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Bio-based porous carbon reinforced modification polyurethane composite material

A composite material and porous carbon technology, applied in the field of composite materials, can solve the problems of poor thermal conductivity and thermal stability, low friction coefficient and high wear amount, and achieve the effects of excellent mechanical properties, simple processing technology and improved tensile strength.

Inactive Publication Date: 2017-12-29
INT CENT FOR BAMBOO & RATTAN +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The soft segment of polyurethane elastomer determines the flexibility and toughness of the material, and the hard segment determines the strength and rigidity of the material. However, there is an obvious phase separation between the soft and hard segment. Therefore, the pure polyurethane material prepared by conventional methods and formulas has relatively low rigidity, thermal conductivity and thermal stability. Poor performance, low friction coefficient but high wear, it needs to be modified to meet engineering requirements

Method used

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  • Bio-based porous carbon reinforced modification polyurethane composite material
  • Bio-based porous carbon reinforced modification polyurethane composite material
  • Bio-based porous carbon reinforced modification polyurethane composite material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] A bio-based porous carbon reinforced modified polyurethane composite material, characterized in that: in parts by weight, including 31 parts of polypropylene glycol, 36 parts of isophorone diisocyanate, 18 parts of 3,3'-dichloro-4, 4'-diaminodiphenylmethane, 1 part bio-based porous carbon, 3-10 coupling agents.

[0016] The molecular weight of polypropylene glycol is 2000.

[0017] The bio-based porous carbon is bamboo carbon, and the specific surface area of ​​the carbon material is 1500m 2 / g.

[0018] The coupling agent is γ-aminopropyltriethoxysilane.

[0019] Stir the dehydrated polypropylene glycol and bio-based porous carbon mechanically at 800 rpm for 10 minutes, add isophorone diisocyanate, react at 100-110°C for 3-6 hours, add coupling agent, 3,3'- The dichloro-4,4'-diaminodiphenylmethane is stirred for 10 to 30 seconds, pressurized and vulcanized, and demolded to obtain a bio-based porous carbon reinforced and modified polyurethane composite material.

Embodiment 2

[0021] A bio-based porous carbon reinforced modified polyurethane composite material, characterized in that: in parts by weight, including 31 parts of polypropylene glycol, 36 parts of isophorone diisocyanate, 18 parts of 3,3'-dichloro-4, 4'-diaminodiphenylmethane, 3 parts of bio-based porous carbon, 3-10 coupling agents.

[0022] The molecular weight of polypropylene glycol is 2000.

[0023] The bio-based porous carbon is bamboo carbon, and the specific surface area of ​​the carbon material is 1500m 2 / g.

[0024] The coupling agent is γ-aminopropyltriethoxysilane.

[0025] Stir the dehydrated polypropylene glycol and bio-based porous carbon mechanically at 800 rpm for 10 minutes, add isophorone diisocyanate, react at 100-110°C for 3-6 hours, add coupling agent, 3,3'- The dichloro-4,4'-diaminodiphenylmethane is stirred for 10 to 30 seconds, pressurized and vulcanized, and demolded to obtain a bio-based porous carbon reinforced and modified polyurethane composite material. ...

Embodiment 3

[0027] A bio-based porous carbon reinforced modified polyurethane composite material, characterized in that: in parts by weight, including 31 parts of polypropylene glycol, 36 parts of isophorone diisocyanate, 18 parts of 3,3'-dichloro-4, 4'-diaminodiphenylmethane, 5 parts of bio-based porous carbon, 3-10 parts of coupling agent.

[0028] The molecular weight of polypropylene glycol is 2000.

[0029] The bio-based porous carbon is bamboo carbon, and the specific surface area of ​​the carbon material is 1500m 2 / g.

[0030] The coupling agent is γ-aminopropyltriethoxysilane.

[0031] Stir the dehydrated polypropylene glycol and bio-based porous carbon mechanically at 800 rpm for 10 minutes, add isophorone diisocyanate, react at 100-110°C for 3-6 hours, add coupling agent, 3,3'- The dichloro-4,4'-diaminodiphenylmethane is stirred for 10 to 30 seconds, pressurized and vulcanized, and demolded to obtain a bio-based porous carbon reinforced and modified polyurethane composite ma...

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Abstract

The invention relates to a bio-based porous carbon reinforced modification polyurethane composite material which comprises the following ingredients in parts by weight: 30-40 parts of polypropylene glycol, 28-36 parts of isophorone diisocyanate, 18-25 parts of 3,3'-dichloro-4,4'-diaminodiphenyl-methane, 1-20 parts of bio-based porous carbon and 3-10 parts of a coupling agent. In the composite material, the bio-based porous carbon is made by taking natural bamboos or bamboo shoots as a raw material, is simple in preparation process and can be produced industrially in large scale; the prepared polyurethane composite material has excellent tensile property, heat stability and friction-reducing and wear-resisting features, thereby having high production value and use value and being wide in market prospect.

Description

technical field [0001] The invention relates to a method in the technical field of composite materials, in particular to a bio-based porous carbon reinforced modified polyurethane composite material. Background technique [0002] Due to the adjustability of the ratio of soft and hard segments, polyurethane elastomers can prepare polyurethane materials with different properties and pathways, which are widely used in aerospace, marine ships, medical equipment, factory and mining machinery and other engineering fields. The soft segment of polyurethane elastomer determines the flexibility and toughness of the material, and the hard segment determines the strength and rigidity of the material. However, there is an obvious phase separation between the soft and hard segment. Therefore, the pure polyurethane material prepared by conventional methods and formulas has relatively low rigidity, thermal conductivity and thermal stability. Poor performance, low friction coefficient but hi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/75C08G18/66C08G18/48C08G18/32C08K7/24
Inventor 费本华张波陈秀芳钟明强赵正平
Owner INT CENT FOR BAMBOO & RATTAN