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Modified foamed titanium particle electrode with electrocatalytic chlorophenol removing function and preparation method thereof

A particle electrode and titanium foam technology, which is applied in chemical instruments and methods, oxidized water/sewage treatment, water pollutants, etc., can solve the problems of short life, insufficient stability, and high cost of electrode materials

Inactive Publication Date: 2017-03-29
BEIJING YIQINGYUAN ENVIRONMENTAL PROTECTION TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the high resistance and low conductivity of traditional electrode materials lead to low current efficiency, insufficient stability, short life, and high cost of electrode materials in wastewater treatment, which limits the application and development of electrocatalytic oxidation technology in water treatment. , so the research and preparation of new electrode materials need to be further strengthened
At present, there is still a lack of electrode materials and preparation methods with high-efficiency electrocatalytic removal of p-chlorophenol specific pollutants

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0059] (1) Wash 126g of foamed titanium particles with a particle size of 4-6mm with 1000mL of deionized water, then soak them in 500mL of chloroform for 8 hours, take them out, wash them with 1000mL of deionized water, and then wash them with 1000mL of 95% by mass. After washing with % ethanol, place it in a drying oven at 85°C for 1.5h to obtain substance A1;

[0060] (2) Add 8.27 grams of platinum nitrate and 750 mL of deionized water into a conical flask with a volume of 1000 mL, stir for 3 minutes at 1000 r / min, add 15 mL of concentrated nitric acid, shake well and divide into 3 equal parts to obtain a mixed solution K1, mixed solution K2, mixed solution K3;

[0061] (3) 820 mg Ce(NO 3 ) 3 and 50 mL of AgNO with a molar concentration of 0.42 mol / L 3 The solution was added to the mixed solution K1, and stirred at 1000r / min for 3 minutes to obtain the mixed solution L1;

[0062](4) Add substance A1 to the mixture L1, shake in a shaker at 45°C for 15 minutes, cool to roo...

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PUM

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Abstract

The invention discloses a modified foamed titanium particle electrode with an electrocatalytic chlorophenol removing function and a preparation method thereof. The preparation method comprises the following steps: preparing a material A from foamed titanium, trichloromethane, and ethanol; modifying the material A by a mixed solution prepared from silver nitrate, platinum nitrate, ether, and Ce(NO3)3 to obtain a material E; modifying the material E by a mixed solution prepared from Co(NO3)2, ethanol, AlCl3, SnCl4, MgCl2, and MnCl2 to obtain a material H; modifying the material H by a mixed solution prepared from sodium dodecyl sulfate, n-hexane, n-butanol, ammonium meta-vanadate, sodium citrate, MgCl2, and MnCl2 to obtain a material K; and modifying the material K by a mixed solution prepared from polyvinyl alcohol and HAuCl4 to obtain the modified foamed titanium particle electrode with an electrocatalytic chlorophenol removing function.

Description

technical field [0001] The invention belongs to the technical field of electrocatalytic oxidation treatment of refractory organic wastewater, and in particular relates to a modified foam titanium particle electrode with the function of electrocatalytically removing chlorophenol and a preparation method thereof. Background technique [0002] Electrocatalytic oxidation technology is a very promising water treatment technology that has gradually developed in recent years. It mainly oxidizes and degrades organic pollutants in wastewater by generating hydroxyl radicals and other active groups with strong oxidizing properties. Refractory organic matter or biotoxic pollutants are converted into biodegradable or non-toxic substances, improving the biodegradability of wastewater, thereby facilitating subsequent biological treatment. Therefore, the electrocatalytic oxidation water treatment technology has the characteristics of no secondary pollution, low cost, strong applicability, a...

Claims

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Application Information

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IPC IPC(8): C02F1/461C02F1/72C02F101/34C02F101/36
CPCC02F1/4672C02F2101/345C02F2101/36
Inventor 不公告发明人
Owner BEIJING YIQINGYUAN ENVIRONMENTAL PROTECTION TECH CO LTD
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