Method for smelting martensitic stainless steel P91 for boiler pipe
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A technology of martensitic stainless steel and smelting methods, applied in the field of smelting, can solve the problems of high cost and unable to meet the needs of continuous casting production, and achieve the effects of short time, saving AOD time and reducing costs
Active Publication Date: 2017-05-10
HENAN ZHONGYUAN SPECIAL STEEL EQUIP MFG CO LTD
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[0002] P91 is a commonly used steel for subcritical and supercritical high-pressure boiler tube walls. The smelting method of EAF+LF+VD+LF is often used. This smelting method needs to use micro-carbon ferrochrome to adjust chromium during the LF refining process to prevent carbon high , higher carbon ferrochrome is more costly than that, and at the same time, a large number of alloys are transferred into the refining furnace during the refining process. 6-8 tons, the LF furnace smelting time is more than 5 hours, which cannot meet the needs of continuous casting production
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[0017] A method for smelting martensitic stainless steel P91 for boiler tubes, using an electric furnace to smelt primary molten steel, the process flow is: electric arc furnace (EAF) / intermediate frequency induction furnace (IF) + argon oxygen refining furnace (AOD) + LF refining furnace + vacuum Degassing (VD) + LF + continuous casting (CC) + billet annealing.
[0018] The smelting process is as follows:
[0019] Step 1: Electric arc furnace smelting: the electric furnace is equipped with 60% of special steel scrap, 30% of low five-hazard pig iron, and 10% of low five-hazard sponge iron. After the sampling test, As≤0.012%, Sn≤0.010%, Pb≤0.010%, Sb≤0.005%, Bi≤0.010%, electric arc furnace tapping conditions: end point [P]≤0.003%, tapping temperature≥1640℃;
[0020] Step 2: The intermediate frequency material is composed of 7-8 tons of high-carbon ferrochromium, 0.5-0.8 tons of ferromolybdenum, and 1-2 tons of P91 material head. Before mixing, carefully check the P content to ...
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Abstract
The invention belongs to the technical field of smelting, and mainly relates to a method for smelting martensitic stainless steel P91 for a boiler pipe. The technological process of an electric arc furnace / medium-frequency induction furnace, an argon-oxygen refining furnace, an LF refining furnace, vacuum degassing, LF and continuous casting is adopted. Components for smelting the martensitic stainless steel for the boiler pipe comprise, by mass percent, 0.08%-0.12% of C, 0.30%-0.50% of Si, 0.30%-0.60% of Mn, not larger than 0.015% of P, not larger than 0.010% of S, not larger than 0.40% of Ni, 8.5%-9.5% of Cr, 0.90%-1.10% of Mo, 0.18%-0.30% of V, not larger than 0.30% of Cu, 0.03%-0.07% of N, 0.05%-0.10% of Nb, not larger than 0.020% of Al, not larger than 0.015% of [As], not larger than 0.010% of [Sn], not larger than 0.010% of [Pb], not larger than 0.010% of [Sb], not larger than 0.010% of [Bi] and the balance Fe and a small quantity of other elements. The method for smelting the martensitic stainless steel P91 for the boiler pipe aims to be low in inclusion content and delta-ferrite content and capable of achieving continuous casting production.
Description
technical field [0001] The invention belongs to the technical field of smelting, and mainly relates to a method for smelting martensitic stainless steel P91 for boiler tubes. Background technique [0002] P91 is a commonly used steel for subcritical and supercritical high-pressure boiler tube walls. The smelting method of EAF+LF+VD+LF is often used. This smelting method needs to use micro-carbon ferrochrome to adjust chromium during the LF refining process to prevent carbon high , the cost of higher carbon ferrochrome is higher than that, and at the same time, 6-8 tons of alloys are transferred in large quantities during the refining process of the refining furnace, and the smelting time of the LF furnace is more than 5 hours, which cannot meet the needs of continuous casting production. Contents of the invention [0003] The object of the present invention is to provide a method for smelting martensitic stainless steel P91 for boiler tubes with low P91 inclusion content a...
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