A Method of Using Magnetic Field to Regulate the Ordered Growth of Organic Thin Film Molecules
An organic thin film and magnetic field control technology, applied in the direction of electric solid-state devices, semiconductor devices, photovoltaic power generation, etc., can solve the problem of reduced diffusion length free carrier mobility, reduced orbital overlap, and discontinuous energy bands formed by barriers between molecules To achieve the effect of improving quality and photoelectric characteristics, increasing the degree of ordering, and reducing defect traps
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Embodiment 1
[0037] Step 1, select photosensitizer and organic solvent according to P3HT film, now photosensitizer and organic solvent are acetone and chlorobenzene solution respectively, the volume ratio of photosensitizer and solution is 1:1, at room temperature, dissolve P3HT film, acetone In the chlorobenzene solution, a mixed solution with a concentration of 0.5mg / mL was obtained;
[0038] Step 2, according to the acetone in the step 1, select the excitation light source with a wavelength of 256nm, and the magnetic field adopts a horizontally rotatable magnetic pole alternating magnetic field;
[0039] Step 3. First pour the mixed solution obtained in step 1 into the solution tank, then clamp the pre-cleaned substrate on the jig of the pulling device, and set the parameters of the excitation light source and magnetic field as follows:
[0040] The excitation light intensity is 50mW / cm 2 , the magnetic field intensity is 700GS, the magnetic field gradient is 30GS / cm, and the magnetic ...
Embodiment 2
[0043] Step 1, select photosensitizer and organic solvent according to PCBM film, now photosensitizer and organic solvent are diacetyl and chlorobenzene solution respectively, the volume ratio of photosensitizer and solution is 1:1, at room temperature, PCBM film, Diacetyl was dissolved in chlorobenzene solution to obtain a mixed solution with a concentration of 0.5 mg / mL;
[0044] Step 2. According to the acetone in step 1, an excitation light source with a wavelength of 360nm-400nm is selected, and the magnetic field adopts a transversely rotatable magnetic pole alternating magnetic field;
[0045] Step 3. First pour the mixed solution obtained in step 1 into the solution tank, then clamp the pre-cleaned substrate on the jig of the pulling device, and set the parameters of the excitation light source and magnetic field as follows:
[0046] The excitation light intensity is 60mW / cm 2 , the magnetic field intensity is 600GS, the magnetic field gradient is 25GS / cm, and the mag...
Embodiment 3
[0049] Step 1, select photosensitizer and organic solvent according to P3BT thin film, now photosensitizer and organic solvent are acetone and chlorobenzene solution respectively, the volume ratio of photosensitizer and solution is 1:1, at room temperature, with P3BT thin film, dibutylene The ketone was dissolved in the chlorobenzene solution to obtain a mixed solution with a concentration of 0.5 mg / mL;
[0050] Step 2, according to the acetone in the step 1, select the excitation light source with a wavelength of 256nm, and the magnetic field adopts a horizontally rotatable magnetic pole alternating magnetic field;
[0051] Step 3. First pour the mixed solution obtained in step 1 into the solution tank, then clamp the pre-cleaned substrate on the jig of the pulling device, and set the parameters of the excitation light source and magnetic field as follows:
[0052] The excitation light intensity is 50mW / cm 2 , the magnetic field intensity is 500GS, the magnetic field gradien...
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