Fluororesin porous body, metal layer-equipped porous body using same, and wiring substrate
A technology of fluororesin and porous body, which is applied in the direction of metal layered products, synthetic resin layered products, porous dielectrics, etc. It can solve the problems of high relative dielectric constant and high relative dielectric constant of materials, and achieve excellent low relative dielectric constant. Excellent electric constant, industrial productivity, and excellent precision
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[0064] In the preparation of the paste in the step (I), when mixing the composition comprising the fluororesin, the hollow inorganic particles and the volatile additive, except that the composition only comprises the fluororesin, the hollow inorganic particle and the volatile additive, It also includes the case where a fluororesin, hollow inorganic particles, and volatile additives are combined with other auxiliary components.
[0065] Next, in the step (II), a molded body with a final target thickness (for example, a thickness of about 0.1 to 2 mm) is produced, and thereafter, the fluorine additive of the present invention can be obtained by removing the volatile additives in the step (III). Resin porous body. The removal of the volatile additive in the step (III) can be carried out by a method appropriately selected from known methods depending on the volatile additive used, and among them, it is preferable to remove the rolled sheet (sometimes referred to as a "film"). Sha...
Embodiment 1~3、 comparative example 1~2
[0089] The above-mentioned raw material components were compounded and mixed in the ratio shown in Table 1 below to prepare a porous body composition (paste), and the paste was rolled at room temperature (23° C.) to form a 150 μm sheet. This sheet was sintered at 400° C. to volatilize the volatile additives to produce a sheet-shaped porous fluororesin body having many pores (average pore diameter: 100 nm).
[0090] Using each of the sheets thus obtained, property evaluation was performed according to the method described later. The results are collectively shown in Table 1 below.
[0091]
[0092] The measurement frequency was set to 10 GHz, the complex permittivity was measured by the resonant cavity perturbation method, and the real number part (εr') was taken as the relative permittivity. Using a relative permittivity measuring device ("NetworkAnalyzer N5230C" manufactured by Agilent Technologie, and "Cavity Resonator 10GHz" manufactured by Kanto Electronic Application a...
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