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Active cathode material for uninterruptible power supply and preparation method thereof

A positive electrode active material and power supply technology, which is applied in the direction of battery electrodes, circuits, electrical components, etc., can solve the problem of battery charge acceptance, high current starting and discharging performance, deep cycle life is not ideal, and cannot meet the requirements of high power and large capacity UPS uninterrupted Power supply requirements, active material binding force, low utilization rate and other issues, to achieve the effect of improving charge acceptance, inhibiting battery dehydration, and improving composite reaction ability

Inactive Publication Date: 2017-11-24
HEFEI TONGYOU ELECTRONICS TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The existing active materials of this kind are mainly composed of lead powder, polypropylene fiber, sulfuric acid, and deionized water. , The utilization rate is not high, and the conductivity is poor, which leads to the unsatisfactory charging acceptance capacity, high-current starting and discharging performance and deep cycle life of the manufactured battery, which cannot meet the requirements of high-power and large-capacity UPS uninterruptible power supply.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A positive electrode active material for an uninterruptible power supply, comprising the following raw materials by weight: 250g of free lead, 430g of lead oxide, 280g of lead dioxide, 80g of aluminum oxide, 6g of polypropylene fiber, 16g of glass fiber, 10g of antimony trioxide, Sulfuric acid 80g, perfluorinated solvent 70g, deionized water 200g. Perfluorinated solvents are alkanes, ethers or amines in which all hydrogen atoms on carbon atoms are replaced by fluorine atoms.

[0022] The preparation method of the positive electrode active material for the above-mentioned uninterruptible power supply comprises the following steps:

[0023] (1) Ball milling: Weigh free lead, lead oxide, and lead dioxide according to weight, mix and stir evenly, and pass it into a pulverizer to pulverize into particles with a particle size of 0.2-0.6 mm, and then add them to a ball mill for ball milling to obtain fine powder; , Ball milling is carried out under an oxygen atmosphere, and t...

Embodiment 2

[0027] A positive electrode active material for an uninterruptible power supply, comprising the following raw materials by weight: 236g of free lead, 385g of lead oxide, 258g of lead dioxide, 86g of aluminum oxide, 3g of polypropylene fiber, 1.6g of glass fiber, and 17g of antimony trioxide , sulfuric acid 86g, perfluorinated solvent 72g, deionized water 156g. Perfluorinated solvents are alkanes, ethers or amines in which all hydrogen atoms on carbon atoms are replaced by fluorine atoms.

[0028] The preparation method of the positive electrode active material for the above-mentioned uninterruptible power supply comprises the following steps:

[0029] (1) Ball milling: Weigh free lead, lead oxide, and lead dioxide according to weight, mix and stir evenly, and pass it into a pulverizer to pulverize into particles with a particle size of 0.2-0.6 mm, and then add them to a ball mill for ball milling to obtain fine powder; , Ball milling is carried out under an oxygen atmosphere,...

Embodiment 3

[0033] A positive electrode active material for an uninterruptible power supply, comprising the following raw materials by weight: 245g of free lead, 415g of lead oxide, 275g of lead dioxide, 92g of aluminum oxide, 6g of polypropylene fiber, 14g of glass fiber, 25g of antimony trioxide, Sulfuric acid 75g, perfluorinated solvent 86g, deionized water 180g. Perfluorinated solvents are alkanes, ethers or amines in which all hydrogen atoms on carbon atoms are replaced by fluorine atoms.

[0034] The preparation method of the positive electrode active material for the above-mentioned uninterruptible power supply comprises the following steps:

[0035] (1) Ball milling: Weigh free lead, lead oxide, and lead dioxide according to weight, mix and stir evenly, and pass it into a pulverizer to pulverize into particles with a particle size of 0.2-0.6 mm, and then add them to a ball mill for ball milling to obtain fine powder; , Ball milling is carried out under an oxygen atmosphere, and t...

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PUM

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Abstract

The invention discloses an active cathode material for an uninterruptible power supply and a preparation method thereof. The active cathode material comprises the following raw materials in parts by weight: 20-30 parts of free lead, 30-50 parts of lead oxide, 20-35 parts of lead dioxide, 5-15 parts of aluminium oxide, 0.2-0.8 part of polypropylene fibers, 0.5-2.5 parts of glass fibers, 1-3 parts of antimonous oxide, 5-15 parts of sulfuric acid, 5-10 parts of a perfluor solvent and 10-26 parts of deionized water. The preparation method comprises the steps of ball milling, preparation of a precursor mixture and heat treatment. The active cathode material is high in capacity and long in cycle life, the energy density of the conventional uninterruptible power supply is improved, the high-temperature performance and the rate capability of the active cathode material are improved, a precursor synthetic method is simple, industrialization is easy, the cost of the cathode material of an uninterruptible power cell is reduced, and a very high popularization value is achieved.

Description

technical field [0001] The invention relates to the field of battery materials, in particular to a positive electrode active material for an uninterruptible power supply and a preparation method thereof. Background technique [0002] With the development of science and technology, information technology plays an increasingly important role in human society, especially in the military and communication fields. In information technology, UPS uninterruptible power supply is widely used, and lead-acid battery for UPS uninterruptible power supply needs to have high current starting discharge and deep cycle discharge performance, which puts forward higher requirements for the positive electrode active material of the battery. The existing active materials of this kind are mainly composed of lead powder, polypropylene fiber, sulfuric acid, and deionized water. , The utilization rate is not high, and the conductivity is poor, which leads to the unsatisfactory charging acceptance ca...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/36H01M4/56H01M4/62H01M10/06
CPCH01M4/362H01M4/56H01M4/62H01M10/06Y02E60/10
Inventor 李丹丹
Owner HEFEI TONGYOU ELECTRONICS TECH CO LTD
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