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Porous composite film and preparation method thereof

A technology of composite film and porous film, which is applied in the field of composite film, can solve the problems of small specific surface area and inability to achieve good sensing, and achieve good composite effect

Active Publication Date: 2017-07-21
WUHAN TEXTILE UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

At present, composite films are widely used in the field of packaging. Due to the characteristics of strong flexibility, excellent mechanical properties, and low production costs, researchers have gradually applied composite films to the fields of sensors, supercapacitors, and functional fibers. However, traditional The surface of the composite film is smooth and flat, and has the disadvantage of small specific surface area, which cannot realize the functions of sensing, conductivity, adsorption and so on.

Method used

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  • Porous composite film and preparation method thereof
  • Porous composite film and preparation method thereof
  • Porous composite film and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] The preparation method of porous composite film, comprises the following steps:

[0025] 1) Weigh 650g of polypropylene and 350g of cellulose acetate butyrate, mix them uniformly as the raw material of the outer film, then weigh 2000g of polypropylene as the polymer of the base film; put the raw material of the outer film and the polymer of the base film into the double-layer flow Film stretching machine, after double-layer casting film machine extrusion, unidirectional stretching and cooling forming process, a composite film (such as image 3 shown);

[0026] 2) Soak the composite film in an acetone solution, use acetone to extract cellulose acetate butyrate in the outer film 3, the outer film 3 forms the outer porous film 1, and obtain a porous composite film (such as figure 1 shown).

[0027] like figure 1 , the thickness of the outer porous film 1 in the porous composite film is 50 μm, and the thickness of the base film 2 is 100 μm, combining figure 2 As shown,...

Embodiment 2

[0029] 1) Weigh 900g of polyethylene and 100g of cellulose acetate butyrate, mix them evenly as the raw material of the outer film, then weigh 1000g of polyethylene as the base film polymer; put the outer film raw material and the base film polymer into the double-layer flow Film stretching machine, after double-layer casting film machine extrusion, unidirectional stretching and cooling forming process, a composite film (such as image 3 shown);

[0030] 2) The composite film is soaked in an acetone solution, and after utilizing acetone to extract cellulose acetate butyrate in the outer film, the outer film 3 forms the outer porous film 1, and the porous composite film (such as figure 1 shown).

[0031] like figure 1 , the thickness of the outer porous film 1 in the porous composite film is 100 μm, and the thickness of the base film 2 is 50 μm, combining figure 2 As shown, the average diameter of the pores in the outer layer porous film 1 is 5 μm.

Embodiment 3

[0033] 1) Weigh 700g of polyester and 300g of cellulose acetate butyrate, mix them evenly as the raw material of the outer film, then weigh 1500g of polyester as the polymer of the base film; put the raw material of the outer film and the polymer of the base film into the double layer Cast film machine, after double-layer cast film machine extrusion, uniaxial stretching and cooling molding process, a composite film (such as image 3 shown);

[0034] 2) the composite film is immersed in the acetone solution, and after utilizing acetone to extract cellulose acetate butyrate in the outer film, the outer film forms an outer porous film, and obtains a porous composite film (such as figure 1 shown).

[0035] like figure 1 , the thickness of the outer porous film 1 in the porous composite film is 65 μm, and the thickness of the base film 2 is 80 μm, combining figure 2 As shown, the average diameter of the pores in the outer layer porous film 1 is 1 μm.

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Abstract

The invention relates to the composite film field, especially to a porous composite film and a preparation method thereof. The porous composite film includes a base membrane, an outer porous film is attached to the outer surface of the base membrane, and holes with an average diameter of 1-10micrometers are evenly distributed on the outer porous film. The preparation method of the porous composite film includes the steps of: 1) weighing an outer layer polymer and cellulose acetate butyrate according to a mass ratio of 6.5:3.5-9:1, mixing the substances evenly to obtain a mixture as an outer film raw material, putting the outer film raw material and a base membrane polymer into a double-layer casting film machine, carrying out extrusion by the double-layer casting film machine, uniaxial tension and cooling molding so as to obtain a composite film formed by superimposition of the base membrane and an outer film; and 2) soaking the composite film in an acetone solution, utilizing acetone to extract cellulose acetate butyrate in the outer film so as to let the outer film form the outer porous film, and then performing drying so as to obtain the porous composite film. The porous composite film has the characteristic of large specific surface area.

Description

technical field [0001] The invention relates to the field of composite membranes, in particular to a porous composite membrane and a preparation method thereof. Background technique [0002] The composite film is a polymer material composed of two or more layers of films of different materials by gluing or hot pressing. The composite film can be composed of multiple layers of films of different materials, so the composite film can be made of multiple materials. Part of the performance, endowing the composite film with more performance combinations. At present, composite films are widely used in the field of packaging. Due to the characteristics of strong flexibility, excellent mechanical properties, and low production costs, researchers have gradually applied composite films to the fields of sensors, supercapacitors, and functional fibers. However, traditional The surface of the composite film is smooth and flat, and has the disadvantage of small specific surface area, whic...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B3/24B32B27/06B32B27/18B29D7/01C08L23/12C08L23/06C08L67/00C08L77/00C08L1/14
CPCB29D7/01B32B3/266B32B27/08B32B27/18B32B2250/24B32B2307/202B32B2307/204B32B2457/00C08L23/06C08L23/12C08L67/00C08L77/00C08L1/14
Inventor 郭启浩王栋赵青华蒋海青李沐芳梅涛吴永智
Owner WUHAN TEXTILE UNIV