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A kind of superhydrophobic coating, preparation method and application of superhydrophobic coating

A technology of super-hydrophobic coatings and super-hydrophobic coatings, applied in the field of coatings, can solve the problems of difficult control of super-hydrophobic surfaces and coating micro-nano structures and surfaces, poor uniformity and reproducibility, unfavorable large-area film formation, etc., to achieve Strong durability, mild conditions, and easy film-forming effects

Active Publication Date: 2019-07-30
HUNAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In view of this, the present invention aims to propose a preparation method and application of superhydrophobic coatings and superhydrophobic coatings to solve the deficiencies in the prior art. There are difficulties, and the micro-nano structure and surface energy of the super-hydrophobic surface and coating are not easy to control, and the uniformity and reproducibility are poor; the rolling angle is large, and it is difficult for water droplets to self-migrate quickly on the surface; at the same time, the method of the present invention is simple and the cost is low. , and strong adhesion on glass, aluminum plate, PVC, UPVC substrate

Method used

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  • A kind of superhydrophobic coating, preparation method and application of superhydrophobic coating
  • A kind of superhydrophobic coating, preparation method and application of superhydrophobic coating
  • A kind of superhydrophobic coating, preparation method and application of superhydrophobic coating

Examples

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Embodiment 1

[0042] A method for preparing a superhydrophobic coating, comprising the steps of,

[0043] 1. Solution preparation

[0044] Liquid A: Add alkyd varnish to mixed solvent (diluent (banana water): dichloromethane = 2:1, V / V), ultrasonic cleaner for 10-15mim to obtain a uniform dispersion, of which the alkyd varnish The volume fraction is 14%;

[0045] Solution B: Weigh commercially available hydrophobic silica powder and ultrasonically disperse it in a mixed solvent (carbon tetrachloride: dichloromethane = 7:2, V / V) for 10-15mim to obtain a stable colorless and transparent dispersion. Wherein the mass-volume concentration of silicon dioxide is 44mg / mL;

[0046] Liquid C: Weigh fluorinated graphite powder and disperse it in dichloromethane solvent, ultrasonically disperse for 10-15 minutes to obtain a stable suspension, in which the mass-volume concentration of fluorinated graphite powder is 10 mg / mL;

[0047] Liquid D: Weigh hard polyvinyl chloride powder (UPVC) and disperse ...

Embodiment 2

[0057] In Example 1, in step 2, five solutions were measured according to the volume ratio of A liquid: B liquid: C liquid: D liquid: E liquid according to the volume ratio of 8.5:18:30:6:2, mixed and ultrasonically dispersed to obtain mixture.

[0058] The glass sheet in step 3 is replaced with a PVC plate, and the rest of the operations are the same, and the required superhydrophobic coating can be obtained, the contact angles are all above 150 degrees, and the rolling angles are all less than 7 degrees. Such as image 3 with Figure 7 shown.

Embodiment 3

[0060] In Example 1, in step 2, five solutions were measured according to the volume ratio of A liquid: B liquid: C liquid: D liquid: E liquid according to the volume ratio of 8.5:18:40:6:2, mixed and ultrasonically dispersed to obtain mixture.

[0061] Replace the glass sheet in step 3 with a UPVC plate; in step 4, put the prepared mixed solution in a high-pressure spraying equipment, spray it on the treated UPVC plate, and dry it at room temperature in a ventilated place. The rest of the operations are the same, and you can get The required super-hydrophobic coatings have a contact angle of more than 150 degrees and a rolling angle of less than 7 degrees. Such as Figure 4 with Figure 8 shown.

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Abstract

The invention provides a super-hydrophobic coating as well as a preparation method and application of the super-hydrophobic. The super-hydrophobic coating comprises the following components: alkyd resin varnish, lyophobic silicon dioxide, carbon monofluoride, and rigid polyvinyl chloride or polystyrene in a mass ratio of (120-140):(70-90):(25-45):(9-15); the super-hydrophobic coating further comprises a solvent; the solvent consists of a diluent, dichloromethane, carbon tetrachloride and styrene in a volume ratio of (3-8):(38-58):(11-17):(1-3); the volume percentage of the alkyd resin varnish is 1-3%. The super-hydrophobic coating is simple in preparation method, relatively low in cost and good in adhesion property on glass, aluminum plates, PVC (Polyvinyl Chloride) and UPVC (Unplasticized Polyvinyl Chloride) substrates.

Description

technical field [0001] The invention belongs to the technical field of coatings, and in particular relates to a superhydrophobic coating, a preparation method and an application of the superhydrophobic coating. Background technique [0002] At present, the main method of preparing silicon dioxide superhydrophobic film: one method is to combine SiO 2 The particles are mixed and stirred with the alcohol solution, ultrasonically dispersed, and the pH is adjusted to obtain a colloidal electrophoretic fluid, and then the electrophoretic fluid is deposited on a glass substrate to obtain SiO 2 thin film, which will then be loaded with SiO 2 The glass of the film is modified in a low surface energy modifier to obtain superhydrophobic SiO 2 film. Another method uses the bonding method to embed the mixed powder particles of micron-sized powder and nano-sized powder in the super-hydrophobic layer into the bonding layer on the surface of the substrate, so that the super-hydrophobic l...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D167/08C09D127/06C09D125/06C09D7/61
CPCC09D7/61C09D7/65C09D167/08C08L27/06C08L25/06C08K3/04C08K3/36
Inventor 宦双燕郑小芳王娅娅江西殷平唐长林赵守仁
Owner HUNAN UNIV