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A kind of polyurethane foaming agent with enhanced function and preparation method thereof

A technology of polyurethane foaming agent and enhanced function, which is applied in the field of polyurethane foaming agent, and can solve the problems of affecting performance, low storage stability of foaming resin composition, affecting uniformity and dispersibility of microcapsule foaming agent, etc. , to achieve the effect of controlling the foaming rate, controllable foaming and uniform stability

Active Publication Date: 2020-07-21
BEIJING KEYING JINGYI TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Above-mentioned two kinds of methods all adopt acidic reaction condition, the adding of acidic substance can reduce the stability of suspending agent silicon dioxide and influence the homogeneity and the dispersibility of microcapsule blowing agent
Moreover, the polymerization reaction under acidic conditions often causes the decomposition of some monomers such as vinylidene chloride, so that the formed microcapsule foaming agent product is relatively acidic (PH<4). The storage stability of the foamed resin composition prepared by the agent is low, and affects the performance
[0008] In practical engineering applications, technical indicators such as bending strength and impact strength of PUR foam cannot meet the requirements of use, which limits its wide application. Therefore, it needs to be enhanced and modified to make up for the shortage of materials and further improve its mechanical properties.

Method used

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  • A kind of polyurethane foaming agent with enhanced function and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0027] A polyurethane foaming agent with enhanced functions, comprising ethyl cellulose capsules and a core material wrapped inside ethyl cellulose;

[0028] The core material includes calcium sulfate whiskers and water.

[0029] The core material comprises the following parts by weight of 80 parts of inorganic whiskers and 20 parts of water.

[0030] The weight ratio of the ethyl cellulose capsule to the core material is 1:5.

[0031] A kind of preparation method of the polyurethane blowing agent with enhanced function, comprises the following steps:

[0032] (1) After mixing water and inorganic whiskers evenly, the water and inorganic whiskers can be well loaded and fixed;

[0033] (2) Make ethyl cellulose and solvent into a liquid, and then wrap the prefabricated material in step (1) in a fluidized bed, dry, and age, and the aging time is 5 hours. The aging temperature is 30-40° C. to obtain a microcapsule foaming agent coated with ethyl cellulose and inorganic whiskers ...

Embodiment 2

[0037] A polyurethane foaming agent with enhanced functions, comprising ethyl cellulose capsules and a core material wrapped inside ethyl cellulose;

[0038] The core material includes silicon carbide whiskers and water.

[0039] The core material comprises the following parts by weight of 90 parts of inorganic whiskers and 10 parts of water.

[0040] The weight ratio of the ethyl cellulose capsule to the core material is 1:10.

[0041] A kind of preparation method of the polyurethane blowing agent with enhanced function, comprises the following steps:

[0042] (1) After mixing water and inorganic whiskers evenly, the water and inorganic whiskers can be well loaded and fixed;

[0043](2) Make ethyl cellulose and solvent into a liquid, and then wrap the prefabricated material in step (1) in a fluidized bed, dry, and age. The aging time is 10 hours. The aging temperature is 30-40° C. to obtain a microcapsule foaming agent coated with ethyl cellulose and inorganic whiskers and...

Embodiment 3

[0047] A polyurethane foaming agent with enhanced functions, comprising ethyl cellulose capsules and a core material wrapped inside ethyl cellulose;

[0048] The core material includes zinc oxide whiskers and water.

[0049] The core material comprises the following parts by weight of 85 parts of inorganic whiskers and 15 parts of water.

[0050] The weight ratio of the ethyl cellulose capsule to the core material is 1:15.

[0051] A kind of preparation method of the polyurethane blowing agent with enhanced function, comprises the following steps:

[0052] (1) After mixing water and inorganic whiskers evenly, the water and inorganic whiskers can be well loaded and fixed;

[0053] (2) Make ethyl cellulose and solvent into a liquid, and then wrap the prefabricated material in step (1) in a fluidized bed, dry, and age. The aging time is 20 hours. The aging temperature is 30-40 DEG C, and the microcapsule foaming agent coated with ethyl cellulose and inorganic whiskers and wate...

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Abstract

The present invention relates to the technical field of polyurethane foaming agents, particularly to a polyurethane foaming agent having an enhancement function, and a preparation method thereof. According to the present invention, the polyurethane foaming agent is a capsule blowing agent formed from an ethyl cellulose capsule, water and inorganic crystal whiskers, wherein the water and the inorganic crystal whiskers are wrapped in the ethyl cellulose; when the polyurethane foaming agent is used for foaming polyurethane, the ethyl cellulose is slowly dissolved by an organic solvent, the inner core water contained in the ethyl cellulose is subjected to a reaction to produce foams, and further the inorganic crystal whiskers are uniformly dispersed in the polyurethane foams through foam expansion diffusion, such that the enhancement effect is provided, and the foaming rate can be controlled so as to achieve the controlled, uniform and stable polyurethane water foaming.

Description

technical field [0001] The invention relates to the technical field of polyurethane foaming agents, in particular to a polyurethane foaming agent with enhanced functions and a preparation method. Background technique [0002] Polyurethane (PU) foam is one of the most commonly used plastics at present. It is estimated that the global annual demand is about 5 million tons, most of which are polyurethane soft foam and hard foam. The PU foam material is extremely flammable in the air, and produces a large amount of toxic gas and smoke when burning. Therefore, foreign countries have paid great attention to the flame retardancy of PU foam materials, and promulgated many regulations and standards on flame retardancy. In my country, although there are no regulations on PU foam flame retardancy, in fact, in recent years, the polyurethane foam used in aircraft, ships, railway vehicles, automobiles, other important industry parts, equipment and some places has proposed regulations. Fl...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08J9/08C08L75/04C08K7/08C08K7/10
CPCC08J9/08C08J2375/04C08K7/08C08K7/10C08L75/04
Inventor 陈庆曾军堂陈兵
Owner BEIJING KEYING JINGYI TECH
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