A kind of nano-medicine for controllable photodynamic therapy and preparation method thereof
A technology of photodynamic therapy and nano-medicine, which is applied in the field of biomedicine, can solve the problem of high dark toxicity of hematoporphyrin, and achieve the effect of improving the therapeutic effect, enhancing the therapeutic effect, and improving the solubility
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Embodiment 1
[0041] Weigh β-CD (126.4 mg,) and CDI (180.56 mg) was dissolved in 7 mL of DMSO. After stirring the reaction sufficiently 6 h, to the solution was added dropwise a solution of fifth generation polyamide - amine dendrimers (G5 PAMAM) (115.9 mg) in DMSO (3 mL), stirred for 3 days at room temperature. After completion of the reaction, the reaction solution was transferred to 8000-14000 Da molecular weight cutoff dialysis bag, the water in the secondary dialyzed for 3 days. Finally lyophilized to give a white powdery product (CP), stored at -20 ℃. Deuterated DMSO was used as 1 H-NMR spectrum of the test solvent, from figure 1 Found that cyclodextrin has been successfully conjugated to PAMAM.
Embodiment 2
[0043] Take CP, ICG, HP aqueous ultraviolet absorption measurement, such as figure 2 Shown, HP at 374nm, 500-620 nm with a UV absorption peak at a, ICG has characteristic UV absorption peak at 778 nm, CP no UV absorption at 300-900 nm. Measuring CP, ICG, HP fluorescence intensity at an excitation wavelength such as 401nm image 3 HP shown in 616nm, 666nm HP has a characteristic peak, while no fluorescence CP and CPI.
Embodiment 3
[0045] Weigh 10 mg CP dissolved in 8mL DMSO, the ICG (2mg, 1mL DMSO) and HP (0.2mg, 1mL DMSO) was added dropwise to the CP solution, stirred for 3 days at room temperature in the dark. The reaction solution was dialyzed for 3 days in a secondary water, and lyophilized to yield CPHI10. Wherein, ICG encapsulation efficiency and the loading rate was 15.4% ± 0.63% and 6.16% ± 0.03%, respectively, HP encapsulation efficiency and the loading rate was 82.5% ± 0.25% and 3.30% ± 0.64%, respectively.
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