Ionic liquid compound, preparation method thereof, ionic liquid polymer, use of ionic liquid polymer and polymer solid electrolyte containing ionic liquid polymer

A technology of ionic liquids and compounds, which can be used in the preparation of hybrid capacitor electrolytes, capacitor electrolytes/absorbents, sulfonamides, etc., and can solve the problems of slow ion migration and low conductivity

Active Publication Date: 2018-04-06
BYD CO LTD
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] The purpose of this disclosure is to provide an ionic liquid polymer and a polymer solid electrolyte containing the ionic liqui

Method used

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  • Ionic liquid compound, preparation method thereof, ionic liquid polymer, use of ionic liquid polymer and polymer solid electrolyte containing ionic liquid polymer
  • Ionic liquid compound, preparation method thereof, ionic liquid polymer, use of ionic liquid polymer and polymer solid electrolyte containing ionic liquid polymer
  • Ionic liquid compound, preparation method thereof, ionic liquid polymer, use of ionic liquid polymer and polymer solid electrolyte containing ionic liquid polymer

Examples

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preparation example Construction

[0063] Optionally, the preparation method of the compound shown in formula (9) comprises: making the compound shown in formula (12) contact with a halogenating reagent under halogenation reaction conditions:

[0064]

[0065] Among them, R f for C h f 2h+1 , h is an integer of 0-10.

[0066] Alternatively, the halogenation reagent can be selected from PX 5 and / or POX 3 , X is at least one of Cl, Br and I; the molar ratio of the compound represented by formula (12) to the halogenating agent can be 1:(2-6).

[0067] Optionally, the conditions of the halogenation reaction may be as follows: the reaction temperature is 0-200°C, the reaction time is 1-24h, and the solvent is at least one of dichloromethane, chloroform, acetonitrile, nitromethane and acetone.

[0068] Alternatively, the preparation method of the compound shown in formula (12) comprises: make the compound shown in formula (13) contact with alkali under neutralization reaction condition:

[0069]

[0070] ...

Embodiment 1

[0160] This example is used to illustrate the preparation method of the ionic liquid compound of the present disclosure.

[0161]

[0162]

[0163] 2.0467g (10mmol) of 3,5-dimethylbenzenesulfonyl chloride was reacted with 0.5109g (30mmol) of liquid ammonia at -35°C for 12h to obtain compound 1a (1.6672g, yield 90%); 1 H NMR (400MHz, CDCl 3 , ppm), δ=7.54(s, 2×1H), 6.90(s, 1H), 2.35(s, 2×3H), 2.0(s, 2H);

[0164] 1.8524g (10mmol) of compound 1a was reacted with 2.3794g (20mmol) of thionyl chloride and 1.2817g (11mmol) of chlorosulfonic acid at 100°C for 12h to obtain compound 1b (2.5538g, yield 90%); 1 H NMR (400MHz, CDCl 3 , ppm), δ=7.54(s, 2×1H), 6.90(s, 1H), 2.35(s, 2×3H), 2.0(s, 1H);

[0165] Take 2.8375g (10mmol) of compound 1b and 2.1451g (12mmol) of SbF 3 Reacted at 60°C for 12h to obtain compound 1c (2.4057g, yield 90%); 1 H NMR (400MHz, CDCl 3 , ppm), δ=7.54(s, 2×1H), 6.90(s, 1H), 2.35(s, 2×3H), 2.0(s, 1H);

[0166] Take 2.6730g (10mmol) of compound 1c and...

Embodiment 2

[0171]

[0172] Take 1.8718g (10mmol) of potassium trifluoromethanesulfonamide monohydrogen and 2.2514g (11mmol) of 3,5-dimethylbenzenesulfonyl chloride to react at 80°C for 12h to obtain compound 2a (2.8558g, yield 90%) ; 1 H NMR (400MHz, CDCl 3 , ppm), δ=7.54(s, 2×1H), 6.90(s, 1H), 2.35(s, 2×3H), 2.0(s, 1H);

[0173] Take 3.1731g (10mmol) of compound 2a and 3.7927g (24mmol) KMnO 4 Reacted at 100°C for 12h to obtain compound 2b (3.3954g, yield 90%); 1 H NMR (400MHz, CDCl 3 , ppm), δ=11(s, 2×1H), 9.14(s, 2×1H), 9.0(s, 1H), 2.0(s, 1H);

[0174] Take 3.7727g (10mmol) of compound 2b and 5.5284g (40mmol) K 2 CO 3 Reacted at 25°C for 2h to obtain compound 2c (4.9154g, yield 100%); 1 H NMR (400MHz, CDCl 3 , ppm), δ=8.76(s, 2×1H), 8.4(s, 1H);

[0175] Take 4.9154g (10mmol) of compound 2c and 4.1648g (20mmol) of PCl 5 Reacted at 60°C for 12h to obtain compound 2d (4.0703g, yield 90%); 1 H NMR (400MHz, CDCl 3 , ppm), δ=9.11(s, 2×1H), 8.9(s, 1H);

[0176] 4.5225g (10mmol...

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Abstract

The invention relates to an ionic liquid compound, a preparation method thereof, an ionic liquid polymer, use of the ionic liquid polymer and polymer solid electrolyte containing the ionic liquid polymer and particularly provides an ionic liquid compound with the structure presented by a formula (1) (shown in the description), a preparation method of the ionic liquid compound, an ionic liquid polymer with the structure represented by a formula (20) (shown in the description) and a preparation method of the ionic liquid polymer. Anion centers of the ionic liquid compound and the ionic liquid polymer are perfluorsulfimide ions with relatively weak coordination capacity, so that the binding capacity of the anion centers to Li<+> is reduced, and the specific conductance and Li<+> transferencenumber of the polymer solid electrolyte containing the containing ionic liquid polymer are increased; and the ionic liquid polymer is compounded with lithium salt so as to form the polymer solid electrolyte containing an ionic liquid-polyion liquid compound, and the ionic liquid-polyion liquid compound has a micro-liquid phase structure, so that the specific conductance and Li<+> transference number of the electrolytecan be further increased.

Description

technical field [0001] The disclosure relates to the field of polymer electrolytes, in particular, to an ionic liquid compound and a preparation method, an ionic liquid polymer, its use, and a polymer solid state electrolyte containing the polymer. Background technique [0002] The polymer electrolyte is composed of polymer and lithium salt. The polymer lithium-ion battery can avoid the defects of liquid leakage and explosion in the organic liquid electrolyte in the traditional lithium-ion battery during use. It has plasticity, flexibility, small size and safety. It has the advantages of good performance and large-scale industrial production, so it has attracted widespread attention. However, the room temperature conductivity of existing polymer electrolytes is low, which cannot meet the application requirements. Ionic liquids are usually liquid at room temperature, and have the characteristics of low viscosity, non-volatile, non-combustible, low toxicity, high room tempera...

Claims

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Application Information

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IPC IPC(8): C07D233/58C07C311/48C07C303/40H01G9/028H01G11/56H01M8/1018H01M10/0565C08G63/688C08G69/42
CPCC07C303/40C07C311/48C07D233/58C08G63/6886C08G69/42H01G9/028H01G11/56H01M8/1018H01M10/0565Y02E60/10Y02E60/50
Inventor 宋威谢静马永军易观贵历彪郭姿珠
Owner BYD CO LTD
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