Pesticide residue detection system capable of uploading data in real time
A pesticide residue detection and real-time upload technology, which is applied in the direction of testing food, measuring devices, material inspection products, etc., can solve the problems of long detection time, few types, complicated pretreatment steps, etc., and achieve cost saving, high comprehensiveness, The effect of broad application prospects
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preparation example Construction
[0034] As another preferred embodiment, a method for preparing a working electrode will be introduced below, comprising the following steps:
[0035] (1) Polish the carbon-titanium alloy sheet with sandpaper until the surface is smooth, and then place it in 75% alcohol solution and deionized water for 1 hour, so as to remove grease and other residues on the surface;
[0036] (2) For the first electropolymerization, immerse the treated carbon-titanium electrode in 0.02mol / L (Prussian blue, PB) hydrochloric acid solution, the working potential is in the range of 0.03-0.9V, the sweep rate is 20mV / s, and the cycle voltage Scan for 10-20 circles, take it out, rinse it with deionized water, and make a PB carbon-titanium electrode;
[0037] (3) Dissolving the combined template molecule and AIBN in the porogen, adding a crosslinking agent and a monomer, and ultrasonicating for 10-20 minutes to form a uniform sol;
[0038] (4) Then use the dipping-pulling method to dip the matrix into...
experiment example
[0042]In order to detect different combinations of template molecules in carbon-titanium electrodes with a sandwich structure, and to explore the detection sensitivity and response time of the sensor, several combinations of template molecules will be selected below, and the combination of template molecules is (combination one (oxytetracycline: doxycycline Prime=1-2:2.1-3); Combination two (oxytetracycline: methacycline: doxycycline=3:2:1.2); Combination three (oxytetracycline: chlorotetracycline: dyramycin: A Oxytetracycline=1.5:2:1:3); Combination four (oxytetracycline: chlorotetracycline: methacycline: doxycycline=2:1:1:0.5).) to the same point to be tested samples Parallel testing is carried out, and the samples to be tested include an agricultural product A whose tetracycline content is known to be within a safe range and another agricultural product B whose tetracycline exceeds the standard; the test results are shown in the following table:
[0043] Table 1 Test result...
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