A kind of production method of impregnated film paper with low formaldehyde emission
A technology of impregnating adhesive film and low formaldehyde release, which can be used in paper, papermaking, paper coating, etc. Effect
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Embodiment 1
[0030] Preparation of urea-formaldehyde resin:
[0031] Formula: 100kg of formaldehyde with a concentration of 37%, 76kg of urea with a concentration of 98%, 15kg of water, and 7kg of compound additives. The molar ratio of formaldehyde to urea, F / U=0.99
[0032] method:
[0033] (1) Put 100kg of formaldehyde into the reactor at one time, put in 32.7kg of urea, add 15kg of water, and adjust the pH to 8.0 with sodium hydroxide solution;
[0034] (2) Open the oil valve and raise the temperature to 80°C, stop the heat supply, let it automatically rise to 85°C, keep warm for 30 minutes, add formic acid solution, control the pH value at 4.5, and carry out polycondensation reaction at 92°C;
[0035] (3) Add 7kg of compound additives and adjust the pH to 7.0 when the glue solution appears dense white mist in 20°C water, and add 24.3kg of urea when the temperature is lowered to 85°C;
[0036] (4) Cool down to 65°C and add 19kg of urea, adjust the pH to 7.0, continue to cool down to ...
Embodiment 2
[0054]The difference between the impregnated film paper described in this embodiment and Example 1 is: the total amount of urea added during the preparation of urea-formaldehyde resin is 78kg, the molar ratio of formaldehyde to urea, F / U=0.96; in the preparation step of urea-formaldehyde resin The add-on of the first batch of urea in (1) is 33.5kg; The add-on of the second batch of urea in the urea-formaldehyde resin preparation step (3) is 25kg; The add-on of the third batch of urea in the urea-formaldehyde resin preparation step (4) is 19.5kg; if there is a parameter range, the middle value of the corresponding parameter range is taken; others are the same as in Example 1.
Embodiment 3
[0056] The difference between the impregnated film paper described in this embodiment and Example 1 is: the total amount of urea added during the preparation of urea-formaldehyde resin is 80kg, the molar ratio of formaldehyde to urea, F / U=0.94; in the preparation step of urea-formaldehyde resin The addition amount of the first batch of urea in (1) is 34.4kg; the addition amount of the second batch of urea in the urea-formaldehyde resin preparation step (3) is 25.6kg; the addition amount of the third batch of urea in the urea-formaldehyde resin preparation step (4) It is 20kg; if there is a parameter range, take the end value of the corresponding parameter range (Example 1 takes the first end value). Others are the same as in Example 1.
[0057] Table 1
[0058] Example 1-3 is compared with the detection value of formaldehyde emission of impregnated film paper on the market as shown in Table 1
[0059]
[0060] It can be seen from Table 1 that the formaldehyde emission of t...
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