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Preparation method of polyamide inhibitor for drilling fluid

The technology of polyamide and inhibitor is applied in the field of preparation of polyamide inhibitor for drilling fluid, which can solve the problems of limited adsorption capacity and loss of inhibitory effect, and achieve the effects of small influence on rheology, good inhibitory effect and good economic benefit.

Inactive Publication Date: 2018-03-27
CHINA NAT PETROLEUM CORP CHUANQING DRILLING ENG CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, due to the limited adsorption capacity of the conventional inhibitors represented by the above-mentioned patent documents, desorption often occurs at high temperatures, resulting in the loss of inhibition at high temperatures.

Method used

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  • Preparation method of polyamide inhibitor for drilling fluid

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] a. Feed the dimer acid A and hydroxyethylethylenediamine B at a molar ratio of 1:1, heat to 60°C, and stir for 30 minutes until the materials are completely melted and mixed evenly.

[0022] b. Under the protection of nitrogen, keep the reaction temperature at 170℃ for 7 hours, and keep the water out.

[0023] c. After the reaction is over, cool the reactant to below 30°C to obtain a yellow viscous liquid as the final product.

Embodiment 2

[0025] a. Feed trimer acid A and hydroxymethyl ethylenediamine B at a molar ratio of 0.75:1, heat to 60°C, and stir for 30 minutes until the materials are completely melted and mixed evenly.

[0026] b. Under the protection of nitrogen, keep the reaction at 180℃ for 8 hours, and keep the water out.

[0027] c. After the reaction, cool the reactant to below 30°C to obtain a brown-yellow viscous liquid that is the final product.

Embodiment 3

[0029] a. Put the mixture of dimer acid A and trimer acid A (1:1) and hydroxyethylethylenediamine B at a molar ratio of 1:1.25, heat to 60℃, stir for 30min, until the material is completely melted, and mix Evenly.

[0030] b. Under the protection of nitrogen, keep the reaction temperature at 180℃ for 6h, and keep the water out.

[0031] c. After the reaction, cool the reactant to below 30°C to obtain a brown-yellow viscous liquid that is the final product.

[0032] Example performance evaluation method

[0033] 1. Rolling recovery experiment of polyamide inhibitor

[0034] Take 4 parts of 350mL distilled water, of which 3 parts were added 1% polyamide inhibitor (Example 1), 7% commonly used inhibitor potassium chloride and 40% commonly used inhibitor potassium formate, in a low-speed agitator (1000rpm / min) and stir for 10 min. Pour four parts of liquid into the aging tank, and then add 50g of shale cuttings. The rolling recovery rate of four liquids was measured at 150℃, and the re...

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Abstract

The invention discloses a preparation method of a polyamide inhibitor for drilling fluid. The preparation method comprises the following steps: (a) feeding a substance A and a substance B into a reactor according to the molar ratio of (0.5 to 2):1, heating to 60 DEG C, and stirring for 30 minutes till the materials are completely melted and mixed uniformly; (b) under the condition of nitrogen-gasprotection, carrying out insulating reaction for 5-8 hours at the temperature of 150-180 DEG C, and separating out water; (c) after the reaction is ended, cooling reactants to below 30 DEG C and obtaining yellow or brown-yellow viscous liquid, namely a final product; the substance A is dimer acid, trimer acid or a mixture of the dimer acid and the trimer acid. The polyamide inhibitor prepared by adopting the method has the characteristics of high-temperature resistance, obvious inhibition effect and slight influence on the rheological property and the like, is applicable to various water-baseddrilling fluid systems, not only can prevent the problem of well-wall instability caused by hydrous dispersion and expansion of clay minerals of the water-sensitive formation, but also can stabilizethe rheological property of the drilling-fluid system effectively and avoid the property from being out of control.

Description

Technical field [0001] The invention relates to the technical field of inhibitors for drilling fluids, and specifically to a method for preparing polyamide inhibitors for drilling fluids. Background technique [0002] When water-sensitive formations such as mudstone and shale are drilled with water-based drilling fluids, the formation minerals are easily hydrated and swelled and dispersed, resulting in instability of the borehole wall and difficulty in controlling the rheology of the drilling fluid. Therefore, the inhibition of the drilling fluid system has become the key to drilling water-sensitive formations. At the same time, as the scope and number of shale gas wells currently being drilled continue to expand, the inhibition of the drilling fluid system has become an important factor for safe drilling on site. [0003] Commonly used water-based drilling fluid inhibitors are mainly potassium salts, ammonium salts and amine (ammonium) polymer inhibitors. Although they have certa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/035
Inventor 陶怀志陈俊斌吴正良袁志平刘翔王兰欧翔
Owner CHINA NAT PETROLEUM CORP CHUANQING DRILLING ENG CO LTD
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