A kind of preparation method of multifunctional polyester fiber

A polyester fiber and multi-functional technology, which is applied in the field of preparation of multi-functional polyester fiber, can solve the problems of poor effect, high addition amount and difficult dispersion, etc., and achieve the effect of low cost, long-lasting effect and increased compatibility

Active Publication Date: 2018-04-20
CHANGSHU GOLD SPRING CHEM FIBERS & KNITTINGS +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Patent CN103710963A provides multi-functionality for the polyester matrix by adding a variety of inorganic nano-powders with a high content. This method is difficult to disperse due to the high amount of addition, and the effect is poor

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A kind of preparation method of multifunctional polyester fiber, concrete steps are:

[0023] The first step: Add 19.5g α-ZrP to 100 ml tetrahydrofuran, ultrasonically and mechanically stir, the ultrasonic power is 50W, the time is 20min; the speed of mechanical stirring is 200r / min, the time is 20min; 1.7g copper chloride is added In the solution, react for 6h; dropwise add the silane coupling agent KH550 to continue the reaction, the mass ratio of the amount of KH550 added to α-ZrP is 0.5:1; add nitric acid with a mass fraction of 80% to treat the multi-walled carbon nanotubes; the reaction temperature at 80°C, and the reaction time was 12 h. E51 was added to modify the acidified multi-walled carbon nanotubes; the molar ratio of acidified carbon material to epoxy modifier E51 was 1:5, the reaction temperature was 80 °C, and the reaction time was 12 h. The molar ratio of epoxy-modified multi-walled carbon nanotubes to KH550-α-ZrP is 1:1; the temperature is raised to 8...

Embodiment 2

[0026] A kind of preparation method of multifunctional polyester fiber, concrete steps are:

[0027] The first step: Add 19.5g α-ZrP to 100 ml DMF, ultrasonically and mechanically stir, the ultrasonic power is 35W, the time is 60 min; the speed of mechanical stirring is 300r / min, the time is 15min; 1.6g copper sulfate is added In the solution, react for 12 h; dropwise add silane coupling agent KH550 to continue the reaction, the mass ratio of the amount of KH550 added to α-ZrP is 1:1; add nitric acid with a mass fraction of 80% to treat the multi-walled carbon nanotubes; react The temperature was 75°C, and the reaction time was 24 h. E51 was added to modify the acidified multi-walled carbon nanotubes; the molar ratio of acidified carbon material to epoxy modifier E51 was 1:5, the reaction temperature was 75 °C, and the reaction time was 24 h. The molar ratio of epoxy-modified multi-walled carbon nanotubes to KH550-α-ZrP is 1:1; the temperature is raised to 80°C, and the react...

Embodiment 3

[0030] A kind of preparation method of multifunctional polyester fiber, concrete steps are:

[0031] Step 1: Add 19.5g α-ZrP to 100 ml tetrahydrofuran, ultrasonically and mechanically stir, the ultrasonic power is 50W, and the time is 30min; the speed of mechanical stirring is 300r / min, and the time is 30min; 0.85g silver nitrate is added to the solution During the reaction for 18 h; the silane coupling agent KH550 was added dropwise to continue the reaction, and the mass ratio of the amount of KH550 added to α-ZrP was 1:1; the mass fraction of 80% was added to treat nano-carbon black with nitric acid; the reaction temperature was 80 °C, and the reaction time was 12 h. E51 was added to modify acidified nano-carbon black; the molar ratio of acidified carbon material to epoxy modifier E51 was 1:5, the reaction temperature was 80 °C, and the reaction time was 24 h. The molar ratio of epoxy-modified multi-walled carbon nanotubes to KH550-α-ZrP is 1:1; the temperature is raised to...

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Abstract

The invention discloses a preparation method of multifunctional polyester fiber, and belongs to the technical field of preparation of functional materials and functional fiber. The preparation method comprises the following steps: 1, enabling functional metal ions to enter alpha-ZrP through ion exchange to form functional alpha-ZrP, then modifying the functional alpha-ZrP through KH550, acidifying a carbon material to obtain an acidified carbon material, modifying the acidified carbon material through an epoxy modifier E51 to obtain a modified carbon material, and adding the KH550-modified functional alpha-ZrP into the modified carbon material to form a multifunctional nanocluster; 2, blending and granulating the multifunctional nanocluster and a polyester matrix at 250 to 270 DEG C, then carrying out drying, and finally carrying out a melt spinning method to preparing the multifunctional polyester fiber by adopting a melt spinning method. The adding amount of an antibacterial object component in the multifunctional polyester fiber is small, and the antibacterial object component is uniformly dispersed; and the multifunctional polyester fiber has a persistent function, and the preparation method is easy and convenient to operate.

Description

technical field [0001] The invention belongs to the technical field of preparation of functional materials and functional fibers, and in particular relates to a preparation method of multifunctional polyester fibers. Background technique [0002] At present, there are more and more varieties of polyester fiber functionalization, and the realization methods are different according to different functions. For example, in order to realize the functionalization of polyester fiber, the commonly used methods are surface modification technology and blending modification technology. However, with the development of society, it becomes more and more difficult for a single function to meet the multi-field and multi-functional requirements. [0003] Patent CN101942759A is to add fibers to a solution containing silver nitrate to absorb silver nitrate in the solution, and then reduce the fibers after absorbing silver nitrate to obtain antibacterial fibers or fabrics with silver attached ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01F6/92D01F1/10
CPCD01F1/10D01F6/92
Inventor 樊海彬朱美芳杨新华周哲张林杨周家良
Owner CHANGSHU GOLD SPRING CHEM FIBERS & KNITTINGS
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