Lophobic or oleophobic micro-nano composite structure and preparation method thereof
A composite structure, micro-nano technology, applied in the direction of metal material coating technology, etc., can solve the problems of low production and low cost
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[0033] Such as Figure 7 As shown, a method for preparing a hydrophobic or oleophobic micro-nano composite structure of the present invention comprises the following steps:
[0034] Step 1, configuring an antiformin solution with a VF (volume fraction) of 5% to 40%, wherein VF is defined as the volume of the antiformin liquid / (volume of the antiformin liquid+volume of deionized water) ;
[0035] Step 2, put the copper base into the antiformin solution in step 1, and react at room temperature for 0.083 to 30 minutes;
[0036] Step 3. Take out the copper base after step 2, rinse it with deionized water and absolute ethanol successively, and then quickly dry it with a hair dryer at a temperature of 70°C to obtain a one-dimensional nano-bean sprout line structure with copper oxide on the surface and Copper base of copper oxide three-dimensional network structure;
[0037] Step 4, such as Figure 4 As shown in (a), adopt stearic acid solution to directly soak the copper base af...
Embodiment 1
[0043] (1) preparing an antiformin solution with a volume fraction VF of 40% as an oxidizing agent and stirring evenly;
[0044](2) Put the red copper sheet into the antiformin diluent at an angle, and the reaction time at room temperature is 10s.
[0045] (3) After the above reaction is completed, the sample is taken out, rinsed with deionized water and absolute ethanol successively, and dried quickly with a hair dryer at a drying temperature of about 70°C. That is, a copper oxide micro-nano composite morphology with a one-dimensional line structure is obtained on the copper surface (morphology such as image 3 As shown in (b), the diffraction effect is as figure 2 (b)).
[0046] (4) Dissolve stearic acid solid powder in absolute ethanol, and ultrasonically oscillate until completely dissolved, and the concentration of stearic acid is 0.03mol / L. Place the red copper sheet after (3) obliquely in the ethanol solution of stearic acid for 15 minutes, remove the red copper she...
Embodiment 2
[0049] (1) Prepare an antiformin solution with a volume fraction VF of 40% as an oxidizing agent and stir evenly.
[0050] (2) Put the red copper sheet into the antiformin diluent at an angle, and the reaction time is 1 min at room temperature.
[0051] (3) After the above reaction is completed, the sample is taken out, rinsed with deionized water and absolute ethanol successively, and dried quickly with a hair dryer at a drying temperature of about 70°C. That is, a copper oxide micro-nano composite morphology with a three-dimensional network structure is obtained on the copper surface (morphology such as image 3 As shown in (c), the diffraction effect is as figure 2 (b)).
[0052] (4) Dissolve stearic acid solid powder in absolute ethanol, and ultrasonically oscillate until completely dissolved, and the concentration of stearic acid is 0.03mol / L. Place the oxidized copper sheet obliquely in the ethanol solution of stearic acid for 15 minutes, remove the copper sheet, was...
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