A kind of anticorrosion coating and its preparation and application method and a kind of composite material
A technology of composite materials and anti-corrosion coatings, applied in the field of materials, can solve problems such as waste of corrosion inhibitors, reduction of anti-corrosion properties of anti-corrosion coatings, corrosion of metal substrates, etc., and achieve the effect of improving corrosion inhibition efficiency and anti-corrosion effect
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[0074] The preparation process of controlled release microcapsules may include the following steps:
[0075] S1. Add water-soluble prepolymer a and a dispersant to solvent A, so that the water-soluble prepolymer is more uniformly dispersed in solvent A. Wherein, the prepolymer refers to a substance containing at least one of an ester group or a thioester group, which can be broken and decomposed under alkaline conditions, such as an amino resin prepolymer; the solvent A can be water or a water-miscible solvent; The dispersant may be sodium lauryl sulfate, gum Arabic (Gum Arabic), xanthan gum, diatomaceous earth and the like.
[0076] S2. Dissolving the corrosion inhibitor in solvent B, the solubility of the corrosion inhibitor in solvent B is greater than that in solvent A. Wherein, the corrosion inhibitor may include sodium nitrite; the solvent B may be a water-miscible solvent, such as tetrahydrofuran (THF), dimethylformamide (DMF), adenosine acid (AMP) and the like.
[00...
Embodiment 1
[0104] At 25° C., 30 parts by weight of the film former, 2.5 parts by weight of additives and 10 parts by weight of solvent were mixed, and stirred at high speed to obtain a mixture. Wherein, the film former includes epoxy resin; the solvent includes water; the auxiliary agent includes modified organosilicone compound, polyether modified organosilicon and sodium lauryl sulfate.
[0105] Add the controllable release microcapsules that are loaded with sodium nitrite in the resulting mixture, wherein the parts by weight of the controllable release microcapsules are 0.5, and the consumption of sodium nitrite accounts for 10% of the total amount of the controllable release microcapsules, which can be controlled The particle diameter of the microcapsules is below 25 μm, and the microcapsules are uniformly dispersed to obtain the anticorrosion coating.
[0106] The microcapsule shell of the controllable release microcapsules ruptures when the pH of the environment where the controlla...
Embodiment 2
[0108] At 25° C., 70 parts by weight of film former, 20 parts by weight of filler, 10 parts by weight of auxiliary agent and 17 parts by weight of solvent were mixed, and stirred at high speed to obtain a mixture. Wherein, the film former includes polyurethane; the solvent includes water; the filler includes talcum powder, nano silicon dioxide, titanium dioxide and calcium carbonate; the auxiliary agent includes sodium lauryl sulfate.
[0109] Add the controlled-release microcapsules that are loaded with sodium nitrite in the resulting mixture, wherein the parts by weight of the controlled-release microcapsules are 30, and the consumption of sodium nitrite accounts for 45% of the consumption of the controlled-release microcapsules, and the controlled-release The particle diameter of the microcapsules is below 25 μm, and the microcapsules are uniformly dispersed to obtain the anticorrosion coating.
[0110] The microcapsule shell of the controllable release microcapsules ruptur...
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