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PET polyester film antistatic agent and preparation method thereof

A technology of antistatic agent and polyester film, applied in the field of antistatic agent and its preparation, can solve problems such as limited application, and achieve the effect of reducing surface resistance and high transparency

Active Publication Date: 2016-12-07
HANGZHOU HUASU IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, it is very easy to generate static electricity, which limits its application in the electrical and electronic industries.

Method used

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  • PET polyester film antistatic agent and preparation method thereof
  • PET polyester film antistatic agent and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Synthesis of Aliphatic Polyester Oligomers. Take 146g of adipic acid, 62g of ethylene glycol, and 1% by mass fraction of p-toluenesulfonic acid, mix and esterify at 160°C for 1 hour. Then evacuate to reduce the vacuum of the system to below 100Pa, and continue the polycondensation for 0.5h. The product was then allowed to cool and THF was added to dissolve the product. Precipitate in ether and dry to obtain an aliphatic polyester oligomer with a molecular weight of 400 g / mol.

[0034] Synthesis of Unsaturated Aliphatic Polyester Oligomers. Take 60 g of the above-mentioned aliphatic polyester oligomer and 14 g of maleic anhydride, and the molar ratio of the two is 1:1. After mixing, esterify at 160°C for 4h. After cooling, THF was added to dissolve the product, followed by precipitation in ether, followed by drying to obtain an unsaturated aliphatic polyester oligomer. The molecular weight is 500 g / mol.

[0035] Synthesis of Copolymer of Unsaturated Aliphatic Polye...

Embodiment 2

[0037] Synthesis of Aliphatic Polyester Oligomers. Take 146g of adipic acid, 62g of ethylene glycol, and 1% by mass fraction of p-toluenesulfonic acid, mix and esterify at 160°C for 1 hour. Then evacuate to reduce the vacuum of the system to below 100Pa, and continue the polycondensation for 0.5h. The product was then allowed to cool and THF was added to dissolve the product. Precipitate in ether and dry to obtain an aliphatic polyester oligomer with a molecular weight of 400 g / mol.

[0038] Synthesis of Unsaturated Aliphatic Polyester Oligomers. Take 60 g of the above-mentioned aliphatic polyester oligomer and 14 g of maleic anhydride, and the molar ratio of the two is 1:1. After mixing, esterify at 160°C for 4h. After cooling, THF was added to dissolve the product, followed by precipitation in ether, followed by drying to obtain an unsaturated aliphatic polyester oligomer. The molecular weight is 500 g / mol.

[0039] Synthesis of Copolymer of Unsaturated Aliphatic Polye...

Embodiment 3

[0041] Synthesis of Aliphatic Polyester Oligomers. Take 146g of adipic acid, 62g of ethylene glycol, and 1% by mass fraction of p-toluenesulfonic acid, mix and esterify at 160°C for 1 hour. Then evacuate to reduce the vacuum of the system to below 100Pa, and continue the polycondensation for 0.5h. The product was then allowed to cool and THF was added to dissolve the product. Precipitate in ether and dry to obtain an aliphatic polyester oligomer with a molecular weight of 400 g / mol.

[0042] Synthesis of Unsaturated Aliphatic Polyester Oligomers. Take 60 g of the above-mentioned aliphatic polyester oligomer and 14 g of maleic anhydride, and the molar ratio of the two is 1:1. After mixing, esterify at 160°C for 4h. After cooling, THF was added to dissolve the product, followed by precipitation in ether, followed by drying to obtain an unsaturated aliphatic polyester oligomer. The molecular weight is 500 g / mol.

[0043]Synthesis of Copolymer of Unsaturated Aliphatic Polyes...

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Abstract

The invention discloses a PET polyester film antistatic agent and a preparation method thereof. The antistatic agent is a copolymer of unsaturated aliphatic polyester and sodium p-styrenesulfonate, and the mass ratio of the unsaturated aliphatic polyester to the sodium p-styrenesulfonate is 70-85:30-15; aliphatic polyester oligomer is synthesized, the aliphatic polyester oligomer is mixed with maleic anhydride to prepare the unsaturated aliphatic polyester, and the unsaturated aliphatic polyester is copolymerized with the sodium p-styrenesulfonate to synthesize the antistatic agent. Anti-static characteristics and high transparency can be well balanced, and PET polyester films processed with the antistatic agent can keep the anti-static characteristics for a long time as well as maintain high transparency.

Description

technical field [0001] The invention relates to an antistatic agent and a preparation method thereof, in particular to a PET polyester film antistatic agent and a preparation method thereof. Background technique [0002] PET (polyethylene terephthalate) has the characteristics of high strength, good wear resistance, good resilience and low cost, so it occupies a considerable proportion in textiles. At the same time, PET is an engineering project with excellent performance and wide application. plastic. However, due to the high resistivity of PET, under the conditions of 65% relative humidity and 25°C, the moisture absorption rate is only 0.4%, and the surface resistance is as high as 10. 14 Ω. Therefore, it is very easy to generate static electricity, which limits its application in industries such as electronics and electricity. The antistatic of PET is generally to reduce the resistivity of PET by adding antistatic agent, so that it can effectively dissipate the charge,...

Claims

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Application Information

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IPC IPC(8): C08F283/01C08F212/14C08G63/52C08L67/02C08L51/08
CPCC08F283/01C08G63/52C08J5/18C08J2367/02C08J2451/08C08L67/02C08L2201/04C08L2201/10C08L2203/16C08F212/14C08L51/08
Inventor 倪旭峰郑武义陈立锋章少华孙江华金双林王水发李晶
Owner HANGZHOU HUASU IND
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