Fe-based amorphous alloy composite

A technology of iron-based amorphous alloys and composite materials, applied in metal processing equipment, transportation and packaging, etc., can solve the problem of iron-based amorphous alloys lacking room temperature plasticity, narrow temperature range for two crystallizations, and materials prone to brittle fractures, etc. problems, to achieve excellent high plasticity and soft magnetic properties, optimization of soft magnetic properties, and the effect of improving plasticity

Active Publication Date: 2017-01-04
南通巨升非晶科技股份有限公司
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  • Claims
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Problems solved by technology

However, its amorphous formation ability is still limited, and its saturation magnetization is lower than that of traditional silicon steel alloys. After annealing and crystallization, although the saturation magnetization and magnetic permeability are improved, the two crystallization temperature ranges of

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  • Fe-based amorphous alloy composite

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[0019] Example one

[0020] An iron-based amorphous alloy composite material, the composition of the iron-based amorphous alloy composite material: Fe 76 Al 4 Ga 2 Y 3 In 1.86 Co 8 B 4 Si 1.14 , Its preparation method includes the following steps:

[0021] Step 1. Preparation of raw materials. Take Fe powder with purity of 99.99%, particle size of 40μm, Al powder with purity of 99.5%, particle size of 80μm, Ga powder with purity of 99%, particle size of 80μm, purity of 99%, particle size Y powder of 75μm, purity of 97.5%, In powder of particle size of 120μm, purity of 98.5%, Co powder of particle size of 75μm, purity of 99.9%, B powder with particle size of 15μm and purity of 99.9%, particle size of 75μm The Si powder is made into nominal alloy composition according to atomic percentage, and then placed in a planetary ball milling tank together with a carbide ball with a diameter of 8mm for ball milling. Before ball milling, the ball milling tank must be vacuumed until the vacuum i...

Example Embodiment

[0024] Example two

[0025] An iron-based amorphous alloy composite material, the composition of the iron-based amorphous alloy composite material: Fe 72 Al 5 Ga 2 V 3 Co 10 B 8 , Its preparation method includes the following steps:

[0026] Step 1. Preparation of raw materials. Take Fe powder with purity of 99.99%, particle size of 40μm, Al powder with purity of 99.5%, particle size of 80μm, Ga powder with purity of 99%, particle size of 80μm, purity of 99.5%, particle size V powder of 75μm, purity of 98.5%, Co powder of particle size of 75μm, purity of 99.9%, particle size of B powder of 15μm, with nominal alloy composition in atomic percentage, and then together with cemented carbide balls with diameter of 8mm Put it in a planetary ball mill tank for ball milling. Before ball milling, the ball mill tank should be vacuumed. When the vacuum in the ball mill tank reaches 0.5Pa, fill the ball mill tank with 1MPa argon gas. The speed of the ball mill is 300r / min. The ball-to-powder ...

Example Embodiment

[0029] Example three

[0030] An iron-based amorphous alloy composite material, the composition of the iron-based amorphous alloy composite material is: Fe 70 Al 3 Ga 2 Y 1.63 V 1.37 In 1 Co 10 B 8 Si 3 , Its preparation method includes the following steps:

[0031] Step 1. Preparation of raw materials. Take Fe powder with purity of 99.99%, particle size of 40μm, Al powder with purity of 99.5%, particle size of 80μm, Ga powder with purity of 99%, particle size of 80μm, purity of 99%, particle size Y powder of 75μm, purity of 99.5%, V powder with particle size of 75μm, purity of 97.5%, In powder with particle size of 120μm, purity of 98.5%, Co powder with particle size of 75μm, purity of 99.9%, particle size of 15μm B powder and Si powder with a purity of 99.9% and a particle size of 75μm are prepared into nominal alloy composition according to atomic percentage, and then placed in a planetary ball milling tank together with a carbide ball with a diameter of 8mm for ball milling. B...

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Abstract

The invention discloses a Fe-based amorphous alloy composite. The composition of the Fe-based amorphous alloy composite is FeaAlbGacY(3-d)VdInxCoyBzSir, wherein a, b, c, d, x, y, z, and r represent atomic percent, a is larger than or equal to 70 and smaller than or equal to 76, b is larger than or equal to 3 and smaller than or equal to 5, c is 0 or 2, d is larger than or equal to 0 and smaller than or equal to 3, x is larger than or equal to 0 and smaller than or equal to 1.86, Co is larger than or equal to 8 and smaller than or equal to 10, z is 4 or 8, and r is larger than or equal to 0 and smaller than or equal to 3. The Fe-based amorphous alloy composite has excellent high plasticity and soft magnetic properties and has the saturation induction density Bs up to 1.73T, the bulk amorphous alloy composite prepared with a powder metallurgy method has the compactness up to 98.7% and strength up to 2.08 GPa, has good mechanical properties and can meet the industrial requirement, meanwhile, the Fe-based amorphous alloy composite contains no expensive rare earth elements, the demand for the only more expensive indium is very low, so that the production cost is not high, the process is not complex, and commercial production is easy to implement.

Description

technical field [0001] The invention relates to the field of metal materials, in particular to an iron-based amorphous alloy composite material. Background technique [0002] Iron-based amorphous and nanocrystalline alloys have excellent soft magnetic and mechanical properties, low price, and have broad application prospects in functional materials and structural engineering materials. However, its amorphous formation ability is still limited, and its saturation magnetization is lower than that of traditional silicon steel alloys. After annealing and crystallization, although the saturation magnetization and magnetic permeability are improved, the two crystallization temperature ranges of the alloy are too narrow, and the amorphous phase The low Curie temperature and the brittleness of the material after crystallization limit the high-temperature application of the material. In addition, iron-based amorphous alloys lack room temperature plasticity, and the material is prone...

Claims

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Application Information

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IPC IPC(8): C22C45/02B22F3/14
CPCC22C45/02B22F3/14B22F2999/00B22F2998/10B22F2201/20B22F2202/13B22F2203/13B22F1/142B22F2009/043
Inventor 许霞
Owner 南通巨升非晶科技股份有限公司
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