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Compressible supercapacitor based on porous sponge structures

A supercapacitor and porous sponge technology, applied in the manufacture of hybrid/electric double layer capacitors, hybrid capacitor electrodes, hybrid capacitor electrolytes, etc., can solve problems such as hindering electrolyte penetration, affecting electrochemical performance, and being unable to withstand stress, etc., to achieve excellent mechanics The effects of performance and electrical performance, high integration, and stable device performance

Inactive Publication Date: 2018-02-16
PEKING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, existing compressible supercapacitors still face many problems
On the one hand, the sponges are mostly carbon-based substances, with average mechanical properties, unable to withstand large stresses, and easy to collapse; on the other hand, due to the hydrophobic nature of some materials used, the penetration of electrolytes is hindered to a certain extent, affecting the Its electrochemical performance

Method used

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  • Compressible supercapacitor based on porous sponge structures
  • Compressible supercapacitor based on porous sponge structures
  • Compressible supercapacitor based on porous sponge structures

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Experimental program
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Embodiment 1

[0040] Aiming at the problems of poor pressure resistance and limited working environment of ordinary energy storage devices today, the embodiment of the present invention provides a supercapacitor with high compressibility, which uses a porous sponge structure electrode. After multiple presses and releases, the electrode The structure and electrical properties hardly change, and based on this, the supercapacitor can be assembled into a supercapacitor, which can maintain stable electrochemical performance and continue to work efficiently under high strain conditions. Among them, the porous sponge structure is obtained by mold infiltration and dissolution, and its electrical conductivity mainly depends on the number of times of dripping the active material solution, and has good mechanical properties. The porous sponge electrode can be assembled with a solid electrolyte to form a compressible supercapacitor, which has stable electrochemical performance and can continuously suppl...

Embodiment 2

[0065] refer to figure 1 , figure 1 It is a structural schematic diagram of the compressible supercapacitor based on the porous sponge structure of the present invention, and its structure includes: porous sponge electrode 1, porous sponge electrode 2, PVA / H 3 PO 4 Solid electrolyte3, flexible diaphragm4, PVA / H 3 PO 4 Solid Electrolyte 5. refer to figure 2 , figure 2 It is a scanning electron micrograph of the porous CNT-PDMS sponge electrode of the present invention. refer to image 3 , image 3 It is the cyclic voltammetry electrochemical waveform of different voltage scan rates in the normal state of the compressible supercapacitor of the present invention. refer to Figure 4 , Figure 4 It is the electrochemical waveform under the cyclic voltage sweep of the compressible supercapacitor of the present invention under different compression states.

[0066] but figure 1 The fabrication steps of the compressible supercapacitor shown are as follows:

[0067] Ste...

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Abstract

The invention provides a compressible supercapacitor based on porous sponge structures and a preparation method. The compressible supercapacitor includes compressible electrodes, solid electrolytes and a flexible diaphragm, the compressible electrodes are of porous sponge structures, the solid electrolytes are permeated in the compressible electrodes, and the flexible diaphragm is between the twocompressible electrodes in which the solid electrolytes are permeated. The abovementioned compressible supercapacitor adopts the electrodes of porous sponge structures, the porous sponge structures have high compressible capability, the high compressible capability is combined with the characteristic of excellent charge storage capacity of an attached active material, the electrodes of porous sponge structures are obtained by performing film inverting dissolution on substances such as cube sugar, the advantages of high compression resistance and large specific surface area of the sponge structures and high electrical conductivity of a carbon nano tube are utilized, the compressible supercapacitor has excellent mechanical property and electrical property, can be applied to various energy storage devices and stress sensing functional devices, has the advantages of simple preparation technology, high integration level, stable device performance and the like, and has very good applicationprospects in the fields of low-power consumption electronic devices and wearable devices.

Description

technical field [0001] The invention relates to the technical field of supercapacitors, in particular to a compressible supercapacitor based on a porous sponge structure and a preparation method thereof. Background technique [0002] With the rapid development of various portable electronic devices, the demand for matching energy units and functional devices is increasing. Compared with rechargeable batteries and traditional capacitors, supercapacitors, as an emerging energy storage device, have good application prospects due to their high power density, good cycle stability, and fast charge and discharge speed. Research. [0003] Nowadays, scientific researchers have done a lot of work on the flexibility of electrode materials and processing methods for applications such as wearable electronics and low-power systems, especially flexible solid-state supercapacitors with good stability, which can avoid electrolyte leakage. Improving the safety and stability of the device, a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G11/26H01G11/56H01G11/84
CPCY02E60/13H01G11/26H01G11/56H01G11/84
Inventor 张海霞宋宇陈号天苏宗明程晓亮
Owner PEKING UNIV
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