The invention discloses application of monofunctional
isocyanate in surface blocking modification of PA66 industrial
yarn, and belongs to the technical field of
polyamide fibers. Aiming at the problems of high hydrolytic sensitivity and poor long-term stability of PA66 in a humid environment, monofunctional
isocyanate can react with an amino-terminated group on the outermost layer of the PA66
fiber to form an
alkyl /
aryl urea terminated structure, a formed
urea bond is more resistant to
hydrolysis than an amido bond, and a monofunctional design ensures that a
body type cross-linked network is not formed, so that the service life of the PA66
fiber is prolonged, and the service life of the PA66
fiber is prolonged. The modification reaction is limited to occur only on the
surface layer, performance loss caused by internal modification can be avoided, the strength
retention rate of the obtained surface-terminated modified PA66 industrial
yarn in a high-damp-heat environment is high, the industrial application requirement for long-term durability is met, and the application prospect is wide. Therefore, the
composite material has a good application prospect in preparation of
radial tire cord fabrics,
automobile safety belts, industrial conveying belts or high-pressure rubber hose reinforcing
layers.