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A kind of low-density inorganic fiber reinforcement and preparation method thereof

An inorganic fiber, low density technology, applied in the field of inorganic fiber reinforcement and its preparation, can solve the problems of many overlapping points of fibers, high density of inorganic fiber mat, increase the density and quality of final material, etc. Thermal conductivity, uniform fiber dispersion, effect of reducing thermal conductivity

Inactive Publication Date: 2019-12-20
CHINA ACADEMY OF SPACE TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, the silica airgel material has low strength and high brittleness, and is easy to crack or break when used. In order to improve the strength of the silica airgel material, inorganic fibers are usually added to the airgel material matrix to form an inorganic fiber composite. Silica airgel material, this fiber composite airgel material has good mechanical properties, for example, the United States NASA reported the use of glass fiber composite silica airgel insulation felt material, the strength can reach 3MPa
However, due to the high density of the inorganic fiber mat used in this inorganic fiber composite silica airgel material, 0.1-0.2g / cm 3 , which increases the density and quality of the final material, and there are more overlapping points of fibers in the fiber mat, which increases the thermal conductivity of the final material and reduces the heat insulation effect

Method used

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  • A kind of low-density inorganic fiber reinforcement and preparation method thereof
  • A kind of low-density inorganic fiber reinforcement and preparation method thereof
  • A kind of low-density inorganic fiber reinforcement and preparation method thereof

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preparation example Construction

[0034] An embodiment of the present invention provides a method for preparing a low-density fiber reinforced body, comprising the following steps:

[0035] Step 1: Put fibers with a diameter of 5-10 μm and a length of 3-15 cm into deionized water to form a fiber suspension with a fiber content of 2-10 g / L;

[0036] Specifically, in the embodiment of the present invention, the fiber may be an inorganic fiber such as glass fiber, quartz fiber, alumina fiber, preferably glass fiber, and the diameter of the fiber is an equivalent diameter;

[0037] In order to obtain inorganic fibers uniformly dispersed in three-dimensional directions, in the embodiment of the present invention, the preparation method of the fibers with a diameter of 5-10 μm and a length of 3-15 cm includes the following steps:

[0038] Step a: if figure 1 As shown, the fiber mat with a fiber diameter of 5-10 μm is cut into a small fiber mat with a side length of 3-15 cm;

[0039] Step b: Stir and disperse the s...

Embodiment 1

[0056] First, cut the purchased glass fiber mat into small pieces of 5*5cm with scissors. Add an appropriate amount of hydrochloric acid to the deionized water, so that the concentration of hydrochloric acid in the solution is 0.05mol / L, and use a mechanical stirrer to stir for 30 minutes to obtain a preliminary dispersed glass fiber suspension.

[0057] Then use gauze to filter the glass fiber suspension to remove impurities such as solid particles therein, and put the filtered glass fiber into an oven at 60° C. to dry for 8 hours to obtain pure and dry glass fiber.

[0058] Use an electronic balance to take 2g of dried glass fiber, put it into an ultrasonic pool, then add 1L of deionized water, the concentration of glass fiber is 2g / L, and then add 0.002mol of tetraethyl orthosilicate, and ultrasonically disperse for 20 minutes to obtain a glass Mixing system with evenly dispersed fibers;

[0059] Then pour the mixed system in which the glass fibers are evenly dispersed int...

Embodiment 2

[0062] First, cut the purchased glass fiber felt into 3*3cm pieces with scissors. The fiber diameter of the fiber felt is 5-10μm, then put the cut 3*3cm pieces into deionized water, and pour them into deionized water. Add an appropriate amount of hydrochloric acid to the water to make the concentration of hydrochloric acid in the solution 0.05mol / L, and use a mechanical stirrer to stir for 20 minutes to obtain a preliminary dispersed glass fiber suspension.

[0063] Then use gauze to filter the glass fiber suspension to remove impurities such as solid particles therein, and put the filtered glass fiber into an oven at 60° C. to dry for 8 hours to obtain pure and dry glass fiber.

[0064] Use an electronic balance to take 5g of dried glass fiber, put it into the ultrasonic tank, add 1L of deionized water, the glass fiber concentration is 5g / L, and then add 0.005mol tetraethyl orthosilicate, and ultrasonically disperse for 30 minutes to obtain glass fiber Uniformly dispersed mix...

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Abstract

The invention relates to low-density inorganic fiber reinforcement and a preparation method thereof, which belong to the field of inorganic material preparation. The preparation method comprises the following steps: adding fiber with the diameter being 5-10 [mu]m and length being 3-15 cm in deionized water to form a fibrous suspension with the fiber content being 2-10 g / L; adding a cross-linking agent in the fibrous suspension, performing ultrasonic dispersion to obtain a mixing system with uniformly dispersed fiber, wherein the concentration of the cross-linking agent is 0.002-0.001 mol / L; refrigerating the mixing system with uniformly dispersed fiber to obtain a frozen mixing system; and performing freeze drying on the frozen mixing system to obtain the low-density inorganic fiber reinforcement. The density of the low-density inorganic fiber reinforcement can reach 2 mg / cm<3>, the glass fibers are uniformly dispersed, an aggregation phenomenon is not generated among the fibers, and the overlapping points among the fibers are little.

Description

technical field [0001] The invention relates to a low-density inorganic fiber reinforcement and a preparation method thereof, belonging to the field of inorganic material preparation. Background technique [0002] Silica airgel material has an extremely low density, the lowest is about 0.003g / cm 3 , which is only 3 times the density of air in the standard state, and the thermal conductivity under normal temperature and pressure conditions is about 0.013W / (m K), which is 4 to 5 times lower than the thermal conductivity of traditional inorganic insulation materials. Excellent thermal insulation materials can be used as thermal insulation and thermal insulation materials in aerospace, petrochemical, construction, transportation and low temperature and other fields. Due to its technological advancement, it has been used in high-tech fields such as aerospace. [0003] However, the silica airgel material has low strength and high brittleness, and is easy to crack or break when us...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B20/02
CPCC04B20/023C04B24/42C04B14/4625C04B14/42C04B14/4618
Inventor 崔方明
Owner CHINA ACADEMY OF SPACE TECHNOLOGY