer preform is biaxially stretched and blow-molded into a multi-layer bottle by the above-mentioned method. With regard to the obtained preform and bottl...

Embodiment 2

[0170] Except that the dry blend of APET1, PET1 and PA1 with a weight ratio of 52.5:17.5:30 was put into the hopper of the injection molding machine for forming the intermediate layer, and the intermediate layer was molded at a temperature of 280° C., the same method as in Example 1 Preforms and bottles were prepared and measured in the same manner.

[0171] In addition, a biaxially stretched sheet was prepared and measured in the same manner as in Example 1, except that a dry blend of APET1 and PET1 in a weight ratio of 3:1 was supplied to the hopper of the injection molding machine.

Embodiment 3

[0173] Except that the dry blend of APET1, PET1 and PA1 with a weight ratio of 35:35:30 was put into the hopper of the injection molding machine for forming the intermediate layer, and the intermediate layer was molded at a temperature of 280° C., in the same manner as in Example 1 Prepare and measure preforms and bottles in the same manner.

[0174] In addition, a biaxially stretched sheet was prepared and measured in the same manner as in Example 1 except that a dry blend of APET1 and PET1 in a weight ratio of 1:1 was supplied to the hopper of the injection molding machine.

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Abstract

The present invention relates to a multilayer stretch blow molded container which is obtained by biaxially stretch blow molding a multilayer preform that comprises inner and outer layers formed of an ethylene terephthalate polyester resin and at least one intermediate layer that is formed of at least a low-crystallinity ethylene terephthalate polyester resin and a gas-barrier aromatic polyamide resin. Since the refractive index difference ([delta]RI) between the low-crystallinity ethylene terephthalate polyester resin and the gas-barrier aromatic polyamide resin represented by the formula below is 0.03 or less, the multilayer stretch blow molded container has excellent gas barrier properties and interlayer adhesion, while having excellent transparency, namely a haze of 3% or less, in the barrel part. [delta]RI = |RIE - RIA| (In the formula, RIE and RIA represent the respective refractive indexes of injection molded plates, which are respectively formed of the low-crystallinity ethylene terephthalate polyester resin and the gas-barrier aromatic polyamide resin, after simultaneous biaxial stretching of 3*3 times.

Description

technical field [0001] The present invention relates to multilayer stretch blow molded containers comprising polyester resins and multilayer preforms capable of being formed into such containers. More specifically, the present invention relates to a multilayer stretch blow molded container excellent in gas barrier properties, interlayer adhesion, and transparency, and a container capable of making the position of an intermediate layer visible and exhibiting excellent transparency after stretch molding Multi-layer prefab. Background technique [0002] Polyester resins represented by polyethylene terephthalate have excellent properties such as formability, transparency, mechanical strength, and chemical resistance, and thus, have been widely used in the field of packaging containers. In order to improve the gas barrier properties of containers containing polyester resins against gases such as oxygen, it has been proposed to form a saponification product of ethylene-vinyl acet...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B29C49/22B29C49/08B65D1/00B65D1/02B32B1/00
CPCB29C49/08B29K2995/0067B29K2995/0069B32B27/08B32B27/34B32B27/36B32B2250/05B32B2250/24B32B2250/40B32B2250/44B32B2307/412B32B2307/518B32B2307/7244B32B2439/60B32B2439/70B65D1/0215B29C2949/3016B29C2949/3036B29C2949/3032B32B1/00B29C49/22B29C49/0005B29K2067/003B29K2077/00B29C49/12B29K2995/0026B29L2031/7158
Inventor 平山由纪子山田俊树长浜英昭
Owner TOYO SEIKAN GRP HLDG LTD