Catalyst for ammonia synthesis
A catalyst and a technology for synthesizing ammonia, which is applied in the field of highly active ammonia synthesis catalysts and can solve the problems of high activity of catalysts
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Embodiment 1
[0027] 1gFe 2 After N and LiH were mixed according to the molar ratio of 1:2, they were ball-milled with a planetary ball mill for 24 minutes, and 0.5 g of the sample was placed in a quartz tube reactor, and then 2 Rise to 300°C at 5K / min under the atmosphere, and pre-activate under this condition for 3 days, then cool down to 200°C, switch to syngas, (N 2 and H 2 Mixed gas with a molar ratio of 1:3), the GHSV of the mixed gas is 10000ml / h / g, the pressure of the mixed gas is increased to 10bar, and the temperature rise test is started from 200°C, the results are as follows figure 1 shown.
Embodiment 2
[0029] Repeat Example 1, just replace LiH with LiNH of equimolar amount 2 , the activity results as figure 2 shown.
Embodiment 3
[0031] According to the method in Example 1, after the same catalyst is preactivated, H 2 , N 2 Mixed gas, keep the temperature constant at 300°C, change the space velocity of the reaction gas, and test the relationship between the speed of the catalyst to synthesize ammonia and the space velocity, such as image 3 shown.
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