Environment-friendly repeated-writing paper and preparation method therefor

A writing paper, environmentally friendly technology, applied in the direction of paper, papermaking, paper coating, etc., to achieve moderate ink absorption uniformity and adhesion, enhance writing performance, and enhance writing clarity.

Active Publication Date: 2017-10-03
BEIJING GUANLAN TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0017] The technical problem solved by the present invention is to overcome the defect of existing repeated writing paper, add hydroxyl protecting group to the nano bacterial cellulose suspension with excellent characteristics such as strong water absorption and water holding capacity, good water permeability and air permeability, etc. Under alkaline conditions, react in stages to make the bacterial cellulose achieve moderate water absorption and water holding capacity; then add a dispersant and use ultrasonic and high-voltage pulse electric field to disperse to obtain a stable and uniform modified bacterial cellulose suspension; finally It is coated on the surface of the base paper to obtain a writing paper with moderate ink absorption uniformity and adhesion, and a dense structure, which can enhance the writing performance of the writing paper; it can also play a waterproof and oil-proof role. Under the condition of not affecting the performance of the paper, the ink on the paper can be wiped off with a cleaning agent, and it can be used repeatedly

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0052] A preparation method of environmentally friendly repetitive writing paper includes the following steps:

[0053] 1) The bacterial cellulose with a water content of 98.7% obtained by fermentation is cleaned and crushed into a bacterial cellulose suspension with a particle size of 70 nm;

[0054] 2) Add the hydroxyl protecting group 2.5 times the dry weight of bacterial cellulose to the bacterial cellulose suspension, mix evenly, adjust the pH of the mixture to 12, first react at room temperature for 0.8 hours, and then react at 70°C for 4 hours , The stirring speed of the whole reaction process is 150rpm; after the reaction, centrifuge at 10000rpm for 30min to separate the supernatant A; add deionized water 100 times its dry weight to the precipitate A, stir evenly, at 10000rpm Centrifuge and wash for 30 minutes at the rotating speed, repeat the above centrifugal washing process until the supernatant is neutral, and separate the supernatant B; add deionized water 80 times its...

Embodiment 2

[0080] A preparation method of environmentally friendly repetitive writing paper includes the following steps:

[0081] 1) Wash the bacterial cellulose with 98% water content obtained by fermentation, and pulverize it into a bacterial cellulose suspension with a particle size of 40 nm;

[0082] 2) Add the hydroxyl protecting group 1.5 times the dry weight of bacterial cellulose to the bacterial cellulose suspension, mix evenly, adjust the pH of the mixture to 11, first react at room temperature for 0.5h, and then react at 60℃ for 3h , The stirring speed of the whole reaction process was 100 rpm; after the reaction, the supernatant A was separated by centrifugal separation at 8000 rpm for 20 min; the precipitate A was added with deionized water 100 times its dry weight and stirred evenly at 8000 rpm Centrifuge and wash for 20 minutes at the rotating speed, repeat the above centrifugal washing process until the supernatant is neutral, and separate the supernatant B; add deionized wat...

Embodiment 3

[0111] A preparation method of environmentally friendly repetitive writing paper includes the following steps:

[0112] 1) Wash the bacterial cellulose with a water content of 99.5% obtained by fermentation, and crush it into a bacterial cellulose suspension with a particle size of 100 nm;

[0113] 2) Add 3 times the dry weight of the bacterial cellulose to the bacterial cellulose suspension with a hydroxyl protecting group, mix uniformly, adjust the pH of the mixture to 13, and first react at room temperature for 1 hour, and then at 80°C for 5 hours, The stirring speed of the whole reaction process was 200 rpm; after the reaction, the supernatant A was separated by centrifugal separation at 12000 rpm for 40 minutes; deionized water of 100 times its dry weight was added to the precipitate A, and stirred evenly at a speed of 12000 rpm Centrifuge and wash for 40 minutes, repeat the above centrifugal washing process until the supernatant is neutral, and separate the supernatant B; add...

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Abstract

The invention discloses environment-friendly repeated-writing paper and a preparation method therefor. According to the environment-friendly repeated-writing paper and the preparation method therefor, a hydroxyl protective group is added into a nano bacterial cellulose suspension with excellent characteristics such as high water absorptivity and water retention ability and good water and air permeability, so as to lower hydrophilicity; a staged reaction is carried out under strong base conditions, so that bacterial cellulose reaches moderate water absorptivity and water retention ability, ink can only be present in a surface layer and be clear in writing while the ink is absorbed, and thus, writing, reading and subsequent handwriting wiping are facilitated; then, a scientifically-compounded dispersant is added, and ultrasonic and high-voltage pulse electric field combined dispersion is carried out, so that a stable and uniform modified bacterial cellulose suspension is obtained; finally, the surface of raw paper is coated with the suspension so as to obtain the writing paper with appropriate ink absorbing uniformity and adhesive power and a dense structure, thus, the writing property of the writing paper can be enhanced, and the clearness of writing is enhanced; and waterproofing and oil-proofing actions can be achieved, most importantly, ink marks on the paper can be erased with a cleanser and the paper can be reused for 40 to 100 times under the condition that the performance of the paper is not affected.

Description

Technical field [0001] The invention relates to repetitive writing paper, in particular to an environmentally friendly repetitive writing paper and a preparation method thereof. Background technique [0002] Paper is one of the main consumables indispensable in our daily life and work. The survey shows that about 40% of printed or copied paper is thrown into the waste paper basket after reading it once, which not only causes a huge waste of resources, but also damages the environment. Therefore, how to reduce the consumption of resources by the paper industry, reduce the damage of the paper industry to the environment, and realize the sustainable development strategy has become a topic of increasing concern by the government and society. [0003] Repetitive writing paper can be used multiple times and repeatedly to reduce paper waste and accelerate the process of sustainable development and environmental protection. At present, there are two main types of research on repetitive w...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D21H11/00D21H15/10D21H21/18D21H17/37D21H23/50D21H19/12D21H21/16D21H21/14D21H21/08C08B15/00
CPCC08B15/00D21H11/00D21H15/10D21H17/37D21H19/12D21H21/08D21H21/14D21H21/16D21H21/18D21H23/50
Inventor 陈文洁金晶段得振张志钊郝华璇
Owner BEIJING GUANLAN TECH
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