Compound solid propellant with low burning rate, high energy and high mechanical property
A solid propellant, burning rate technology, applied in the direction of offensive equipment, compressed gas generation, explosives, etc., can solve the melting point of more than 55 ℃, difficult to dissolve and other problems, to achieve excellent and stable mechanical properties, to meet the structural integrity requirements , good compatibility effect
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Embodiment 1
[0041] (1) Propellant composition
[0042] components
PAO-PCL
NG / BTTN
AP
HMX
Al
Content (%wt)
7
18.3
15
42
18
components
TPB
MNA
NPBA
TDI
Content (%wt)
0.05
0.3
0.2
0.15
[0043] Among them: PAO-PCL is the PAO with f=3, Mn=10000 as the initiator, and the PAO-PCL adhesive with f=3, Mn=20000 is prepared according to the molar ratio PAO:PCL=1:1, and the melting point is 50.1°C .
[0044] (2) Propellant performance
[0045] Energy performance (6.86MPa measured specific impulse): 255.2s
[0046] Burning rate: r6.86MPa=7mm / s
[0047] Mechanical properties: 25℃ σ m =0.91MPa, ε m =115%
[0048] +70°C ε m =87%
[0049] -30℃ε m =92%
Embodiment 2
[0051] (1) Propellant composition
[0052] components
PAO-PCL
NG / BTTN
AP
HMX
Al
Content (%wt)
6
19
12.25
47
15
components
TPB
MNA
NPBA
HDI
Content (%wt)
0.05
0.3
0.2
0.2
[0053] Wherein: PAO-PCL is to use the PAO of f=3, Mn=15000 as initiator, according to the molar ratio PAO:PCL=2:1 feeding intake, prepare f=3, the PAO-PCL adhesive of Mn=22500, melting point 50.2°C.
[0054] (2) Propellant performance
[0055] Energy performance (measured specific impulse of 6.86MPa): 255.3s
[0056] Burning rate: r6.86MPa=7.3mm / s
[0057] Mechanical properties: 25℃ σ m =0.91MPa, ε m =125%
[0058] +70°C ε m =97%
[0059] -30℃ε m =98%
Embodiment 3
[0061] (1) Propellant composition
[0062] components
PAO-PCL
NG / BTTN
AP
HMX
Al
Content (%wt)
6.3
19
12
46
16
components
TPB
MNA
NPBA
TDI
Content (%wt)
0.05
0.3
0.2
0.15
[0063] Wherein: PAO-PCL is to use the PAO of f=3, Mn=20000 as initiator, according to molar ratio PAO:PCL=2:1 feeds intake, prepares f=3, the PAO-PCL adhesive of Mn=30000, melting point 51.2°C.
[0064] (2) Propellant performance
[0065] Energy performance (measured specific impulse of 6.86MPa): 255.3s
[0066] Burning rate: r6.86MPa=7.4mm / s
[0067] Mechanical properties: 25℃ σ m =0.91MPa, ε m =129%
[0068] +70°C ε m =102%
[0069] -30℃ε m =90%
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