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A nanopowder with dual detection effects on temperature and pH and its preparation method

A nano-powder, dual technology, applied in thermometers, chemical instruments and methods, thermometers with physical/chemical changes, etc., can solve problems such as limited, achieve high sensitivity, simple method, small size effect

Active Publication Date: 2020-09-11
山东零一智慧科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In many scientific fields, there is a wide demand for simultaneous measurement of temperature and pH. However, reports on temperature and pH fluorescent dual detection sensing materials in the prior art are very limited. The nano-powder for detection has a small particle size and a wide range of applications. At the same time, it has high detection accuracy and sensitivity and can quickly respond to temperature and pH changes.

Method used

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  • A nanopowder with dual detection effects on temperature and pH and its preparation method

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Embodiment 1

[0033] A method for preparing a nanopowder with dual detection effects on temperature and pH, the preparation method comprising the following processes:

[0034] (1) First, put silk fibroin powder, sodium phosphate, and biphenyl dicarboxylic acid in deionized water, stir for 30 minutes, then centrifuge the powder from the mixed solution, roll it once, and first place it at 70-90°C Pre-bake for 5 minutes, then bake at a high temperature of 150-160°C for 3 minutes, rinse with deionized water for 5 times, and dry to obtain the first aromatic polycarboxylic acid modified powder; powder, sodium phosphate, biphenyl dicarboxylate The mass ratio is 1:5:8

[0035] (2) Place the powder, catalyst, and aromatic polycarboxylic acid modified by aromatic polycarboxylic acid for the first time in deionized water, repeat the operation of step (1), the number of repetitions is 3 times, and obtain multiple aromatic polycarboxylic acid Modified powder;

[0036] (3) Powder modified with multiple...

Embodiment 2

[0038] A method for preparing a nanopowder with dual detection effects on temperature and pH, the preparation method comprising the following processes:

[0039] (1) First, put silk fibroin powder, sodium phosphate, and terephthalic acid in deionized water, stir for 30 minutes, then centrifuge the powder from the mixed solution, roll it once, and pre-heat at 70-90°C. Bake for 5 minutes, then bake at a high temperature of 150-160°C for 3 minutes, rinse with deionized water for 5 times, and dry to obtain the first aromatic polycarboxylic acid modified powder; the quality of the powder, sodium phosphate, and terephthalic acid The ratio is 1:5:8;

[0040] (2) Place the powder, catalyst, and aromatic polycarboxylic acid modified by aromatic polycarboxylic acid for the first time in deionized water, repeat the operation of step (1), and repeat the number of times for 3 times to obtain multiple aromatic polycarboxylic acid Modified powder;

[0041] (3) Powder modified with multiple...

Embodiment 3

[0043]A method for preparing a nanopowder with dual detection effects on temperature and pH, the preparation method comprising the following processes:

[0044] (1) First, put silk fibroin powder, sodium phosphate, biphenyl dicarboxylic acid and 4-hydroxypyridine-2,6-dicarboxylic acid in deionized water, stir for 30 minutes, and then centrifuge the powder from the mixed solution , rolled once, pre-baked at 70-90°C for 5 minutes, then baked at a high temperature of 150-160°C for 3 minutes, rinsed with deionized water for 5 times, and dried to obtain the first aromatic polycarboxylic acid modified powder body; the mass ratio of biphenyl dicarboxylic acid to 4-hydroxypyridine-2,6-dicarboxylic acid is 1:1, and the mass ratio of powder, sodium phosphate, and hydroxycarboxylic acid is 1:5:8;

[0045] (2) Place the powder, catalyst, and aromatic polycarboxylic acid modified by aromatic polycarboxylic acid for the first time in deionized water, repeat the operation of step (1), the nu...

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Abstract

The invention provides a nanopowder with dual detection effects on temperature and pH, characterized in that: the nanopowder raw materials include powder, catalyst, aromatic polycarboxylic acid, hydroxycarboxylic acid, rare earth salt and water, rare earth salt One or more of the chloride salts or nitrates of Eu and Tb. And provide a kind of method for preparing this nanopowder, comprise the following steps: (1) prepare aromatic polycarboxylic acid modified powder: powder, catalyst, aromatic polycarboxylic acid are placed in deionized water, stir, dry, Obtain the powder modified by aromatic polycarboxylic acid; (2) mix aromatic polycarboxylic acid modified powder, rare earth salt, hydroxycarboxylic acid, take deionized water as medium, carry out hydrothermal reaction, after reaction, drop to room temperature, centrifuged, and dried. The temperature detection range of the nanometer powder is 50-300K, and the pH detection range is 2-6.

Description

technical field [0001] The invention belongs to the field of temperature and pH detection, in particular to a nanopowder with dual detection effects on temperature and pH. Background technique [0002] Temperature is a parameter that often needs to be measured in multidisciplinary fields and industrial production. However, the contact temperature detectors mainly used in the prior art, such as mercury and resistance thermometers, must be in contact with the substance to be measured and respond to the presence of the thermometer. Defects such as slow speed limit the use of traditional thermometers or detectors. In recent years, with the deepening of research, people began to conduct extensive research on temperature sensing materials, and proposed and prepared the use of fluorescence, infrared and other means to achieve temperature sensing to achieve the purpose of detecting temperature. Among them, fluorescence has the characteristics of fast response to temperature changes...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K11/06G01K11/32G01N21/64C08H1/00C08H1/06
CPCG01K11/32G01N21/6428C09K11/06C08H1/00C08H1/06C09K2211/182
Inventor 刘瑞娜任李培肖杏芳徐卫林赵三平
Owner 山东零一智慧科技有限公司
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