Nickel-based active material for lithium secondary battery, method of preparing the same, and lithium secondary battery including positive electrode including the nickel-based active material
A lithium secondary battery, active material technology, applied in secondary batteries, battery electrodes, chemical instruments and methods, etc., can solve the problems of unsatisfactory capacity characteristics, high resistance, short and long-term life, etc.
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preparation Embodiment 1
[0179] Preparation Example 1: Composite metal hydroxide (Ni 0.6 co 0.2 mn 0.2 (OH) 2 ) preparation
[0180] Composite metal hydroxide powders (Ni 0.6 co 0.2 mn 0.2 (OH) 2 ).
[0181] Ammonia water and raw materials for the nickel-based active material were added to the reactor. The amount of said raw material for the nickel-based active material is controlled or selected to achieve the desired stoichiometric composition of the composite metal hydroxide. Sodium hydroxide was used to adjust the pH of the reactor mixture. Next, continuous agitation of the mixture in the reactor is performed until the desired size of the final product is reached, at which point the addition of the mixture of raw materials to the reactor is stopped. The resulting product is subjected to a drying process, thereby producing a composite metal hydroxide. The process for preparing the composite metal hydroxide will be described in more detail as follows.
[0182] Raw materials to be use...
preparation Embodiment 2
[0185] Preparation Example 2: Composite metal hydroxide (Ni 0.5 co 0.2 mn 0.3 (OH) 2 ) preparation
[0186] Obtain composite metal hydroxide (Ni in the same manner as in Preparation Example 1 0.5 co 0.2 mn 0.3 (OH) 2 ), except that the amounts of nickel sulfate, cobalt sulfate and manganese sulfate were changed to a molar ratio of 5:2:3 and the reaction was carried out for 25 hours.
preparation Embodiment 3
[0187] Preparation Example 3: Composite metal hydroxide (Ni 0.8 co 0.1 mn 0.1 (OH) 2 ) preparation
[0188] Obtain composite metal hydroxide (LiNi 0.8 co 0.1 mn 0.1 (OH) 2 ), except that the amounts of nickel sulfate, cobalt sulfate, and manganese sulfate were changed to a molar ratio of 8:1:1 and the reaction was carried out for 25 hours.
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