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Novel low-carbon low-silicon steel refining slag

A low-carbon, low-silicon, refining slag technology, applied in the field of iron and steel smelting, can solve the problems affecting the qualified rate of products, the reduction of molten steel yield, erosion, etc., to achieve the best inclusion adsorption capacity, improve the purity of molten steel, reduce Si increase Effect

Active Publication Date: 2017-09-19
RIZHAO STEEL HLDG GROUP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The refining slag of the prior art has a high TFe content, the yield of molten steel is reduced, the slag is highly oxidizable, and the deoxidation is not sufficient, which is not conducive to the adsorption of inclusions, and the CaO / Al in the slag 2 o 3 High value is not conducive to Al 2 o 3 The adsorption of inclusions, if simply increase the Al 2 o 3 content, it will cause the fluidity of the slag to increase sharply, so that the SiO 2 +Al→Si+Al 2 o 3 The reaction is obviously accelerated, and the Si increase in the steel is serious, so it cannot be used in low-carbon and low-silicon steel
At the same time, the MgO content is low, and the molten steel severely corrodes the refractory material of the ladle, resulting in an increase in the total oxygen content and excessive inclusions in the steel when producing tinplate substrate steel. Simply increasing MgO will increase the viscosity of the slag, thereby reducing the fluidity of the slag. It is conducive to the floating of inclusions, so it cannot be applied in low-carbon and low-silicon steel
At the same time, due to the large amount of calcium carbide, the refining process increases C by 0.018%, and the converter is forced to reduce the C content at the end point, which increases the blowing loss of the steel converter and increases the production cost.
The above existing problems seriously affect the qualified rate of products and cause economic losses to enterprises

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] The amount of raw materials to be added per ton of steel is: lime 9kg; aluminum particles 1.2kg; fluorite 0.9kg; calcium carbide 0.3kg; magnesium carbonate 1.3kg.

[0026] The chemical components of the refining slag are as follows: TFe: 0.56%, SiO 2 : 4.52%, CaO: 53.06%, MgO: 9.32%, Al 2 o 3 : 35.6%, MnO: 0.13%, TiO 2 : 0.13%, S: 0.46%, P 2 o 5 : 0.019%, the rest are unavoidable impurities; basicity R: 11.74.

[0027] Above-mentioned refining slagging process comprises the following steps:

[0028] (1) Ladle slag pre-melting:

[0029] During the tapping process of the converter, when 1 / 3 of the steel is tapped, 3kg / t lime and 0.6kg / t fluorite are added to the ladle to reduce the melting temperature of the ladle slag and prevent the ladle slag from crusting;

[0030] (2) Ladle slag argon station pre-deoxidation:

[0031] After the converter is tapped, after the molten steel enters the argon station, 0.4kg / t aluminum particles are evenly sprinkled on the slag sur...

Embodiment 2

[0041] The amount of raw materials to be added per ton of steel is: lime 8.5kg; aluminum particles: 1.35kg; fluorite: 0.8kg; calcium carbide 0.1kg; magnesium carbonate 1.42kg.

[0042] The chemical composition of the obtained refining slag is: TFe: 0.51%, SiO 2 : 4.52%, CaO: 50.12%, MgO: 11.19%, Al 2 o 3 : 35.8%, MnO: 0.14%, TiO 2 : 0.15%, S: 0.42%, P 2 o 5 : 0.015%, the rest are unavoidable impurities, basicity R: 11.0.

[0043] Above-mentioned refining slagging process comprises the following steps:

[0044] (1) Ladle slag pre-melting:

[0045] During the tapping process of the converter, when 1 / 3 of the steel is tapped, 3kg / t lime and 0.6kg / t fluorite are added to the ladle to reduce the melting temperature of the ladle slag and prevent the ladle slag from crusting;

[0046] (2) Ladle slag argon station pre-deoxidation:

[0047] After the converter is tapped, after the molten steel enters the argon station, 0.45kg / t aluminum particles are evenly sprinkled on the sla...

Embodiment 3

[0057] The amount of raw materials to be added per ton of steel is: lime 9.5kg; aluminum particles: 1.5kg; fluorite: 0.7kg; calcium carbide 0kg; magnesium carbonate 1.5kg.

[0058] The chemical composition of the obtained refining slag is: TFe: 0.45%, SiO 2 : 4.51%, CaO: 54.15%, MgO: 10.31%, Al 2 o 3 : 36.1%, MnO: 0.12%, TiO 2 : 0.14%, S: 0.32%, P 2 o 5 : 0.015%, the rest are unavoidable impurities; basicity R: 12.

[0059] Above-mentioned refining slagging process comprises the following steps:

[0060] (1) Ladle slag pre-melting:

[0061] During the converter process, when 1 / 3 of the steel is tapped, 3kg / t lime and 0.6kg / t fluorite are added to the ladle to reduce the melting temperature of the ladle slag and prevent the ladle slag from crusting;

[0062] (2) Ladle slag argon station pre-deoxidation:

[0063] After the converter is tapped, after the molten steel enters the argon station, 0.5kg / t aluminum particles are evenly sprinkled on the slag surface of the ladle...

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Abstract

The invention discloses novel low-carbon low-silicon steel refining slag. Raw materials comprise lime, aluminum particles, fluorite, calcium carbide and magnesium carbonate. The chemical constituents of the refining slag comprise 0.45%-0.56% of TFe, 4.51%-4.52% of SiO2, 50.12%-54.15% of CaO, 9.32%-11.19% of MgO, 35.6%-36.1% of Al2O3, 0.12%-0.14% of MnO, 0.13%-0.15% of TiO2, 0.32%-0.46% of S, 0.015%-0.019% of P2O5 and the balance inevitable impurities. Compared with the prior art, the novel low-carbon low-silicon steel refining slag has the advantages of being low in cost and stable in product quality.

Description

technical field [0001] The invention relates to the field of iron and steel smelting, in particular to a novel low-carbon and low-silicon steel refining slag. Background technique [0002] Tinplate, also known as tinplate, is a tinplated steel product whose substrate is low-carbon low-silicon steel plate and steel strip. Tinplate is widely used in canning, packaging materials, stamping containers and other industries. The chemical composition, grain size, precipitation of solid-dissolved carbon and nitrogen, and flatness of the tinplate substrate are the main factors affecting the hardness and wrinkle resistance of the tinplate substrate; the tinplate (RGMR2) substrate is low-silicon and low-carbon steel. The composition requires that the carbon content is less than 0.04%, the silicon is less than 0.03%, the inclusions are controlled to be less than 0.04 / m2 through refining, and the particle size is less than 20μm. Refining slag in the refining process is the main method to...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21C7/076C21C7/068C21C7/06C21C1/08C22C33/08
CPCC21C1/08C21C7/06C21C7/068C21C7/076C22C33/08Y02P10/20
Inventor 蒲锐孙作迎周永志齐士兵王岩
Owner RIZHAO STEEL HLDG GROUP