The present invention provides an
oxygen carrier for chemical looping
hydrogen generation, a preparation method and applications thereof. According to the present invention, the
oxygen carrier comprises, by
mass, 5-65% of Fe2O3, 5-35% of MoO3 and 30-90% of Al2O3; the
oxygen carrier is prepared through a dipping method and can be used for chemical looping
hydrogen generation, wherein an
alumina carrier is dipped in a soluble solution containing iron and
molybdenum, and
drying and
roasting are performed to prepare the oxygen carrier;
molybdenum oxide as the auxiliary agent is added to the oxygencarrier, and the conversion between Mo<6+> and Mo<3+> forms a
redox cycle, such that the
redox reaction can be promoted, and the reducibility of the
active component iron oxide can be easily improved; the
dispersity of
iron oxide can be improved with
molybdenum oxide, such that the particle of the
iron oxide can be reduced so as to improve the stability of the oxygen carrier; and the oxygen carrier is suitable for carrying out the reaction at the high temperature, has advantages of good
thermal stability, cheap and easily available raw materials and simple preparation method, and is suitablefor industrial applications.