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Electrical-melting yttrium oxide ceramic crucible for titanium alloy melting casting and preparation method of ceramic crucible

A technology of yttrium trioxide and ceramic crucible, which is applied in the field of electrofused yttrium trioxide ceramic crucible for molten titanium alloy casting and its preparation, can solve the problems of non-wetting and the like, and achieves reduction in use cost, increase in service life and stability and the effect of improving the purity

Active Publication Date: 2016-11-16
ZHENGZHOU FANGMING HIGH TEMPERATURE CERAMIC NEW MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to overcome the deficiencies in the prior art, and provide a kind of electric fusion yttrium trioxide ceramic crucible and preparation method thereof for molten casting of titanium alloy, this high-purity oxide ceramic crucible and zirconia / calcium oxide / oxide Compared with titanium alloy molten metal, magnesium has the characteristics of non-sticking, non-wetting, good thermal shock performance and ultra-high service life. The safe use temperature is below 2300 degrees, which effectively avoids contact with titanium alloy metal solution at high temperature. The low life of the crucible caused by the chemical reaction caused by the high activity and the decrease in the purity of the titanium alloy caused by the peeling off after the reaction, etc.

Method used

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Examples

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Effect test

Embodiment 1

[0029] An electric fused diyttrium trioxide ceramic crucible for melting and casting of titanium alloys, the percentage by weight of oxides is 100% in total, and it is composed of the following chemical composition: 98% Y2O3, other trace impurities not greater than 0.5%, and the rest Zro2, other trace impurities are oxides, including Fe 2 o 3 、Cr 2 o 3 、TiO 2 , CaO, K 2 O, SiO 2 、Al 2 o 3 , MgO, Na 2 O.

[0030] A preparation method of the above-mentioned electro-fused diyttrium trioxide ceramic crucible for fusion casting of titanium alloy comprises the following steps:

[0031] a. High-purity crystalline raw materials are prepared by magnetically stirring and smelting diyttrium trioxide melt by high-frequency heating fusion shell method

[0032] Diyttrium trioxide with a raw material purity of 99.999% is smelted at a temperature of 2500°C-2800°C, using water-cooled copper-cold crucible crystallization electromagnetic induction heating; the purity is 99.999%, and th...

Embodiment 2

[0041] An electric fused diyttrium trioxide ceramic crucible for melting and casting of titanium alloys, the percentage by weight of oxides is 100% in total, and it is composed of the following chemical composition: 95% Y2O3, no more than 0.5% other trace impurities, and the rest Zro2, other trace impurities are oxides, including Fe 2 o 3 、Cr 2 o 3 、TiO 2 , CaO, K 2 O, SiO 2 、Al 2 o 3 , MgO, Na 2 O.

[0042] A preparation method of the above-mentioned electro-fused diyttrium trioxide ceramic crucible for fusion casting of titanium alloy comprises the following steps:

[0043] a. High-purity crystalline raw materials are prepared by magnetically stirring and smelting diyttrium trioxide melt by high-frequency heating fusion shell method

[0044] Diyttrium trioxide with a raw material purity of 99.999% is smelted at a temperature of 2500°C-2800°C, using water-cooled copper-cold crucible crystallization electromagnetic induction heating; the purity is 99.999%, and the D5...

Embodiment 3

[0053] An electric fused diyttrium trioxide ceramic crucible for melting and casting of titanium alloys, the percentage by weight of oxides is 100% in total, and it is composed of the following chemical composition: 90% Y2O3, no more than 0.5% other trace impurities, and the rest Zro2, other trace impurities are oxides, including Fe 2 o 3 、Cr 2 o 3 、TiO 2 , CaO, K 2 O, SiO 2 、Al 2 o 3 , MgO, Na 2 O.

[0054] A preparation method of the above-mentioned electro-fused diyttrium trioxide ceramic crucible for fusion casting of titanium alloy comprises the following steps:

[0055] a. High-purity crystalline raw materials are prepared by magnetically stirring and smelting diyttrium trioxide melt by high-frequency heating fusion shell method

[0056] Diyttrium trioxide with a raw material purity of 99.999% is smelted at a temperature of 2500°C-2800°C, using water-cooled copper-cold crucible crystallization electromagnetic induction heating; the purity is 99.999%, and the D5...

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Abstract

The invention relates to the field of application of oxide ceramics, in particular to an electrical-melting yttrium oxide ceramic crucible for titanium alloy melting casting and a preparation method of the ceramic crucible. The ceramic crucible is prepared from, by oxide weight, 70%-99.5% of Y2O, 30%-0.5% of ZrO2 and not more than 0.5% of other trace impurities, wherein the trace impurities are oxides. The preparation method comprises the steps of conducting magnetic stirring melting on an yttrium oxide melting body through a high-frequency heating melting method for preparing a high-purity crystal material, crushing the yttrium oxide crystal for meeting the granularity and conducting shaping, sintering the yttrium oxide ceramic crucible and the like. The yttrium oxide ceramic crucible has the advantages of being free of adhesion and infiltration, good in thermal shock resistance, ultralong in service life and the like, the safe using temperature is below 2,300 DEG C, and the problems that due to the fact that the activity of a titanium alloy metal solution is high under high temperature, a chemical reaction is caused, the service life of the crucible is short, and the purity of titanium alloy is reduced due to disengagement after the reaction are solved.

Description

technical field [0001] The invention relates to the application field of oxide ceramics, in particular to an electric fused diyttrium trioxide ceramic crucible for titanium alloy fused casting and a preparation method thereof. Background technique [0002] Titanium alloy is an important structural metal developed in the 1950s. Titanium alloy is widely used in various fields because of its high strength, good corrosion resistance, and high heat resistance. Many countries in the world have recognized the importance of titanium alloy materials, have successively carried out research and development on them, and obtained practical applications, mainly to develop high-temperature titanium alloys for aero-engines and structural titanium alloys for airframes. Since the 1980s, resistance to Titanium alloys and high-strength titanium alloys have been further developed. They are mainly used to make aircraft engine compressor parts, followed by structural parts of rockets, missiles and...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/505C04B35/653C04B35/622
CPCC04B35/505C04B35/622C04B35/653C04B2235/3201C04B2235/3206C04B2235/3208C04B2235/3217C04B2235/3232C04B2235/3241C04B2235/3244C04B2235/3272C04B2235/3418C04B2235/66
Inventor 梁新星梁奇星
Owner ZHENGZHOU FANGMING HIGH TEMPERATURE CERAMIC NEW MATERIAL CO LTD
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