Method for synthesizing microporous conductive polymeric material by using nano reactor

Abstract

The invention relates to a method for synthesizing a microporous conductive polymeric material by using a nano reactor. The method for synthesizing the microporous conductive polymeric material by using the nano reactor comprises the following steps: firstly, synthesizing the organic and inorganic hybridized nano reactor; representing the microstructure of the nano reactor by means of a scanning electron microscope, and meanwhile, representing the structure by means of an X-ray diffractometer; and secondly, by taking the nano reactor as a template, synthesizing the microporous conductive polymeric material which has polythiophene of a three-dimensional structure with a regular porous structure by means of an electrochemical method inside, has a reversible oxidation reduction cycle volt-ampere property and has the conductivity of 0.1S / cm. The conductive polymeric material with the microporous structure is synthesized by using the nano reactor as the template by means of the method for the first time, so that novel polythiophene with the microporous structure is obtained.

Description

technical field [0001] The invention relates to the technical field of synthesizing conductive polymer materials with a microporous structure, in particular to a method for synthesizing microporous conductive polymer materials with a nano-reactor. Background technique [0002] In the past few years, research groups around the world have consciously increased their efforts to design and develop new materials to prepare porous organic frameworks (POFs) with specific functions in the size range from a few nanometers to hundreds of nanometers, including covalent organic frameworks. (COFs), metal-organic frameworks (MOFs) and microporous conjugated polymers (CMPs). Recently, porous organic frameworks with unique electronic and optoelectronic properties have aroused great interest among scientists. Due to the great potential of organic-based conductive porous materials in photovoltaic applications, more and more efforts have been devoted to the research of such materials. Such m...

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Problems solved by technology

Two-dimensional (2D) porous polymers based on conjugated organic ligands have also been synthesized, such as electroactive organic frameworks (EOFs), CMPs, and COFs. induced electrical properties, but its conductivity is very low, which may come from inefficient stacking of p-systems

MOFs membrane materials have been widely studied as a new class of functional materials with wide applications in gas storage, gas separation, carbon capture, catalysis, sensing, etc. However, summarizing all the literature on the use of MOFs materials we found that, Most of these literatures are reporting the application of MOFs materials in gas-liquid separation, gas adsorption and storage, and optics, but there are still very few electrochemical applications.

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