Method for preparing manganese-copper-based catalyst for degrading VOCs (Volatile Organic Compounds)
A catalyst, manganese-copper technology, applied in catalyst activation/preparation, chemical instruments and methods, physical/chemical process catalysts, etc., can solve the problems of industrialization difficulty, increase investment cost, corrode equipment, etc., and achieve raw material economy and cost. Economical and easy to operate
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Embodiment 1
[0032] (1) the preparation method of the catalyst provided in embodiment 1, comprises the steps:
[0033] Mix potassium permanganate and copper acetate evenly in a dry powder mixer (the molar ratio: Mn:Cu=4:1), then spread the mixture on a glass plate, ignite it with an electronic igniter, and react for a few seconds , to obtain a black manganese-copper-based catalyst, and then the appeal black powder was washed with water and filtered to obtain a pure manganese-copper-based (Mn4Cu1) catalyst.
[0034] (2) Catalytic activity test: toluene concentration 1000ppm, gas space velocity 30000ml g catalyst -1 h-1 . Gas chromatography TCD detection reaction tail gas CO 2 And CO, FID detects the content in toluene and other organic matter. The catalyst obtained in Example 1 catalytically burns toluene (90% conversion of toluene) at a temperature of 330°C, and the 50% degradation rate of toluene is 276°C. In the catalytic degradation reaction of toluene, the products are only toluene...
Embodiment 2
[0036] (1) the preparation method of the above-mentioned catalyst provided in embodiment 2, comprises the steps:
[0037] Mix potassium permanganate and copper acetate evenly in a dry powder mixer (molar ratio: Mn:Cu=10:1), then spread the mixture on a glass plate, ignite it with an electronic igniter, and react for a few seconds , to obtain a black manganese-copper-based catalyst, and then the appeal black powder was washed with water and filtered to obtain a pure manganin-copper-based (Mn10Cu1) catalyst.
[0038] (2) Catalytic activity test: toluene concentration 1000ppm, gas space velocity 30000ml g catalyst -1 h -1 . Gas chromatography TCD detection reaction tail gas CO 2 And CO, FID detects the content in toluene and other organic matter. The catalyst obtained in Example 2 of the present invention completely catalytically burns toluene (100% conversion of toluene) at a temperature of 303°C, 90% conversion of toluene is 276°C, and 50% conversion of toluene is at 254°C...
Embodiment 3
[0040] (1) the preparation method of above-mentioned catalyst provided by the present invention, comprises the steps:
[0041] Mix potassium permanganate and copper acetate evenly in a dry powder mixer (molar ratio: Mn:Cu=2:1), then spread the mixture on a glass plate, ignite it with an electronic igniter, and react for a few seconds , to obtain a black manganese-copper-based catalyst, and then the appeal black powder was washed with water and filtered to obtain a pure manganese-copper-based (Mn2Cu1) catalyst.
[0042] (2) Catalytic activity test: toluene concentration 1000ppm, gas space velocity 30000ml g catalyst -1 h -1 . Gas chromatography TCD detection reaction tail gas CO 2 And CO, FID detects the content in toluene and other organic matter. The catalyst prepared in Example 3 of the present invention catalytically burns toluene (50% conversion of toluene) at a temperature of 291°C. In the catalytic degradation reaction of toluene, the products are only toluene, car...
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