Environment-friendly repeated-writing paper and preparation method therefor
A writing paper, environmentally friendly technology, applied in the direction of paper, papermaking, paper coating, etc., to achieve moderate ink absorption uniformity and adhesion, enhance writing performance, and enhance writing clarity.
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Embodiment 1
[0052] A preparation method of environmentally friendly repetitive writing paper includes the following steps:
[0053] 1) The bacterial cellulose with a water content of 98.7% obtained by fermentation is cleaned and crushed into a bacterial cellulose suspension with a particle size of 70 nm;
[0054] 2) Add the hydroxyl protecting group 2.5 times the dry weight of bacterial cellulose to the bacterial cellulose suspension, mix evenly, adjust the pH of the mixture to 12, first react at room temperature for 0.8 hours, and then react at 70°C for 4 hours , The stirring speed of the whole reaction process is 150rpm; after the reaction, centrifuge at 10000rpm for 30min to separate the supernatant A; add deionized water 100 times its dry weight to the precipitate A, stir evenly, at 10000rpm Centrifuge and wash for 30 minutes at the rotating speed, repeat the above centrifugal washing process until the supernatant is neutral, and separate the supernatant B; add deionized water 80 times its...
Embodiment 2
[0080] A preparation method of environmentally friendly repetitive writing paper includes the following steps:
[0081] 1) Wash the bacterial cellulose with 98% water content obtained by fermentation, and pulverize it into a bacterial cellulose suspension with a particle size of 40 nm;
[0082] 2) Add the hydroxyl protecting group 1.5 times the dry weight of bacterial cellulose to the bacterial cellulose suspension, mix evenly, adjust the pH of the mixture to 11, first react at room temperature for 0.5h, and then react at 60℃ for 3h , The stirring speed of the whole reaction process was 100 rpm; after the reaction, the supernatant A was separated by centrifugal separation at 8000 rpm for 20 min; the precipitate A was added with deionized water 100 times its dry weight and stirred evenly at 8000 rpm Centrifuge and wash for 20 minutes at the rotating speed, repeat the above centrifugal washing process until the supernatant is neutral, and separate the supernatant B; add deionized wat...
Embodiment 3
[0111] A preparation method of environmentally friendly repetitive writing paper includes the following steps:
[0112] 1) Wash the bacterial cellulose with a water content of 99.5% obtained by fermentation, and crush it into a bacterial cellulose suspension with a particle size of 100 nm;
[0113] 2) Add 3 times the dry weight of the bacterial cellulose to the bacterial cellulose suspension with a hydroxyl protecting group, mix uniformly, adjust the pH of the mixture to 13, and first react at room temperature for 1 hour, and then at 80°C for 5 hours, The stirring speed of the whole reaction process was 200 rpm; after the reaction, the supernatant A was separated by centrifugal separation at 12000 rpm for 40 minutes; deionized water of 100 times its dry weight was added to the precipitate A, and stirred evenly at a speed of 12000 rpm Centrifuge and wash for 40 minutes, repeat the above centrifugal washing process until the supernatant is neutral, and separate the supernatant B; add...
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