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A kind of preparation method of wax for paper packaging material

A technology for packaging materials and raw materials, which is applied in petroleum wax refining, petroleum wax recycling, wax physical treatment, etc., can solve the problems of decreased product yield, prolonged sweating time, and low product yield.

Active Publication Date: 2019-06-18
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0012] Ordinary sweating separation process can produce soap wax and low melting point paraffin wax with coarse flaky crystal structure in the solid state with a melting point of 40 ℃ ~ 60 ℃, but for the ordinary sweating separation method, the solid components (higher melting point Waxes) and liquid components (oil and lower melting point waxes) are in solid and liquid phases respectively, but it is difficult to completely separate them
In order to make the oil content of the final product meet the requirements, the method of prolonging the sweating time and raising the sweating termination temperature is usually adopted, but this will lead to a long production cycle and a decrease in product yield
[0013] Compared with solvent separation, the sweating process is an intermittent operation, and the product yield is lower and the production cycle is longer, but the sweating process has the advantages of less investment, simple production process, low operating cost, safe production process, energy saving and no pollution to the environment, etc. Advantages, some manufacturers are still using this method to produce soap wax products
[0014] Over the years, the sweating method has been developed in terms of production equipment and technology, such as CN89214332 (vertical square multi-section sweating tank), CN94223980.6 (dish-type sweating device), CN98233254.8 (paraffin sweating tank), CN200920033500. X (new paraffin sweating tank), CN201210508905.0 (a high-efficiency paraffin sweating device), CN201320127680.4 (tubular paraffin deoiling device), etc., have made improvements in sweating production equipment; CN91206202 (a high-efficiency paraffin sweating tank ) has improved the sweating process, but there are still shortcomings such as long production cycle and low product yield

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0054] This embodiment includes two parts: (A) emulsification and (B) sweating.

[0055] (A) emulsification

[0056] This part includes (A1) oil phase material preparation, (A2) water phase material preparation, (A3) emulsion preparation three steps.

[0057](A1) Oil phase material preparation

[0058] take 58 # Semi-refined wax (Sinopec Gaoqiao Branch, melting point 59.1°C, oil content 1.52%, sticking point temperature 35.7°C) 78.0Kg, heat to 75°C and add 2.0Kg of sorbitan monostearate, diethyl Diol monolaurate 0.9Kg and lauryl betaine 0.7Kg, stir well.

[0059] (A2) Preparation of aqueous phase materials

[0060] 0.15Kg of CO at 20.1 to 20.3 atmospheres 2 Dissolve in 18.25Kg of water and heat to 80°C.

[0061] (A3) Emulsion preparation

[0062] Pressurize the oil-phase material to 20.1-20.3 atmospheres, and stir at a speed of 600r / min; add the water-phase material prepared in (A2) to the oil-phase material prepared in (A1), and continue stirring for 25 minutes to form...

Embodiment 2

[0079] This embodiment includes two parts: (A) emulsification and (B) sweating.

[0080] (A) emulsification

[0081] This part includes (A1) oil phase material preparation, (A2) water phase material preparation, (A3) emulsion preparation three steps.

[0082] (A1) Oil phase material preparation

[0083] take 58 # Semi-refined wax (same as Example 1) 81.0Kg, heated to 80°C and melted, added 2.6Kg of sorbitan monooleate, 1.0Kg of sorbitan monolaurate and 0.6Kg of triacetamide oleate, Stir well.

[0084] (A2) Preparation of aqueous phase materials

[0085] With 27.5% H 2 o 2 solution, solid KOH and H 2 O formulated with H 2 o 2 0.6%, KOH 2.5 mg / Kg aqueous solution, take 14.8Kg, pressurize to 22.8-23.0 atmospheres under nitrogen condition, and heat to 85°C.

[0086] (A3) Emulsion preparation

[0087] Pressurize the oil phase material to 22.8-23.0 atmospheres under nitrogen, and stir at a speed of 300r / min; add the water phase material prepared in (A2) to the oil phase ...

Embodiment 3

[0093] This embodiment includes two parts: (A) emulsification and (B) sweating.

[0094] (A) emulsification

[0095] This part includes (A1) oil phase material preparation, (A2) water phase material preparation, (A3) emulsion preparation three steps.

[0096] (A1) Oil phase material preparation

[0097] take 58 # Semi-refined wax (same as Example 1) 82.5Kg, heated to 71°C and melted, then added 2.0Kg of sorbitan monostearate, 0.5Kg of sorbitan monopalmitate and 0.3 Kg of sodium oleamide carboxylate , stir well.

[0098] (A2) Preparation of aqueous phase materials

[0099] With 27.5% H 2 o 2 solution, solid NaOH and H 2 O formulated with H 2 o 2 1.6%, NaOH 6.6 mg / Kg aqueous solution, take 14.7Kg, pressurize to 28.5-28.7 atmospheric pressure under nitrogen condition, and heat to 78°C.

[0100] (A3) Emulsion preparation

[0101] Pressurize the oil phase material to 28.5-28.7 atmospheres under nitrogen, and stir at a speed of 400r / min; add the water phase material prep...

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Abstract

The invention discloses a method for preparing wax for a paper packaging material. The method utilizes paraffin as a raw material and produces a desired product through sweating. Based on the ordinary sweating method, airflows pass through a wax layer and carry away a liquid component in the sweating process so that a solid component and the liquid component are forcibly separated, and preferably, the raw material wax and a water solution containing a substance decomposable into gas are emulsified so that the liquid component can be fast discharged. The method has the advantages of low equipment investment, simple production process, low operation cost, safety, energy saving and no solvent pollution. The product can be used as wax for a paper packaging material.

Description

technical field [0001] The invention belongs to the technical field of special wax production, in particular to a preparation method of wax for paper packaging materials. Background technique [0002] The use of wax to process paper packaging materials has a long history, which utilizes the lubricating, waterproof, strength, gloss and other performance properties of wax. Similar substances also have the characteristics of anti-odor, fragrance retention, and meeting FDA requirements. [0003] When wax-processed paper products are stacked or rolled together for storage, due to the effects of temperature, time, and pressure, there will be a natural sticking phenomenon between paper and paper, which is called "hardening" (commonly known as adhesion). The main factors that cause hardening of packaging paper products are the melting point, chemical composition and oil content of the selected wax. This is an important issue that should be paid special attention to when processing ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G73/36C10G73/42C10G73/40
CPCC10G73/36C10G73/40C10G73/42
Inventor 孙剑锋赵永鹤毕文卓陈保莲孙鹏何凤友
Owner CHINA PETROLEUM & CHEM CORP