BDAPP type artificial granite plate and preparing method thereof
A technology of granite and granite powder, which is applied in the field of organic-inorganic composite materials and its preparation, can solve problems such as unsatisfactory heat resistance, achieve good market application prospects, simple preparation process, and environmental friendliness
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Embodiment 1
[0031] 100 grams of hydrogenated bisphenol A diglycidyl ether, 280 grams of N,N,N',N'-tetraglycidyl-4,4'-diaminodiphenyl ether epoxy resin, 180 grams of E-44 epoxy Resin, 230 grams of 1,3-diglycidyl resorcinol epoxy resin, 210 grams of N,N,O-triglycidyl p-aminophenol epoxy resin were added to the reaction kettle, and after mixing evenly, add 20 gram of 2,2-bis[4-(2,4-diaminophenoxy)phenyl]propane (BDAPP), stirred and mixed, reacted at 115°C for 1 hour, cooled to below 60°C, and added 150 grams of latent Curing agent LRC30, then add the liquid anhydride of 100 grams of dodecyl succinic anhydride and 100 grams of tung oil anhydride, stir and mix evenly to obtain 1370 grams of BDAPP resin, which is designated as BDAPP-1.
Embodiment 2
[0033] 120 grams of hydrogenated bisphenol A diglycidyl ether, 100 grams of N,N,N',N'-tetraglycidyl-4,4'-diaminodiphenyl ether epoxy resin, 280 grams of CE793 epoxy resin, Add 320 grams of N,N,N',N'-tetraglycidyl-4,4'-diaminodiphenylmethane epoxy resin and 180 grams of diglycidyl phthalate epoxy resin into the reaction kettle, stir After mixing evenly, add 30 grams of 2,2-bis[4-(2,4-diaminophenoxy)phenyl]propane (BDAPP), stir and mix, react at 120°C for 1 hour, then cool to below 60°C , add 100 grams of latent curing agent LRC30, then add 300 grams of liquid anhydride of hexahydrophthalic anhydride, stir and mix evenly to obtain 1430 grams of BDAPP resin, which is designated as BDAPP-2.
Embodiment 3
[0035] 200 grams of hydrogenated bisphenol A diglycidyl ether, 300 grams of N,N,N',N'-tetraglycidyl-4,4'-diaminodiphenyl ether epoxy resin, 50 grams of 1,3-bis Add glycidyl resorcinol epoxy resin, 300 grams of o-cresol-formaldehyde novolac type epoxy resin, and 150 grams of 4,5-epoxycyclohexane-1,2-dicarboxylic acid diglycidyl ester into the reactor After stirring and mixing evenly, add 40 grams of 2,2-bis[4-(2,4-diaminophenoxy)phenyl]propane (BDAPP), stir and mix, react at 125°C for 0.5 hours, and cool to Below 60°C, add 200 grams of latent curing agent LRC30, then add 40 grams of methyltetrahydrophthalic anhydride, 20 grams of tungoleic anhydride and 40 grams of dodecyl succinic anhydride, stir and mix evenly to obtain 1340 grams of BDAPP type resin, record as BDAPP-3.
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