Complex protective coating of sink roll used for hot dip coating and preparation method

A technology of protective coating and sinking roll, which is applied in the field of composite protective coating and preparation of sinking rolls for hot-dip galvanizing, which can solve the problem of zinc sticking on the roll surface, poor reusability of the coating, and ineffective resistance to zinc-aluminum solution corrosion, etc. question

Active Publication Date: 2017-12-29
SHANGHAI BAOSTEEL IND TECHNOLOGICAL SERVICE
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Problems solved by technology

However, since the temperature of the molten high-aluminum zinc solution is as high as 550-650°C, which is 100-200°C higher than that of ordinary hot-dip pure zinc (about 450°C), it is more corrosive. Traditionally used WC-Co, Thermal spray coatings such as WC-Co-Cr and Fe-Al can no longer effectively resist the corrosion of zinc-aluminum solution, which greatly reduces the service life of the sinking roller
Therefore, the short service life of sinking rolls and stabilizing rolls has become a bottleneck factor restricting the efficient production of hot-dip high-aluminum zinc sheets
[0006] In order to increase the service life of the sinking roll and improve the quality of the strip steel, there have been attempts at various coatings in the early stage, such as WC-Co, MoB-CoCr, etc., but the results are not satisfactory.
WC-Co will decompose when it exceeds 540°C, so it can

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  • Complex protective coating of sink roll used for hot dip coating and preparation method

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Embodiment Construction

[0019] The composite protective coating of the sink roll for hot dip coating of the present invention includes a primer layer, a transition layer and a working layer; the primer layer is a CoCrW coating, and the transition layer is CaO·SiO 2 Coating of a mixture with CoCrW in proportion, the working layer is CaO·SiO 2 Coating; Among them, the thermal expansion coefficient CTE1 of the bottom layer material is between the thermal expansion coefficient CTE0 of the roller body material and the thermal expansion coefficient CTE3 of the working layer material, and meets CTE1=2CTE0 / 3+CTE3 / 3; the thermal expansion coefficient of the transition layer material CTE2 is between the thermal expansion coefficient CTE0 of the roller body material and the thermal expansion coefficient CTE3 of the working layer material, and satisfies CTE2=CTE0 / 3+2CTE3 / 3.

[0020] Preferably, set CaO·SiO in the transition layer 2 The volume of the material is V1, the volume of the CoCrW material is V2, and the mixi...

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Abstract

The invention discloses a complex protective coating of a sink roll used for hot dip coating and a preparation method. The complex protective coating comprises a bottom layer, a transition layer and a working layer; the bottom layer is a CoCrW coating, the transition layer is a coating of a mixture formed by CaO-SiO2 and CoCrW according to a proportion, and the working layer is a CaO-SiO2 coating; and a thermal expansivity relation among the coatings and a thermal expansivity relation among the coatings and a roll body are set. Coating is performed on the bottom layer by means of high velocity oxygen-fuel equipment, coating is performed on the transition layer and the working layer by means of plasma spraying equipment, corresponding technological parameters are set in the coating forming processes, and accordingly the complex protective coating on the surface of the sink roll is obtained. According to the complex protective coating provided by the invention, through design on the coating structure, good thermal expansion matching between the complex protective coating and base metal of the roll is achieved, and the purpose that the complex protective coating can be applied to practical production stably in a long term is achieved; and the preparation method is easy to operate, and the complex protective coating on the surface of the roll can be prepared and obtained.

Description

Technical field [0001] The invention relates to a composite protective coating of a sinking roller for hot dip plating and a preparation method. Background technique [0002] At present, most anti-corrosion steel products must be hot-dip galvanized. Hot-dip galvanizing technology has become the most economical and effective method for steel anti-corrosion applications. Hot-dip galvanized sheets have good corrosion resistance, processing formability, weldability, Paintability and environmental protection are widely used in many manufacturing fields such as construction, home appliances, vehicles, vessels, containers, and electromechanics. [0003] In the continuous hot-dip galvanizing production line, the zinc liquid is strongly corrosive to all parts in the zinc pot, especially the sunken roller, the surface condition of which is very important and directly affects the surface quality of the steel plate. In actual production, due to the corrosion of the zinc liquid on the parts an...

Claims

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Application Information

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IPC IPC(8): C23C4/129C23C4/134C23C4/08C23C4/06C23C4/11C23C2/00
CPCC23C2/003C23C4/06C23C4/08
Inventor 谭兴海徐建明蒋振华王倩朱文婕
Owner SHANGHAI BAOSTEEL IND TECHNOLOGICAL SERVICE
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