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A Method of Using Magnetic Field to Regulate the Ordered Growth of Organic Thin Film Molecules

An organic thin film and magnetic field control technology, applied in the direction of electric solid-state devices, semiconductor devices, photovoltaic power generation, etc., can solve the problem of reduced diffusion length free carrier mobility, reduced orbital overlap, and discontinuous energy bands formed by barriers between molecules To achieve the effect of improving quality and photoelectric characteristics, increasing the degree of ordering, and reducing defect traps

Active Publication Date: 2020-03-27
XIAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The disorder of the molecules leads to the reduction of molecular arrangement density in the film, the increase of the distance between adjacent molecules, the generation of a large number of defect traps, the reduction of orbital overlap, the formation of potential barriers between molecules, and the discontinuity of energy bands.
These problems will lead to a decrease in the diffusion length of excitons by 10nm and a decrease in free carrier mobility10 -7 cm 2 / V·S~10 -2 cm 2 / V·S, thus reducing the transport efficiency
In addition, due to the increase of heterojunction interface states formed at the same time, the exciton recombination rate increases and the separation efficiency decreases, which will eventually affect the electrical characteristics of optoelectronic devices.

Method used

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  • A Method of Using Magnetic Field to Regulate the Ordered Growth of Organic Thin Film Molecules
  • A Method of Using Magnetic Field to Regulate the Ordered Growth of Organic Thin Film Molecules
  • A Method of Using Magnetic Field to Regulate the Ordered Growth of Organic Thin Film Molecules

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Step 1, select photosensitizer and organic solvent according to P3HT film, now photosensitizer and organic solvent are acetone and chlorobenzene solution respectively, the volume ratio of photosensitizer and solution is 1:1, at room temperature, dissolve P3HT film, acetone In the chlorobenzene solution, a mixed solution with a concentration of 0.5mg / mL was obtained;

[0038] Step 2, according to the acetone in the step 1, select the excitation light source with a wavelength of 256nm, and the magnetic field adopts a horizontally rotatable magnetic pole alternating magnetic field;

[0039] Step 3. First pour the mixed solution obtained in step 1 into the solution tank, then clamp the pre-cleaned substrate on the jig of the pulling device, and set the parameters of the excitation light source and magnetic field as follows:

[0040] The excitation light intensity is 50mW / cm 2 , the magnetic field intensity is 700GS, the magnetic field gradient is 30GS / cm, and the magnetic ...

Embodiment 2

[0043] Step 1, select photosensitizer and organic solvent according to PCBM film, now photosensitizer and organic solvent are diacetyl and chlorobenzene solution respectively, the volume ratio of photosensitizer and solution is 1:1, at room temperature, PCBM film, Diacetyl was dissolved in chlorobenzene solution to obtain a mixed solution with a concentration of 0.5 mg / mL;

[0044] Step 2. According to the acetone in step 1, an excitation light source with a wavelength of 360nm-400nm is selected, and the magnetic field adopts a transversely rotatable magnetic pole alternating magnetic field;

[0045] Step 3. First pour the mixed solution obtained in step 1 into the solution tank, then clamp the pre-cleaned substrate on the jig of the pulling device, and set the parameters of the excitation light source and magnetic field as follows:

[0046] The excitation light intensity is 60mW / cm 2 , the magnetic field intensity is 600GS, the magnetic field gradient is 25GS / cm, and the mag...

Embodiment 3

[0049] Step 1, select photosensitizer and organic solvent according to P3BT thin film, now photosensitizer and organic solvent are acetone and chlorobenzene solution respectively, the volume ratio of photosensitizer and solution is 1:1, at room temperature, with P3BT thin film, dibutylene The ketone was dissolved in the chlorobenzene solution to obtain a mixed solution with a concentration of 0.5 mg / mL;

[0050] Step 2, according to the acetone in the step 1, select the excitation light source with a wavelength of 256nm, and the magnetic field adopts a horizontally rotatable magnetic pole alternating magnetic field;

[0051] Step 3. First pour the mixed solution obtained in step 1 into the solution tank, then clamp the pre-cleaned substrate on the jig of the pulling device, and set the parameters of the excitation light source and magnetic field as follows:

[0052] The excitation light intensity is 50mW / cm 2 , the magnetic field intensity is 500GS, the magnetic field gradien...

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Abstract

A method for using a magnetic field to regulate the orderly growth of organic film molecules disclosed in the present invention is specifically implemented according to the following steps: Step 1. Select a photosensitizer and an organic solvent according to the organic material, and dissolve the organic material and the photosensitizer in the organic solvent to form Uniform mixed solution; step 2, select the excitation light source and magnetic field according to the photosensitizer in step 1; step 3, first pour the mixed solution obtained in step 1 into the solution tank, and then clamp the pre-cleaned substrate in the On the jig of the pulling device, the parameters of the excitation light source and the magnetic field are set, and under the action of the excitation light source and the magnetic field, the organic film molecules are grown by the solution pulling method. During the growth process of organic thin films, by adding photosensitizers in the growth solution, exciting light sources, applying magnetic fields and other technological conditions, the degree of ordering of organic thin film molecules is improved, and the quality and photoelectric characteristics of the thin films are improved.

Description

technical field [0001] The invention belongs to the technical field of organic semiconductor thin films, and relates to a method for regulating the orderly growth of organic thin film molecules by using a magnetic field. Background technique [0002] Organic semiconductor thin films are generally molecularly highly disordered thin films. The disorder of molecules leads to the decrease of molecular arrangement density in the film, the increase of the distance between adjacent molecules, the generation of a large number of defect traps, the reduction of orbital overlap, the formation of potential barriers between molecules, and the discontinuity of energy bands. These problems will lead to a decrease in the diffusion length of excitons by 10nm and a decrease in free carrier mobility10 -7 cm 2 / V·S~10 -2 cm 2 / V·S, thereby reducing the transport efficiency. In addition, due to the increase of heterojunction interface states formed at the same time, the exciton recombinatio...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L51/48H01L51/56C08L57/00C08L65/00C08L73/00
CPCC08L57/00C08L65/00C08L73/00H10K71/15Y02E10/549
Inventor 安涛杨圣
Owner XIAN UNIV OF TECH
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